Safety data sheet

Safety Data Sheet
MSDS 2.001.031
Page no.:
4 of 7
Electronically generated document - no signature required.
VARTA Microbattery GmbH
Daimlerstraße 1
73479 Ellwangen
Germany
Fo_175
Edition:
25.05.2016
Version:
11
5. Fire-fighting measures
Suitable extinguishing media:
Metal fire extinction powder, rock salt or dry sand shall be used.
In case only water is available, it can be used in large amounts.
Extinguishing media with limited
suitability:
Carbon dioxide (CO
2
) is not suitable.
Water in small quantities may have adverse effects.
Special protection equipment during
fire-fighting:
Contamination cloth including breathing apparatus.
Special hazard:
Cells may explode and release metal parts.
At contact of electrolyte with water traces of hydrofluoric acid may be formed.
In this case avoid contact and take care for good ventilation.
At contact of charged anode material with water extremely flammable
hydrogen gas is generated.
Attention:
Do not let used extinguishing media penetrate into surface water or ground
water. If necessary, thicken water or foam with suitable solids. Dispose off
properly.
6. Accidental release measures
Person related measures:
Wear personal protective equipment adapted to the situation (protection gloves,
face protection, breathing protection).
Environment protection measures:
Bind released ingredients with powder (rock salt, sand).
Dispose off according to the local law and rules.
Avoid leached substances to penetrate into the earth, canalization or water.
Treatment for cleaning:
If battery casing is dismantled, small amounts of electrolyte may leak. Package
the battery tightly including ingredients together with lime, sand or rock salt. Then
clean with water.
7. Handling and storage
Guideline for safe handling:
Always follow the warning information on the batteries and in the manuals of
devices. Only use the recommended battery types.
Keep batteries away from children.
For devices to be used by children, the battery casing should be protected
against unauthorized access.
Unpacked batteries shall not lie about in bulk.
In case of battery change always replace all batteries by new ones of identical
type and brand.
Do not swallow batteries.
Do not throw batteries into water.
Do not throw batteries into fire.
Avoid deep discharge.
Do not short-circuit batteries
Use recommended charging time and current.
Do not open or disassemble batteries.
Storage:
Storage preferably at room temperature (approx. 20°C). Avoid large
temperature changes. Do not store close to heating devices. Avoid direct
sunlight. At higher temperature the electrical performance may be reduced.
Preferred storage at 50% of the nominal capacity (OCV see chapter 1, or
multiples of this in case of serial multi-cell configurations).
Storage of unpacked batteries can cause short circuit and heat generation.
Storage category
according to TRGS 510:
It is recommended to consider the “Technical Rule for Hazardous Substances
TRGS 510 - Storage of hazardous substances in nonstationary containers” and
to handle rechargeable lithium ion batteries according to storage category 11
(“combustible solids“).