SAFETY DATA SHEET THE DOW CHEMICAL COMPANY Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 Print Date: 06/11/2018 THE DOW CHEMICAL COMPANY encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions. 1.
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 Signal word: DANGER! Hazards Flammable aerosol. Contains gas under pressure; may explode if heated. Causes skin and eye irritation. May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. May cause harm to breast-fed children.
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 Other hazards No data available 3. COMPOSITION/INFORMATION ON INGREDIENTS This product is a mixture. Component CASRN Concentration Polymethylenepolyphenylisocyanate, propoxylated glycerin polymer 57029-46-6 >= 30.0 - <= 60.0 % Diphenylmethane Diisocyanate, isomers and homologues 9016-87-9 >= 10.0 - <= 30.
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by qualified personnel. Call a physician or transport to a medical facility. Skin contact: Remove material from skin immediately by washing with soap and plenty of water.
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 Hazardous combustion products: During a fire, smoke may contain the original material in addition to combustion products of varying composition which may be toxic and/or irritating. Combustion products may include and are not limited to: Nitrogen oxides. Isocyanates. Hydrogen chloride. Carbon monoxide. Carbon dioxide. Hydrogen cyanide.
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 7. HANDLING AND STORAGE Precautions for safe handling: Keep away from heat, sparks and flame. Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated contact with skin. Wash thoroughly after handling. Keep container closed. Use only with adequate ventilation. No smoking, open flames or sources of ignition in handling and storage area.
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 from the source of vapor/aerosol generation and people working at this point. The odor and irritancy of this material are inadequate to warn of excessive exposure. Lethal concentrations may exist in areas with poor ventilation. Individual protection measures Eye/face protection: Use safety glasses (with side shields).
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 12oz HC ES SASTW 12ct Lower explosion limit Upper explosion limit Vapor Pressure Relative Vapor Density (air = 1) Relative Density (water = 1) Water solubility Partition coefficient: noctanol/water Auto-ignition temperature Decomposition temperature Kinematic Viscosity Explosive properties Oxidizing properties Molecular weight Issue Date: 06/07/2018 No test data available No test data available 1,151 kPa at 55 °C (131 °F) Calculated.
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 Acute toxicity Acute oral toxicity Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal handling operations are not likely to cause injury; however, swallowing larger amounts may cause injury. Observations in animals include: Gastrointestinal irritation. As product: Single dose oral LD50 has not been determined. LD50, Rat, > 2,000 mg/kg Estimated.
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 Contains component(s) which are classified as specific target organ toxicant, single exposure, category 3. Specific Target Organ Systemic Toxicity (Repeated Exposure) Tissue injury in the upper respiratory tract and lungs has been observed in laboratory animals after repeated excessive exposures to MDI/polymeric MDI aerosols.
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 Diphenylmethane Diisocyanate, isomers and homologues Acute toxicity to fish The measured ecotoxicity is that of the hydrolyzed product, generally under conditions maximizing production of soluble species. Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 Chronic toxicity to aquatic invertebrates NOEC, Daphnia magna (Water flea), semi-static test, 21 d, number of offspring, 32 mg/l Paraffin waxes and Hydrocarbon waxes, chlorinated Acute toxicity to fish Material is highly toxic to aquatic organisms on an acute basis (LC50/EC50 between 0.1 and 1 mg/L in the most sensitive species tested). LC50, Oncorhynchus mykiss (rainbow trout), 96 Hour, > 0.
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 Biodegradability: Expected to degrade slowly in the environment. For similar material(s): Biodegradation: 5 % Exposure time: 28 d Method: OECD Test Guideline 301D Theoretical Oxygen Demand: 2.89 mg/mg Isobutane Biodegradability: Biodegradation may occur under aerobic conditions (in the presence of oxygen). Theoretical Oxygen Demand: 3.
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 Test Type: Half-life (indirect photolysis) Sensitization: OH radicals Atmospheric half-life: 8.4 d Method: Estimated. Bioaccumulative potential Polymethylenepolyphenylisocyanate, propoxylated glycerin polymer Bioaccumulation: No relevant data found. Diphenylmethane Diisocyanate, isomers and homologues Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3).
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 Diphenylmethane Diisocyanate, isomers and homologues In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas.
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 14. TRANSPORT INFORMATION DOT Proper shipping name UN number Class Packing group Aerosols UN 1950 2.1 Classification for SEA transport (IMO-IMDG): Proper shipping name AEROSOLS UN number UN 1950 Class 2.
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community Right-to-Know Act of 1986) Section 313 This product contains the following substances which are subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and which are listed in 40 CFR 372.
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 AICS - Australian Inventory of Chemical Substances; ASTM - American Society for the Testing of Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Substances List (Canada); ECx -
