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Article Safety Data Sheet - Lithium Batteries Version: 2019-12-01
Page 2 of 17
Eye Dam. 1 H318: Causes serious eye damage
Skin Irrit. 2 H315: Causes skin irritation
Acute Tox. 4 H302: Harmful if swallowed
Acute Tox. 4 H332: Harmful if inhaled
STOT RE 2 H373: May cause damage to organs (Brain) through prolonged or repeated exposure (Inhalation)
Repr. 1B H360 FD: May damage fertility. May damage the unborn child.
Water-react. 1 H260: In contact with water releases flammable gases which may ignite spontaneously
2.2 GHS Label elements, including precautionary statements
The UN GHS labeling information is not provided in this section as batteries are articles and therefore are exempted
from the UN GHS labeling requirements. Other labeling requirements apply for batteries according to EU Directive
2006/66/EC.
Nevertheless the following warning must be observed:
Keep out of reach of children.
2.3 Other hazards which do not result in classification
The chemicals mentioned in Section 3 are contained in a sealed can.
Risk of exposure occurs only if the battery is mechanically or electrically abused or if it is ingested (see Safety
precautions in Section VII). Swallowing of a battery can lead to chemical burns, perforation of soft tissues and death.
Severe burns can occur within 2 hours of ingestion. In case of ingestion, seek medical attention immediately.
Section 3 - Composition / Information on Ingredients
3.1 Substances
Not applicable
3.2 Mixtures
IMPORTANT NOTE: The battery should not be opened or exposed to heat because exposure of the following
ingredients contained within could be harmful under some circumstances.
Hazardous substances contained in the product according to UN-GHS:
CAS No.
Content % of
total weight
Hazard class and
category
Hazard statement
Manganese Dioxide (MnO
2
) 1313-13-9 12 - 50
Acute Tox. 4, Acute Tox.
4, STOT RE 2
H302, H332, H373
(Brain) (Inhalation)
Lithium* 7439-93-2 1.1 - 3.3
Water-react. 1
Skin Corr. 1B
H260,
H314
108-32-7
2 - 9
Eye Irrit. 2
H319
1,2 dimethoxy ethane (DME)** 110-71-4 1 - 3.5
Flam Liq. 2, Acute Tox.
4, Repr. 1B
H225, H332,
H360FD
Lithium Perchlorate (LiClO
4
) 7791-03-9 0.2 0.8
Ox. Sol. 2, Skin. Irrit. 2,
Eye Irrit. 2, STOT SE 3
H272, H315,
H319, H335
* Approximate weight content of lithium in each model can be found in Annex I