SDS

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Acute (short term): see Section 8 for exposure controls.
In the event that this cell or pack has been ruptured, the electrolyte solution contained within the cell would
be corrosive and can cause burns to skin and eyes.
Inhalation: Inhalation of materials from a sealed cell is not an expected route of exposure. Vapors or mists
from a ruptured cell may cause respiratory irritation.
Ingestion: Swallowing of materials from a sealed cell is not an expected route of exposure. Swallowing the
contents of an open cell can cause serious chemical burns to mouth, esophagus, and gastrointestinal tract.
Skin: Contact between the cell and skin will not cause any harm. Skin contact with the contents of an open
cell can cause severe irritation or burns to the skin.
Eye: Contact between the cell and the eye will not cause any harm. Eye contact with the contents of an open
cell can cause severe irritation or burns to the eye.
CHRONIC (long term): see Section 11 for additional toxicological data.
Interactions with other chemicals: Immersion in high conductivity liquids may cause corrosion and breaching of
the cell or battery enclosure. The electrolyte solution inside of the cells may react with alkaline (basic) materials
and present a flammability hazard.
Potential Environmental Effects: Not Available.
3. Composition/information on ingredients
Hazardous components
Chemical Name
CAS No.
*Mass range in cell (g/g %)
Electrolyte
Contains Electrolyte salt and solvents.
5-20
Electrolyte salt
Lithium hexafluorophosphate
21324-40-3
0.05-5
Electrolyte
solvent
Includes one or more of the following;
Ethelyne Carbonate
Propylene Carbonate
Diethyl Carbonate
Ethyl propionate
96-49-1
108-32-7
105-58-8
105-37-3
5-20
PVDF
Polyvinylidenfluoride
24937-79-9
<1
Copper
Cu
7440-50-8
3-15
Aluminium
Al
7429-90-5
2-10
Cathode
Lithium cobalt oxide
12190-79-3
20-50
Anode
Graphite
7782-42-5
10-30
Steel, Nickel, and
inert components
Various
Balance
Because of the cell structure the dangerous ingredients will not be available if used properly.
During charge process a lithium
graphite intercalation phase is formed.
4. First Aid Measures
Description of first aid measures
The hazardous components of this cell or battery are contained within a sealed unit. The following measures are only
applicable if exposure has occurred to components when a cell or battery leaks, is exposed to high temperatures or is
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mechanically, electrically or physically abused/damaged. The hazardous contents are caustic alkaline electrolytes
contained in cells with lithium metal oxide cathodes, graphite and carbon anodes and Polyvinylidenfluoride binders.
Ingestion: Have victim rinse mouth thoroughly with water. DO NOT INDUCE VOMITING. Quickly transport victim
to an emergency care facility.
EYE: If eye contact with contents of an open cell occurs, immediately flush the contaminated eye(s) with water.
Quickly transport victim to an emergency care facility.
Skin Contact: Immediately flush with water. If irritation or pain persists, seek medical attention.
Inhalation: Remove the patient from exposure into fresh air, seek medical attention.
PROTECTION FOR FIRST
AIDERS: Do not enter corrosive vapor contaminated areas without a respirator or Self Contained Breathing
Apparatus. Wear adequate personal protective equipment as indicated in Section 8.
FIRST AID FACILITIES: Eye wash bottle, fountain, safety showers or at least a source of running water are required
in the area where the product is used.
Most important symptoms & effects, acute & delayed, caused by exposure:
ACUTE: The contents of the battery are rated as corrosive. Ingestion of the electrolyte could lead to severe
gastrointestinal tract irritation with nausea, vomiting and potentially burns. Inhalation of vapors may lead to severe
irritation of the mouth and upper respiratory tract with a burning sensation, pain, burns and inflammation in the
nose and throat; there may also be coughing or difficulty breathing. Eye contact may lead to severe eye irritation
or in worst case scenario irreversible damage and possible eye burns. Skin contact may lead to irritation and
possible skin burns.
CHRONIC: Skin contact may aggravate/exacerbate existing skin conditions, such as dermatitis. Chronic inhalation
may lead to the same symptoms as listed for acute inhalation above.
Indication of any immediate medical attention and special treatment needed
ADVICE TO DOCTOR: Treat symptomatically if the person comes into contact with the corrosive electrolyte liquid
contents of a damaged battery.
5. Fire Fighting Measures
Suitable extinguishing media
Cold water and dry powder in large amount are applicable.
Use metal fire extinction powder or dry sand if only few cells are involved.
Special hazards arising from the chemical
May form hydrofluoric acid if electrolyte comes into contact with water.
In case of fire, the formation of the following flue gases cannot be excluded:
Hydrogen fluoride (HF), Carbon monoxide and carbon dioxide.
Protective equipment and precautions for firefighters
Wear self-contained breathing apparatus and protective suit.
Additional information
If possible, remove cell(s) from fire fighting area. If heated above 125°C, cell(s) can explode/vent. Cell is
not flammable but internal organic material will burn if the cell is incinerated.
6. Accidental Release Measures
Personal precautions, protective equipment and emergency procedures:
As an immediate precautionary measure, isolate spill or leak area for at least 25 meters (75 feet) in all directions.
Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate closed areas before entering.