SDS

Alkaline Zn-Mn Dry Battery LR6AA
Safety Data Sheet
According t o OSHA Hazard Communication Standard 29 C FR 1910.1200
02/28/2020 EN (English) 2/8
3.2. Mixtures
Nam e
Product identifier
%
Manganese oxide (MnO2)
(CAS-No.)
1313-13-9
42 - 48
Zinc
(CAS-No.)
7440-66-6
15 - 25
Steel
(CAS-No.)
12597-69-2
15 - 22
Potassium hy droxide
(CAS-No.)
1310-58-3
12 - 18
Viny l acetal poly mers , f ormals
(CAS-No.)
63148-64-1
1 - 3
Full text of hazard classes and H-statements : see section 16
SECTION 4: First-aid measures
4.1. Description of first aid m easures
First-aid measures general
:
No hazards w hich require special first aid measures.
If you f eel unw ell, seek medical advice (show directions for use or safety data sheet if possible).
First-aid measures after inhalation
:
Not an expected route of exposure.
First-aid measures after skin contact
:
Not expected to present a skin hazard under anticipated conditions of normal use. No special
technical protective measures are necessary.
First-aid measures after eye contact
:
Not an expected route of exposure.
First-aid measures after ingestion
:
Rinse mouth Get medical attention Never give anything by mouth to an unconscious person
4.2. Most important symptoms and effects (acute and delayed)
Symptoms/ef fects after ingestion
:
Symptoms may include tightness in the chest, flushing, headache, nausea, vomiting,
respiratory depression, w eakness, irregular heartbeat, abdominal pain, convulsions, and shock
4.3. Im mediate medical attention and special treatment, if ne cessary
Treat symptomatically.
SECTION 5: Fire-fighting measure s
5.1. Suitable (and unsuitable) e xtinguishing media
Suitable extinguishing media
:
Dry sand or Class D extinguishing agents. If the battery is burning, w ater can also be
submerged ignition ground.
Unsuitable extinguishing media
:
No information available.
5.2. Specific hazards ar ising from the chemical
Fire hazad
:
Battery can be overheated by an external source or by internal shorting and develop metal
hydroxide mist.
In fire situations fumes containing manganese, Zinc, etc. may evolved.
Toxic vapor may release in case of fire.
Thermal shock may cause battery case to crack open.
Containers may explode w hen heated.
Firefighting w ater runoff and dilution w ater may be toxic and corrosive and may cause adverse
environmental impacts.
On some bad using conditions (e.g., mechanical damage, external short circuit.) and in case of
a bad functioning, some electrolyte can be removed from the cell by the security vent.
Exposure to the ingredients contained w ithin the battery pack could be harmful under some
circumstances.
Hazardous decomposition products in case of
fire
Thermal decomposition can lead to release of irritating and toxic gases and vapors
5.3. Special protective e quipment and precautions for fire-fighters
Protection during firefighting
:
Do not attempt to take action w ithout suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.
Other information
:
Evacuate personnel to a safe area. Move containers f rom fire area if it can be done without
personal risk. Cool tanks/drums w ith w ater spray/remove them into safety. Stay upwind.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and e mergency procedures
6.1.1. For non-emergency personnel
Emergency procedures
:
Evacuate personnel to a safe area;Ensure adequate ventilation, especially in conf ined
areas;No flames, no sparks. Eliminate all sources of ignition. Do not breathe
dust/fume/gas/mist/vapors/spray. Avoid contact with skin, eyes and inhalation of vapors