Datasheet

ManualsBrandsAlcoa Inc. ManualsMechanical ComponentsAluminium Angle Section, Length 1 m

SAFETY DATA SHEET

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

WROUGHT ALUMINIUM PRODUCTS, 6xxx SERIES ALLOYS

Trade name or designation

of the mixture

668

SDS number

August 24, 2017.

Revision date

Version number

Mixture

Chemical description

6xxx series alloys, Alclad 6061 * C02U, C03T, CO3U, C04J, C04T, C05T, C14N, C16N, C17T,

C211, C25T, C333, C34P, C36P, C38P, C39P, C400, C40H, C41P, C420, C43P, C44P, C456,

C45A, C45E, C593, C63B, C703, C704, C73H, C74H, C76E, C87H, C95T, C989, CA65, CB90,

CE84, CH68, CU74, CZ19, CZ26, C32T, C40T, C58P, C74W, C95U, C83Z, C412F, C411F, C83S,

C452F, C16T, C471F, C472F, C485F, C41H, C439F, C61B, * C61B, C532F, C710, C81U, C57H,

C22Z, C501F, C593F, C020D, C010D, C79A, C030D, C31P, C37Z, C02T, C040D, C629F, C67Z,

C69Z, C76Z, C01U, C51ZM, C94T, C85A, C2A5, C0A2, C0A8, C3A4, C1A9, C669F, C651F, *

C682F, C46P, C504F, C871F, C872F, C885F, C03S, C01T, C822F, C20U, C42P, C88U, C336,

C050D, C6A1, C156H, C12Z, C166H, C4A1, C183H, C184H, C197H, C196H, C201H, C225H,

C226H, C227H, C229H, C167H, C230H, C231H, C45P, C247H, C221H, * C128H, C199H, C312H,

C7A1, C256H, C173H, C296H, C300H, C292H, C328H, C327H, C324H, C329H, C398H, C399H,

C344H, C362H, C346H, C347H, C350H, C214H, C311H, C317H, C323H, C209H, C321H, C348H,

C361H, C325H, C301H, C200H, C0A7, C224H, C65U, C364H, C366H

Synonyms

Aluminium: Arconic Fusina Rolling s.r.l 01-2119529243-45-XXXX; Arconic Manufacturing (GB)

Ltd 01-2119529243-45-XXXX; Arconic-Köfém Light Metal Works of Székesfehérvár LLC

01-2119537203-49-XXXX.

Magnesium:Arconic Fusina Rolling s.r.l 01-2119537203-49-XXXX

Silicon: Arconic Fusina Rolling s.r.l 01-2119529243-45-XXXX.

REACH Registration Number

1.2. Relevant identified uses of the substance or mixture and uses advised against

Various fabricated aluminium parts and products

Identified uses

Does not include alloys: C217H, C228H, C524F, 6012, 6018, 6026, 6042, 6064, 6064A, 6068,

6262, C6262,C6262V (See SDS Number 390); C213H, C366, C533F, 6012A, 6020, C6020, 6021,

6023, 6028, 6040, 6041, 6262A (See SDS Number 723); C210, C215H, C26N (See SDS Number

973); C7A5, (See SDS Number 1008); C016D, (See SDS Number 807)

Commercial or industrial use.

Recommended Restrictions

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Material name: WROUGHT ALUMINIUM PRODUCTS, 6xxx SERIES ALLOYS

668 Version #: 13 Revision date: 24-August-2017 Issue date: 09-March-2017

ARCONIC SDS GBR 2016

Summary of content (20 pages)

PAGE 1
SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name or designation of the mixture WROUGHT ALUMINIUM PRODUCTS, 6xxx SERIES ALLOYS SDS number 668 Revision date August 24, 2017.
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1.3. Details of the supplier of the safety data sheet Arconic Inc. 201 Isabella Street Pittsburgh, PA 15212-5858 USA Health and Safety Tel: 1-412-553-4649 Health and Safety Fax: 1-412-553-4822 Health and Safety Email: SDSInfo@arconic.com 1.4 Emergency Information Website Fusina Rolling s.r.l Via dell'elettronica 31 30176 Marghera loc. Fusina - Venice. Italy Tel: +39 041 2917200 Fax: +39 041 2917250 Arconic-Köfém Kft.
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Precautionary statements Prevention Observe good industrial hygiene practices. Prevent dust accumulation to minimize explosion hazard. Not available. Response Storage Keep dry. Store in a dry place. P402 Disposal Reuse or recycle material whenever possible. Dispose of contents/container in accordance with local/regional/national/international regulations. P501 Supplemental label information None. 2.3. Other hazards None known. SECTION 3: Composition/information on ingredients 3.2.
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List of abbreviations and symbols that may be used above † - Present as impurity. While Lead is not intentionally added to this mixture, it could potentially enter through the recycle stream. † - Alloys: 6033, 6061A, 6065, 6082A. 6351A. ‡ - Present as impurity. While Nickel is not intentionally added to this mixture, it could potentially enter through the recycle stream . Additional compounds which may be formed during processing are listed in Section 8.
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Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Not sensitive. Product as shipped: Not sensitive. Dust from processing Take precautionary measures against static discharges when there is a risk of dust explosion. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Avoid generating dust. Avoid contact with sharp edges or heated metal.
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Requirements for Processes which Generate Dusts or Fines If processing of this product generates dust or if extremely fine particulate is generated, obtain and follow the safety procedures and equipment guides contained in Aluminum Association Bulletin F-1 and National Fire Protection Association (NFPA) brochures listed in Section 16. Use non-sparking handling equipment, tools and natural bristle brush. Cover and reseal partially empty containers.
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UK. EH40 Workplace Exposure Limits (WELs) Compounds Formed Type During Processing Value Form Inhalable Lead compounds, inorganic Magnesium oxide (CAS 1309-48-4) TWA TWA 10 mg/m3 0,15 mg/m3 4 mg/m3 Manganese compounds, inorganic Manganese oxide (CAS 1344-43-0) Ozone (CAS 10028-15-6) TWA 10 mg/m3 0,5 mg/m3 TWA 0,5 mg/m3 STEL 0,4 mg/m3 Silica, amorphous (CAS 112926-00-8) TWA 0,2 ppm 6 mg/m3 Inhalable dust. Welding fumes TWA 2,4 mg/m3 4 mg/m3 10 mg/m3 Respirable dust. Respirable dust.
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Arconic Compounds Formed During Processing Type Value Form Aluminium oxide (non-fibrous) (CAS 1344-28-1) TWA 3 mg/m3 Respirable fraction. TWA 10 mg/m3 0,25 ug/m3 Total dust. Chromium (VI) compounds, certain water insoluble forms Chromium (VI) compounds (CAS 18540-29-9) Manganese compounds, inorganic TWA 0,25 µg/m3 TWA 0,05 mg/m3 Total dust, as Mn. 0,02 mg/m3 Nickel compounds, insoluble Residuals TWA 0,1 mg/m3 Respirable fraction, as Mn.
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US ACGIH Threshold Limit Values: Time Weighted Average (TWA): mg/m3, non-standard units Compounds Formed Value Type During Processing Form Lead compounds, inorganic Magnesium oxide (CAS 1309-48-4) Manganese compounds, inorganic TWA TWA 0,05 mg/m3 10 mg/m3 Inhalable fraction. TWA 0,1 mg/m3 Inhalable fraction. Manganese oxide (CAS 1344-43-0) TWA 0,02 mg/m3 0,1 mg/m3 Respirable fraction. Inhalable fraction.
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Individual protection measures, such as personal protective equipment Personnel who handle and work with molten metal should utilize primary protective clothing like General information polycarbonate face shields, fire resistant tapper's jackets, neck shades (snoods), leggings, spats and similar equipment to prevent burn injuries. In addition to primary protection, secondary or day-to-day work clothing that is fire resistant and sheds metal splash is recommended for use with molten metal.
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Solubility(ies) Solubility (water) Solubility (other) Insoluble Not available. Partition coefficient (n-octanol/water) Not applicable. Not applicable Auto-ignition temperature Not applicable Decomposition temperature Not applicable Viscosity Not applicable. Explosive properties Dust clouds may be explosive under certain conditions. Oxidising properties Not applicable. 9.2.
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10.5. Incompatible materials 10.6. Hazardous decomposition products Chips, fines, dust and molten metal are considerably more reactive with the following: • Strong oxidizers: Violent reaction with considerable heat generation. Can react explosively with nitrates (e.g., ammonium nitrate and fertilizers containing nitrate) when heated or molten. • Acids and alkalis: Reacts to generate flammable/explosive hydrogen gas. Generation rate is greatly increased with smaller particles (e.g., fines and dusts).
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Hexavalent chromium compounds (chromium VI): Can cause irritation of eye, skin and respiratory tract. Skin contact: Can cause irritant dermatitis, allergic reactions and skin ulcers. Chronic overexposures: Can cause perforation of the nasal septum, respiratory sensitization, asthma, the accumulation of fluid in the lungs (pulmonary edema), lung damage, kidney damage, lung cancer, nasal cancer and cancer of the gastrointestinal tract. IARC/NTP: Listed as "known to be a human carcinogen" by the NTP.
PAGE 14
Components Species Test results Rat > 9000 mg/kg Rat > 10000 mg/kg ‡Nickel (CAS 7440-02-0) Acute Oral LD50 Aluminium (CAS 7429-90-5) Acute Oral LD50 > 2000 mg/kg Zinc (CAS 7440-66-6) Acute Oral LD50 Rat 630 mg/kg Skin corrosion/irritation Not classified. Based on available data, the classification criteria are not met. Non-corrosive. Serious eye damage/eye irritation Dust and fume from processing: Can cause mechanical irritation.
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Reproductive toxicity Product as shipped: Does not present any reproductive hazards. Dust from mechanical processing: Can present a reproductive hazard (Lead). Additional health effects from elevated temperature processing (e.g., welding, melting): Dust and fume from processing: Can present a reproductive hazard (Lead compounds, Manganese compounds). Specific target organ toxicity - single exposure Not classified. Based on available data, the classification criteria are not met.
PAGE 16
Components Species Test results EC50 Water flea (Daphnia magna) 40 mg/l, 48 hours Aquatic Crustacea EC50 Water flea (Daphnia magna) 2,8 mg/l, 48 hours Fish LC50 Rainbow trout,donaldson trout (Oncorhynchus mykiss) 0,56 mg/l, 96 hours Manganese (CAS 7439-96-5) Aquatic Crustacea Zinc (CAS 7440-66-6) * Estimates for product may be based on additional component data not shown. The product contains inorganic compounds which are not biodegradable. 12.2. Persistence and degradability 12.3.
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Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 1 as amended Lead compounds, inorganic (CAS S~PB~I) Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 2 as amended Not listed. Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 3 as amended Not listed. Regulation (EU) No.
PAGE 18
‡Nickel (CAS 7440-02-0) Chromium (VI) compounds (CAS 18540-29-9) Lead compounds, inorganic (CAS S~PB~I) Nitrogen dioxide (CAS 10102-44-0) The product is classified and labelled in accordance with EC directives or respective national laws. Other regulations National regulations This safety datasheet has been prepared according to European Union legislation.
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Key/Legend: ACGIH American Conference of Governmental Industrial Hygienists AICS Australian Inventory of Chemical Substances CAS Chemical Abstract Services CERCLA Comprehensive Environmental Response, Compensation, and Liability Act CFR Code of Federal Regulations CPR Cardio-pulmonary Resuscitation DOT Department of Transportation DSL Domestic Substances List (Canada) EC Effective Concentration ED Effective Dose EINECS European Inventory of Existing Commercial Chemical Substances ENCS Japan - Existing and N
PAGE 20
WROUGHT ALUMINIUM PRODUCTS, 6xxx SERIES ALLOYS CONTAINS: Nickel; Lead; Aluminium; Chromium; Copper; Iron; Magnesium; Manganese; Silicon; Zinc Hazard statements May form combustible dust concentrations in air. Precautionary statements Observe good industrial hygiene practices. Prevent dust accumulation to minimize explosion hazard. Keep dry. P402 - Store in a dry place. Reuse or recycle material whenever possible.