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Safety Data Sheet

According to OSHA HCS 2012 (29 CFR 1910.1200)

Section 1: Identification

Product Identifier:

Propane

Other means of identification:

Commercial Propane(All)

HD5 Propane

LP-Gas

Liquefied Petroleum Gas

Odorized Propane

Propane (Unstenched)

Propane Commercial

Propane Motor Fuel

Propane for Process

Stenched Propane

Unodorized Propane

SDS Number: 169570

Intended Use:

Fuel

Uses Advised Against:

All others

Emergency Health and Safety

Number:

Chemtrec: 800-424-9300 (24 Hours)

Section 2: Hazards Identification

Manufacturer:

Phillips 66 Company

P.O. Box 4428

Houston, Texas 77210

SDS Information:

Phone: 800-762-0942

Email: SDS@P66.com

URL: www.Phillips66.com

Classified Hazards Other Hazards

H220 -- Flammable gases -- Category 1

H280 -- Gases under pressure -- Liquefied gas

May displace oxygen and cause rapid suffocation

Label Elements

Section 3: Composition / Information on Ingredients

Chemical Name CASRN Concentration¹

Propane 74-98-6 80-100

Propene 115-07-1 <20

Ethane 74-84-0 <6

Butane 106-97-8 <5

Isobutane 75-28-5 <2.5

¹ All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _

Odorized products contain small quantities (<0.1%) ethyl mercaptan as an olfactory indicator.

169570 - Propane

DANGER

Page 1/8

Extremely flammable gas

Contains gas under pressure. May explode if heated.

Date of Issue: 08-Oct-2013

May displace oxygen and cause rapid suffocation

Status: FINAL

Keep away from heat/sparks/open flames/hot surfaces. - No smoking; Take precautionary measures against static discharge;

Leaking gas fire: Do not extinguish, unless leak can be stopped safely; Eliminate all ignition sources if safe to do so; Protect from

sunlight. Store in a well ventilated place

Summary of content (8 pages)

PAGE 1
Safety Data Sheet According to OSHA HCS 2012 (29 CFR 1910.
PAGE 2
169570 - Propane Page 2/8 Date of Issue: 08-Oct-2013 Status: FINAL _____________________________________________________________________ Section 4: First Aid Measures Eye Contact: For contact with the liquefied gas, remove contact lenses if present and easy to do, hold eyelids apart and gently flush the affected eye(s) with lukewarm water. Seek immediate medical attention. Skin Contact: Liquefied gases may cause cryogenic burns or injury.
PAGE 3
169570 - Propane Page 3/8 Date of Issue: 08-Oct-2013 Status: FINAL _____________________________________________________________________ Special protective actions for firefighters: For fires beyond the initial stage, emergency responders in the immediate hazard area should wear protective clothing. When the potential chemical hazard is unknown, in enclosed or confined spaces, a self contained breathing apparatus should be worn.
PAGE 4
169570 - Propane Page 4/8 Date of Issue: 08-Oct-2013 Status: FINAL _____________________________________________________________________ Conditions for safe storage: Keep container(s) tightly closed and properly labeled. Use and store this material in cool, dry, well-ventilated areas away from heat, direct sunlight, hot metal surfaces, and all sources of ignition. Store only in approved containers. Post area "No Smoking or Open Flame." Keep away from any incompatible material (see Section 10).
PAGE 5
169570 - Propane Page 5/8 Date of Issue: 08-Oct-2013 Status: FINAL _____________________________________________________________________ Section 10: Stability and Reactivity Reactivity: Not chemically reactive. Chemical stability: Stable under normal ambient and anticipated conditions of use. Possibility of hazardous reactions: Hazardous reactions not anticipated. Conditions to avoid: Avoid all possible sources of ignition. Heat will increase pressure in the storage tank.
PAGE 6
169570 - Propane Page 6/8 Date of Issue: 08-Oct-2013 Status: FINAL _____________________________________________________________________ Propane Target Organs: No systemic or neurotoxic effects were noted in rats exposed to concentrations of propane as high as 12,000 ppm for 28 days. Reproductive Toxicity: No adverse reproductive or developmental effects were observed in rats exposed to propane; no observed adverse effect level = 12,000 ppm.
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169570 - Propane Page 7/8 Date of Issue: 08-Oct-2013 Status: FINAL _____________________________________________________________________ Note: For domestic transportation only, UN1075 may be substituted for the UN number shown as long as the substitution is consistent on package markings, shipping papers, and emergency response information. See 49 CFR 172.102 Special Provision 19. Containers of NON-ODORIZED liquefied petroleum gas must be marked either NON-ODORIZED or NOT ODORIZED as of September 30, 2006.
PAGE 8
169570 - Propane Page 8/8 Date of Issue: 08-Oct-2013 Status: FINAL _____________________________________________________________________ Canada: Canadian Regulations: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS contains all the information required by the Regulations.