Specification

ManualsBrandsBarrette ManualsFencing0.4375 in. x 4 in. x 6 ft. Brown Pressure-Treated Spruce Pine Fir Stockade Gothic Wood Fence Picket

MATERIAL SAFETY DATA SHEET

Wolmanized® Residential Outdoor® Wood

September 1, 2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Identifier: Wolmanized® Residential Outdoor® Wood

General Use: Treated Wood Products

Synonyms: Copper Azole (CA-B) Treated Wood, Copper Azole Treated Wood with Water Repellant,

Copper Azole Treated Wood with Mold Inhibitor, Copper Azole Treated Formaldehyde Bonded

Wood Products.

MANUFACTURER: TELEPHONE NUMBERS:

Barrette Wood Inc 450-357-7000

583 Grand Bernier North

St-Jean-sur-richelieu Qc

Canada J3B 8K1

2. COMPOSITION / INFORMATION ON INGREDIENTS

HAZARDOUS

INGREDIENTS

PERCENT

CAS # EXPOSURE LIMITS (mg/m

)

OSHA-PEL ACGIH-TLV ACGIH-STEL

Basic Copper Carbonate or

Copper Oxide (Both as Cu)

(Dust/Mist)

<3 7440-50-8 1.0 1.0 None

Tebuconazole <1 107534-96-3 None None None

Ethanolamine <1 141-43-5 6.0 7.5 15

Wood Dust

Western Red Cedar

All other Species

>95 N/A

15(total) 5.0 (respirable)

0.5 (inhalable)

1.0 (inhalable)

None

Formaldehyde

<0.1 50-00-0 0.75ppm 0.37 (Ceiling) 2ppm

Ammonia

<1 7664-41-7 50ppm 25ppm 35ppm

Notes:

Actual retention may vary due to differences in wood stock and treatment retention levels.

A state-run OSHA program may have more stringent limits for wood dust and/or PNOR.

Only applies to Plywood Products

Only applies to wood sold in the West Coast and Canadian regions. Ammonia added at 1% to treating

solution at local treating facility.

3. HAZARDS IDENTIFICATION

WARNING! MAY FORM COMBUSTIBLE DUST CONCENTRATIONS IN AIR (DURING PROCESSING)

Inhalation: Airborne treated or untreated wood dust may cause nose, throat or lung irritation. Various species of

untreated wood dust can elicit allergic respiratory response in sensitized persons.

Eye Contact: Treated or untreated wood dust may cause mechanical irritation.

Skin Contact: Handling wood may result in skin exposure to splinters. Prolonged and/or repeated contact with

treated or untreated wood dust may result in mild irritation. Various species of untreated wood dust can elicit allergic

type skin irritation in sensitized persons.

Ingestion: Not anticipated to occur.

Chronic Wood Dust (treated or untreated) Effects: Wood dust, depending on species, may cause dermatitis on

prolonged, repetitive contact; may cause sensitization and/or irritation.

4. FIRST AID MEASURES

Inhalation: Remove from wood dust exposure. If breathing has stopped administer artificial respiration. Seek

medical aid if symptoms persist.

Eye Contact: Gently flush any particles from the eyes with large amounts of water for at least 15 minutes. DO NOT

RUB THE EYES. Seek medical aid if irritation persists.

Summary of content (4 pages)

PAGE 1
MATERIAL SAFETY DATA SHEET Wolmanized® Residential Outdoor® Wood September 1, 2009 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Identifier: Wolmanized® Residential Outdoor® Wood General Use: Treated Wood Products Synonyms: Copper Azole (CA-B) Treated Wood, Copper Azole Treated Wood with Water Repellant, Copper Azole Treated Wood with Mold Inhibitor, Copper Azole Treated Formaldehyde Bonded Wood Products.
PAGE 2
Page 2 of 4 Wolmanized ® Residential Outdoor® Wood September 1, 2009 Skin Contact: Rinse wood dust off with water. DO NOT RUB. Once the skin is free of the wood dust, wash thoroughly with soap and water. Seek medical aid if severe irritation develops. Ingestion: Rinse the victim's mouth out with water. Do not induce vomiting. If symptoms develop, call a physician. 5.
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Page 3 of 4 Wolmanized ® Residential Outdoor® Wood September 1, 2009 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Odor Solubility in Water Physical State pH Light Brown to Green None NA Solid NA Specific Gravity (Water =1) Boiling Point Vapor Density (Air=1) Vapor Pressure Freezing Point NA NA NA NA NA 10. STABILITY AND REACTIVITY Conditions contributing to instability: None known. Incompatibilities: Strong acids, open flame and oxidizers.
PAGE 4
Page 4 of 4 Wolmanized ® Residential Outdoor® Wood September 1, 2009 slow flowing streams or lakes, where current speeds might be as low as 1.0 cm/sec, are 468 times higher than the flows created in these tests. Preliminary modeling indicates that a pier sitting on 25 CA-B treated piling in freshwater flowing at a very low current speed of 2.0cm/sec (typical of many small lakes) would increase the copper concentrations by 0.28 µg Cu/L at pH 6.5.