MSDS

The Clorox Company
1221 Broadway
Oakland, CA 94612
Tel. [phone]
Material Safety
Data Sheet
I Product:
CLOROX
®
AUTOMATIC TOILET BOWL CLEANER I
Description:
WHITE TABLET WITH CHLORINE ODOR
Other Designations Distributor Emergency Telephone Nos.
EPA Reg. No. 5813-65
The Clorox Sales Company
1221 Broadway
Oakland, CA 94612
For Medical Emergencies call:
1-800-446-1014
For Transportation Emergencies, call Chemtrec:
1-800-424-9300
II Health Hazard Data III Hazardous Ingredients
Direct contact with eyes may cause irreversible damage. Harmful if
swallowed. Direct contact with mucous membranes may cause severe
irritation or irreversible damage. Severe skin irritant. Prolonged contact with
skin may cause irreversible damage. Animal ingestion studies in several
species, at high doses, indicate that borates cause reproductive and
developmental effects. A human study of occupational exposure to borate
dust showed no adverse effect on reproduction.
No medical conditions are known to be aggravated by exposure to this
product.
FIRST AID
:
EYE CONTACT
: Flush eyes immediately with water for at least 15 minutes;
then call a physician.
INGESTION
: Rinse mouth, and drink a glassful of water. Do not induce
vomiting. Call a physician.
SKIN CONTACT
: Wash skin immediately with water for 15 minutes; then call
a physician.
INHALATION
: Remove to fresh air. If irritation or breathing problems persist,
call a physician.
Ingredient
Concentration Worker Exposure Limit
1-bromo-3-chloro-5,5-
dimethylhydantoin 51% Not established.
CAS # 16079-88-2
1,3-Dichloro-5,5-
dimethylhydantoin 23.3% 0.2 mg/m
3
- TLV-TWA
a
CAS # 118-52-5 0.4 mg/m
3
- TLV-STEL
b
0.2 mg/m
3
- PEL
c
1,3-Dichloro-5-ethyl-5-
methylhydantoin 9.0% Not established.
CAS # 89415-87-2
Boric Acid
CAS #10043-35-3 10-20% 10 mg/m
3
– TLV-TWA
a
15 mg/m
3
-PEL
c
(total dust)
5 mg/m
3
- PEL
c
(respirable dust)
a
TLV-TWA = ACGIH Threshold Limit Value - Time Weighted Average.
b
TLV-STEL = ACGIH Threshold Limit Value - Short Term Exposure Limit.
c
PEL = OSHA - Permissible Exposure Limit
None of the materials in this product are on the IARC, OSHA, or NTP
carcinogen lists.
IV Special Protection and Precautions V Transportation and Regulatory Data
Hygienic Practices
: Wash hands after direct contact. Do not wear product-
contaminated clothing for prolonged periods.
Engineering Controls
: Not normally required if product us used as directed.
However, if handling of product produces dust, local exhaust may be
necessary.
Personal Protective Equipment
: Wear safety glasses or goggles and rubber
gloves. Respiratory equipment is not normally required if product is used as
directed. However, if handling of product produces dust, respiratory
equipment may be necessary.
DOT Proper Shipping Name
: Consumer Commodity ORM-D.
IMO Proper Shipping Name
: Dangerous goods in limited quantities of Class
5.1.
IATA Proper Shipping Name
: Oxidizing solid, n.o.s., Class 5.1, Packing
Group II.
EPA - SARA Title III/CERCLA
: This product is a hazardous chemical
reportable under Sections 311/312; contains no chemicals regulated under
Section 313; and contains no chemicals which are regulated under Section
304/CERCLA.
VI Spill Procedures/Waste Disposal VII Reactivity Data
Spill Procedures
: Wear appropriate protective gear and respiratory
protection. Sweep up material and place in a compatible container for
disposal. Since material is toxic to fish, do not discharge into lakes, streams,
ponds or public water unless in accordance with NPDES permit.
Waste Disposal
: Dispose of in accordance with all applicable federal, state,
and local regulations.
Reacts with other household chemicals such as acid toilet bowl cleaners, rust
removers, acids, vinegar, and ammonia-containing products to produce
hazardous gases, such as chlorine/bromine and other chlorinated/brominated
compounds. Avoid contact with strong alkalis.
Material is an oxidizer. Avoid contact with readily-oxidizable materials.
Stable under normal use and storage conditions.
VIII Fire and Explosion Data IX Physical Data
Flashpoint:
>200°F
Not flammable or explosive. Decomposes at 165°C. Do not use ABC-type
fire extinguishers with fires involving this product.
Density (a granule) ..........................................................................1.57gr/cc
pH............................................................................................................. NA
©1963, 1991 THE CLOROX COMPANY
DATA SUPPLIED IS FOR USE ONLY IN CONNECTION WITH OCCUPATIONAL SAFETY AND HEALTH DATE PREPARED 1/09