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CloSure Clean

Safety Data Sheet

According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations

Revision Date: 02/26/2016

Date of issue: 10/12/2015

Version: 1.2

02/26/2016 FII-XX-CC EN (English US) 1/13

SECTION 1: IDENTIFICATION

Product Identifier

Product Form: Mixture

Product Name: CloSure Clean

Product Code: CC25

Note: This product, in contact with air or moisture, evolves chlorine dioxide gas. The hazard information for this is contained in

section 2.3 and 3.

Intended Use of the Product

Deodorizer

Name, Address, and Telephone of the Responsible Party

CloSure Clean LLC

P.O. Box 4674

Mooresville, NC 28117

(704)851-8000

www.closureclean.com

Emergency Telephone Number

Emergency Number : US: (800) 424-9300; International: (703) 527-3887 (CHEMTREC)

SECTION 2: HAZARDS IDENTIFICATION

Classification of the Substance or Mixture

GHS-US classification

Comb. Dust

Acute Tox. 4 (Oral)

H302

Acute Tox. 3 (Dermal)

H311

Acute Tox. 4 (Inhalation: dust,mist)

H332

Skin Corr. 1B

H314

Eye Dam. 1

H318

STOT RE 2

H373

Full text of H-phrases: see section 16

Label Elements

GHS-US Labeling

Hazard Pictograms (GHS-US)

GHS05

GHS06

GHS08

Signal Word (GHS-US)

Danger

Hazard Statements (GHS-US)

H232 - May form combustible dust concentrations in air.

H302+H332

- Harmful if swallowed or if inhaled.

H311

- Toxic in contact with skin.

H314

- Causes severe skin burns and eye damage.

H373 - May cause damage to organs (Spleen) through prolonged or repeated exposure.

Precautionary Statements (GHS-US)

P260 - Do not breathe dust, mist.

P264

- Wash hands, forearms, and exposed areas thoroughly after handling.

P270

- Do not eat, drink or smoke when using this product.

P271

- Use only outdoors or in a well-ventilated area.

P280

- Wear eye protection, face protection, protective clothing, protective gloves.

P301+P312

- If swallowed: Call a poison center or doctor if you feel unwell.

P301+P330+P331

- If swallowed: rinse mouth. Do NOT induce vomiting.

P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing.

Summary of content (13 pages)

PAGE 1
CloSure Clean Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Revision Date: 02/26/2016 Date of issue: 10/12/2015 Version: 1.2 SECTION 1: IDENTIFICATION Product Identifier Product Form: Mixture Product Name: CloSure Clean Product Code: CC25 Note: This product, in contact with air or moisture, evolves chlorine dioxide gas. The hazard information for this is contained in section 2.3 and 3.
PAGE 2
CloSure Clean Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Other Hazards Rinse skin with water/shower. P304+P340 - If inhaled: Remove person to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 - Immediately call a poison center or doctor.
PAGE 3
CloSure Clean Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Name Chlorine dioxide Product Identifier (CAS No) 10049-04-4 % 100 Classification (GHS-US) Ox. Gas 1, H270 Compressed gas, H280 Acute Tox. 1 (Inhalation:gas), H330 Skin Corr.
PAGE 4
CloSure Clean Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Reference to Other Sections Refer to section 9 for flammability properties. SECTION 6: ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Do not get in eyes, on skin, or on clothing. Do not breathe dust or fumes. Keep away from heat, sparks, open flames, hot surfaces – No smoking.
PAGE 5
CloSure Clean Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Note: This product, in contact with air or moisture, evolves chlorine dioxide gas. The product is designed to generate chlorine dioxide solution when the pouch is placed in specified amount of water. The product design limits both the amount of gas generated and the rate of release. The exposure limits for this are contained below.
PAGE 6
CloSure Clean Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Yukon Yukon Yukon Yukon Exposure Controls OEL STEL (mg/m³) OEL STEL (ppm) OEL TWA (mg/m³) OEL TWA (ppm) 0.9 mg/m³ 0.3 ppm 0.3 mg/m³ 0.1 ppm Appropriate Engineering Controls: Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Ensure adequate ventilation, especially in confined areas.
PAGE 7
CloSure Clean Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations SECTION 10: STABILITY AND REACTIVITY Reactivity: SODIUM CHLORITE is self-reactive. The trihydrate crystals of sodium chlorite explode on percussion. Sodium chlorite reacts with acids to form spontaneously explosive chlorine dioxide gas (ClO2). If heated above 175 °C, the reaction yields enough heat to become self sustaining.
PAGE 8
CloSure Clean Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Calcium chloride (10043-52-4) LD50 Oral Rat LD50 Dermal Rat LD50 Dermal Rabbit 2301 (1455 - 2781) mg/kg 2630 mg/kg > 5000 mg/kg Sodium chlorite (7758-19-2) IARC Group 3 SECTION 12: ECOLOGICAL INFORMATION Toxicity Ecology - General: Very toxic to aquatic life.
PAGE 9
CloSure Clean Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Pollutant : CORROSIVE SOLIDS, TOXIC, N.O.S. (Sodium chlorite), 8;6.1, II, Marine Pollutant Transport Document Description (DOT) : CORROSIVE SOLIDS, TOXIC, N.O.S. (Sodium chlorite), 8;6.1, II, Marine Pollutant Transport Document Description (TDG) : CORROSIVE SOLIDS, TOXIC, N.O.S. (Sodium chlorite), 8;6.
PAGE 10
CloSure Clean Safety Data Sheet According To Federal Register / Vol. 77, No.
PAGE 11
CloSure Clean Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Dot Vessel Stowage Other Subsidiary Risks (IMDG) Limited Quantities (IMDG) Special Provisions (IMDG) Excepted Quantities (IMDG) IBC Packing Instructions (IMDG) IBC Special Provisions (IMDG) Packing Instructions (IMDG) Tank Instructions (IMDG) Tank Special Provisions (IMDG) Stowage Category (IMDG) EMS-NO. (Fire) MFAG-NO EMS-NO.
PAGE 12
CloSure Clean Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations RTK - U.S. - Massachusetts - Right To Know List U.S. - Minnesota - Chemicals of High Concern RTK - U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - California - Safer Consumer Products - Initial List of Candidate Chemicals and Chemical Groups RTK - U.S. - Pennsylvania - RTK (Right to Know) List U.S. - Texas - Effects Screening Levels - Long Term U.S.
PAGE 13
CloSure Clean Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations ------------------------------------------------------------------------------------------------------------------------- Acute Tox. 4 (Inhalation:dust,mist) Acute Tox. 4 (Oral) Aquatic Acute 1 Aquatic Chronic 3 Comb. Dust Eye Dam. 1 Eye Irrit. 2A Ox. Sol. 1 Skin Corr. 1B STOT RE 2 Comb.