MSDS

ManualsBrandsCLR ManualsCleaning28 oz. Calcium, Lime and Rust Remover

SAFETY DATA SHEET

521213 Page 1 of 6 Date issued 12-December-2013

1 - PRODUCT AND COMPANY IDENTIFICATION

SDS ID: 521213

Product Name

CLR Calcium, Lime & Rust Remover

Product Use Aqueous Acidic Cleaner for Removal of Calcium, Lime, and Rust from Hard

Surfaces Retail Package: [28 fl. oz., 42 fl. oz., and 128 fl. oz. (one gallon)}

CAS# Proprietary Mixture

Restrictions on Use Incompatible with strong oxidizing agents, metals (except stainless steel, chrome),

acids, bases, and bleach.

Manufacturer: Jelmar, LLC Emergency Phone Number: 1(800) 323-5497 (USA)

Address: 5550 W. Touhy Ave. Monday – Friday 8:30 A.M. – 4:30 P.M. CST

Skokie, IL 60077 Emergency 24 hour Contact: Chemtrec 1(800) 424-9300

2 – HAZARDS IDENTIFICATION

Emergency Overview: WARNING: EYE IRRITATANT. GHS Toxicity Category 2A Causes eye

irritation and possible SKIN IRRITATANT GHS Category 3 – on sensitive skin.DO NOT get in

eyes, on skin or clothing. DO NOT mix with bleach or other household chemicals as harmful

fumes may result. DO NOT ingest. DO NOT breathe vapor or mist. Use in well ventilated

areas. Keep container closed when not in use.

KEEP OUT OF REACH OF CHILDREN

Potential Short Term Health Effects

Routes of Exposure Eyes, Skin, Inhalation, Ingestion.

Eyes Irritant

Avoid eye contact

Effects may vary depending on length of exposure, solution concentration

Skin Irritant. Prolonged contact may cause dermatitis, and itching.

Inhalation No adverse effects expected under typical use conditions.

Ingestion Oral burns, vomiting, and gastrointestinal disturbance.

Target organs Eyes. Skin.

SECTION 3 - COMPOSITION /INFORMATION ON INGREDIENTS

Component CAS# OSHA HAZARD % by Weight

1. Lactic Acid 79-33-4 YES 12.00-18.00

2. Lauramine Oxide 1643-20-5 YES 1.50-3.25

SECTION 4 – FIRST AID MEASURES

Summary of content (6 pages)

PAGE 1
SAFETY DATA SHEET 1 - PRODUCT AND COMPANY IDENTIFICATION SDS ID: 521213 Product Name Product Use CLR Calcium, Lime & Rust Remover Aqueous Acidic Cleaner for Removal of Calcium, Lime, and Rust from Hard Surfaces Retail Package: [28 fl. oz., 42 fl. oz., and 128 fl. oz. (one gallon)} CAS# Proprietary Mixture Restrictions on Use Incompatible with strong oxidizing agents, metals (except stainless steel, chrome), acids, bases, and bleach. Manufacturer: Address: Jelmar, LLC 5550 W. Touhy Ave.
PAGE 2
SAFETY DATA SHEET EYE CONTACT: In case of eye contact, immediately rinse eye thoroughly with plenty of water. Remove contact lenses, and continue rinsing for at least 15 minutes. If irritation persists, get medical attention. SKIN CONTACT: Can be irritating to skin, prolonged contact can be more severe, no adverse effects during normal usage. In case of skin contact, rinse area for at least 15 minutes. Remove contaminated clothing and shoes, wash thoroughly before reuse.
PAGE 3
SAFETY DATA SHEET SECTION 8 – EXPOSURE CONTROLS / PERSONAL PROTECTION VENTILATION REQUIREMENT: Avoid prolonged breathing mists or dusts of this product. Use with adequate ventilation. Do not use in closed or confined spaces. RESPIRATORY PROTECTION: None required during normal household use. EYE PROTECTION: Not required during normal household usage. Do not wear contact lenses. Emergency responders should wear full eye and face protection. SKIN PROTECTION: Rubber gloves with protective cuff.
PAGE 4
SAFETY DATA SHEET ECOTOXICOLOGICAL INFORMATION: LACTIC ACID: Persistence / degradability Readily biodegradable, according to appropriate OECD test. Biochemical oxygen demand (BOD)5 = 0.45 mg O2 /mg Biochemical oxygen demand (BOD)20= 0.60 mg O2/mg Chemical oxygen demand (COD) =0.90 mg O2 /mg Bioaccumulation None. Ecotoxicity EC50/48h/Daphnia = 240mg/l LC50/48h/Fish = 320 mg/l EC50/Algae = 3500 mg/l(neutral) No data available. GLUCONIC ACID: Fish 96-h LC50 > 1000.0 mg/L Daphnid 48-h LC50 > 1000.
PAGE 5
SAFETY DATA SHEET Rate Constant Atmospheric Half-life Method 4.97E-11 cm3/s 2.6 h Estimated. OECD Biodegradation Tests: Biodegradation Exposure Time Method 91 % 28 d OECD 301E Test 96 % 28 d OECD 302B Test Theoretical Oxygen Demand: 2.35 mg/mg ECOTOXICITY Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
PAGE 6
SAFETY DATA SHEET IMMEDIATE (ACUTE) HEALTH HAZARARD: DELAYED (CHRONIC) HEALTH HAZARD: FIRE HAZARD: SUDDEN RELEASE OF PRESSURE: REACTIVE HAZARD: YES NO NO NO NO SARA SECTIONS 302/304/313/HAP: NO INTERNATIONAL CHEMICAL INVENTORY STATUS: EUROPEAN UNION (EINECS) YES JAPAN (METI) YES AUSTRALIA (ACIS) YES KOREA (KECL) YES CANADA (DSL) YES CANADA (NDSL) NO PHILIPPINES YES STATES RIGHT TO KNOW: California, New Jersey, Pennsylvania, Minnesota, Massachusetts, and Wisconsin.