SDS

ManualsBrandsCrossbow ManualsOutdoors32 oz. Concentrate Weed and Brush Killer

Product name: CROSSBOW™ Herbicide

Issue Date: 05/20/2015

Print Date: 05/22/2015

Southern Agricultural Insecticides, Inc. encourages and expects you to read and understand the

entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions iden-

tied in this document unless your use conditions would necessitate other appropriate methods or actions.

1. IDENTIFICATION

Product name: CROSSBOW™ Herbicide

Recommended use of the chemical and restrictions on use

Identied uses: End use herbicide product

COMPANY IDENTIFICATION

Southern Agricultural Insecticides, Inc.

P.O. Box 218

Palmetto, FL 34220

United States

Customer Information Number: 941-722-3285

sales@southernag.com

EMERGENCY TELEPHONE NUMBER

Chemtrec (800) 424-9300 (24 hour transportation spill response)

Medical: Rocky Mountain Poison Control Center (866) 673-6671 (24hrs)

2. HAZARDS IDENTIFICATION

Hazard classication

This material is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29CFR 1910.1200.

Flammable liquids - Category 4

Acute toxicity - Category 4 - Oral

Skin sensitisation - Sub-category 1B

Aspiration hazard - Category 1

Label elements

Hazard pictograms

Signal word: DANGER!

Hazards

Combustible liquid.

Harmful if swallowed.

May be fatal if swallowed and enters airways.

May cause an allergic skin reaction.

Precautionary statements

Prevention

Keep away from heat/sparks/open ames/hot surfaces. - No smoking.

Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.

CROSSBOW

™

SAFETY DATA SHEET

Page 1 of 12

Summary of content (12 pages)

PAGE 1
CROSSBOW™ SAFETY DATA SHEET Product name: CROSSBOW™ Herbicide Issue Date: 05/20/2015 Print Date: 05/22/2015 Southern Agricultural Insecticides, Inc. encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions. 1.
PAGE 2
Wash skin thoroughly after handling. Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/ eye protection/ face protection. Response IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. IF ON SKIN: Wash with plenty of soap and water. Do NOT induce vomiting. If skin irritation or rash occurs: Get medical advice/ attention. Wash contaminated clothing before reuse.
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Most important symptoms and effects, both acute and delayed: Aside from the information found under Description of first aid measures (above) and Indication of immediate medical attention and special treatment needed (below), any additional important symptoms and effects are described in Section 11: Toxicology Information. Indication of any immediate medical attention and special treatment needed Notes to physician: Skin contact may aggravate preexisting dermatitis.
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7. HANDLING AND STORAGE Precautions for safe handling: Keep out of reach of children. Keep away from heat, sparks and flame. Containers, even those that have been emptied, can contain vapors. Do not cut, drill, grind, weld, or perform similar operations on or near empty containers. Avoid contact with eyes, skin, and clothing. Do not swallow. Avoid breathing vapor or mist. Wash thoroughly after handling. Keep container closed. Use with adequate ventilation.
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Odor Threshold pH Melting point/range Freezing point Boiling point Flash point Evaporation Rate (Butyl Acetate = 1) Flammability (solid, gas) Lower explosion limit Upper explosion limit Vapor Pressure Relative Vapor Density (air = 1) Relative Density (water = 1) Water solubility Partition coefficient: n-octanol/water Auto-ignition temperature Decomposition temperature Dynamic Viscosity Kinematic Viscosity Explosive properties Oxidizing properties Liqui
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Acute inhalation toxicity Prolonged excessive exposure to mist may cause adverse effects. Excessive exposure may cause irritation to upper respiratory tract (nose and throat) and lungs. Observations in animals include: Lethargy. As product: LC50, Rat, male and female, 4 Hour, Aerosol, > 5.19 mg/l Skin corrosion/irritation Brief contact is essentially nonirritating to skin. Prolonged contact may cause moderate skin irritation with local redness. May cause drying and flaking of the skin.
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For the minor component(s): Has caused birth defects in laboratory animals only at doses toxic to the mother. Has been toxic to the fetus in laboratory animals at doses toxic to the mother. These concentrations exceed relevant human dose levels. Reproductive toxicity For similar active ingredient(s). 2,4-Dichlorophenoxyacetic acid. In laboratory animals, excessive doses toxic to the parent animals caused decreased weight and survival of offspring. For similar active ingredient(s). Triclopyr.
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Acute toxicity to algae/aquatic plants ErC50, Pseudokirchneriella subcapitata (green algae), 96 Hour, Growth rate inhibition, > 3.00 mg/l, OECD Test Guideline 201 EbC50, diatom Navicula sp., 120 Hour, Biomass, 0.193 mg/l EbC50, Lemna gibba, Biomass, 2.2 mg/l Chronic toxicity to fish NOEC, Rainbow trout (Oncorhynchus mykiss), 0.0263 mg/l Chronic toxicity to aquatic invertebrates NOEC, Daphnia magna (Water flea), 21 d, number of offspring, 1.
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Triclopyr-2-butoxyethyl ester Biodegradability: Chemical degradation (hydrolysis) is expected in the environment. Material is expected to biodegrade very slowly (in the environment). Fails to pass OECD/EEC tests for ready biodegradability. 10-day Window: Fail Biodegradation: 18 % Exposure time: 28 d Method: OECD Test Guideline 301B or Equivalent Theoretical Oxygen Demand: 1.39 mg/mg Biological oxygen demand (BOD) Incubation Time BOD 0.004 mg/mg Stability in Water (1/2-life) Hydrolysis, half-life, 8.
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Incubation Time 5d 10 d 20 d BOD 26 - 70 % 75 - 81 % 86 - 87 % Photodegradation Test Type: Half-life (indirect photolysis) Sensitizer: OH radicals Atmospheric half-life: 9.7 Hour Method: Estimated. Balance Biodegradability: No relevant data found. Bioaccumulative potential 2,4-Dichlorophenoxyacetic acid, butoxyethyl ester Bioaccumulation: Bioconcentration potential is moderate (BCF between 100 and 3000 or Log Pow between 3 and 5). Partition coefficient: n-octanol/water(log Pow): 4.
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13. DISPOSAL CONSIDERATIONS Disposal methods: If wastes and/or containers cannot be disposed of according to the product label directions, disposal of this material must be in accordance with your local or area regulatory authorities. This information presented below only applies to the material as supplied. The identification based on characteristic(s) or listing may not apply if the material has been used or otherwise contaminated.
PAGE 12
Pennsylvania (Worker and Community Right-To-Know Act): Pennsylvania Hazardous Substances List and/or Pennsylvania Environmental Hazardous Substance List: The following product components are cited in the Pennsylvania Hazardous Substance List and/or the Pennsylvania Environmental Substance List, and are present at levels which require reporting.