SDS

ManualsBrandsCrossbow ManualsOutdoors32 oz. Concentrate Weed and Brush Killer

Product name: CROSSBOW™ Herbicide

Southern Agricultural Insecticides, Inc. encourages and expects you to read and understand the entire (M)SDS, as there

is important information throughout the document. We expect you to follow the precautions identied in this document un-

less your use conditions would necessitate other appropriate methods or actions.

1. IDENTIFICATION

Product name: CROSSBOW™ Herbicide

Recommended use of the chemical and restrictions on use

Identied uses: End use herbicide product

COMPANY IDENTIFICATION

Southern Agricultural Insecticides, Inc.

P.O. Box 218

Palmetto, FL 34220

United States

Customer Information Number: 941-722-3285

sales@southernag.com

EMERGENCY TELEPHONE NUMBER

Chemtrec (800) 424-9300 (24 hour transportation spill response)

Medical: Rocky Mountain Poison Control Center (866) 673-6671 (24hrs)

2. HAZARDS IDENTIFICATION

Hazard classication

OSHA Regulatory Status

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Flammable liquids - Category 4 - (H227)

Acute toxicity - Oral - Category 4 - (H302)

Skin sensitisation - Sub-category 1B - (H317)

Aspiration toxicity - Category 1 - (H304)

Label elements

Hazard pictograms

Signal word: DANGER!

Hazards

H302 - Harmful if swallowed

H304 - May be fatal if swallowed and enters airways

H317 - May cause an allergic skin reaction

H351 - Suspected of causing cancer

H227 - Combustible liquid

CROSSBOW

™

SAFETY DATA SHEET

Page 1 of 13

Summary of content (13 pages)

PAGE 1
CROSSBOW™ SAFETY DATA SHEET Product name: CROSSBOW™ Herbicide Southern Agricultural Insecticides, Inc. encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions. 1.
PAGE 2
Precautionary statements Prevention P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P281 - Use personal protective equipment as required P264 - Wash face, hands and any exposed skin thoroughly after handling P270 - Do not eat, drink or smoke when using this product P261 - Avoid breathing dust/fume/gas/mist/vapors/spray P272 - Contaminated work clothing should not be allowed out of the workplace P280 - Wear protective gloves Precau
PAGE 3
Eye contact: Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes. Get medical attention. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. Ingestion: Call a poison control center or doctor for treatment advice. Have person sip a glass of water if able to swallow. Do NOT induce vomiting unless directed to do so by medical personnel.
PAGE 4
6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures: Isolate area. Keep unnecessary and unprotected personnel from entering the area. Refer to section 7, Handling, for additional precautionary measures. Keep upwind of spill. Ventilate area of leak or spill. No smoking in area. Use appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection.
PAGE 5
the instructions/specifications provided by the glove supplier. Other protection: Use protective clothing chemically resistant to this material. Selection of specific items such as face shield, boots, apron, or full body suit will depend on the task. Respiratory protection: Respiratory protection should be worn when there is a potential to exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, use an approved respirator.
PAGE 6
Toxic gases are released during decomposition. Decomposition products can include trace amounts of: Phosgene. 11. TOXICOLOGICAL INFORMATION Toxicological information appears in this section when such data is available. Acute toxicity Acute oral toxicity Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal handling operations are not likely to cause injury; however, swallowing larger amounts may cause injury.
PAGE 7
Contains component(s) which have been reported to cause effects on the following organs in animals: Blood. Spleen. Kindey. Liver. Carcinogenicity For the solvent(s): In a lifetime animal dermal carcinogenicity study, an increased incidence of skin tumors was observed when kerosene was applied at doses that also produced skin irritation. This response was similar to that produced in skin by other types of chronic chemical/physical irritation.
PAGE 8
Equivalent Acute toxicity to aquatic invertebrates LC50, Daphnia magna (Water flea), static test, 48 Hour, 7.2 - 33 mg/l, OECD Test Guideline 202 or Equivalent Acute toxicity to algae/aquatic plants EbC50, Pseudokirchneriella subcapitata (green algae), static test, 5 d, Biomass, 25 mg/l, OECD Test Guideline 201 or Equivalent EbC50, Lemna minor (duckweed), static test, 5 d, Biomass, 0.576 mg/l, OECD 221.
PAGE 9
Ethylhexanol Acute toxicity to fish Material is slightly toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and 100 mg/L in the most sensitive species tested). LC50, Oncorhynchus mykiss (rainbow trout), 96 Hour, 32 - 37 mg/l Acute toxicity to aquatic invertebrates LC50, Daphnia magna (Water flea), 48 Hour, 35.
PAGE 10
d 39.700 % 20 d 58.600 % Photodegradation Test Type: Half-life (indirect photolysis) Sensitizer: OH radicals Atmospheric half-life: 0.767 d Method: Estimated. Ethylhexanol Biodegradability: Material is readily biodegradable. Passes OECD test(s) for ready biodegradability. Material is ultimately biodegradable (reaches > 70% mineralization in OECD test(s) for inherent biodegradability).
PAGE 11
2-Ethylhexanol Bioaccumulation: Bioconcentration potential is moderate (BCF between 100 and 3000 or Log Pow between 3 and 5). Partition coefficient: n-octanol/water(log Pow): 3.1 Measured Balance Bioaccumulation: No relevant data found. Mobility in soil 2,4-Dichlorophenoxyacetic acid, butoxyethyl ester No relevant data found. Triclopyr-2-butoxyethyl ester Calculation of meaningful sorption data was not possible due to very rapid degradation in the soil. For the degradation product: Triclopyr.
PAGE 12
15. REGULATORY INFORMATION OSHA Hazard Communication Standard This product is a “Hazardous Chemical” as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.
PAGE 13
SKIN, DSEN, BEI TWA Absorbed via Skin, Skin Sensitizer, Biological Exposure Indice Time weighted average Southern Agricultural Insecticides, Inc. urges each customer or recipient of this SDS study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. The information herein is provided in good faith and believed to be accurate as of the effective date shown above.