SDS

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Lithium-ion Battery Pack

Page 1 of 14

SDS Preparation Date (mm/dd/yyyy): 03/13/2019

SAFETY DATA SHEET

SECTION 1. IDENTIFICATION

Product identifier used on the label

Lithium-ion Battery Pack

Product Code(s) :

MTD48RB30/MTD48RB23

Lithium battery packs for lawnmowers

No restrictions on use known.

Recommended use of the chemical and restrictions on use

Chemical family :

Article

Privada Murrieta S/N

Parque Industrial San Ramón

C.P. 84092

Nogales, Sonora, México

Name, address, and telephone number of the manufacturer:

MTD Consumer Products México S.A. de C.V.

631 31 42991

Manufacturer's Telephone #

MTD Southwest Inc.

9235 S McKemy St.

Tempe, AZ, USA

85284

Name, address, and telephone number of the supplier:

(480) 961-1002 (8:00 am to 5:00 pm)

Supplier's Telephone #

24 Hr. Emergency Tel #

INFOTRAC: (800) 535-5053 (Within Continental US and Canada); (352) 323-3500

(International)

SECTION 2. HAZARDS IDENTIFICATION

Classification of the chemical

Lithium ion battery contained in protective black plastic casing. No odor.

Most important hazards:

This product is an article, and is not hazardous in the form in which it is shipped by the manufacturer. However, if the

battery is misused or damaged, it will present a physical and health hazard. If the battery is damaged or misused (e.g. is

short-circuited; is exposed to moisture), hazardous properties may include the following:

When exposed to heat, when short circuited, or when exposed to incompatible materials, the battery may rupture and

release hazardous substances. These substances can explode and burn.

Causes skin and eye irritation. Harmful if inhaled. Inhalation of mists can cause severe respiratory irritation. Contains

material that may cause adverse reproductive effects. Contains material which can cause cancer. Occupational exposure

to the substance or mixture may cause adverse effects. For further information, please refer to section 11 of the SDS.

An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Avoid release to the

environment. See Section 12 for more environmental information.

If the battery is damaged or misused (e.g. is short-circuited; is exposed to moisture), the product will be classified as

hazardous under U.S. OSHA regulations (29CFR 1910.1200) (Hazcom 2012) and Canadian WHMIS regulations

(Hazardous Products Regulations) (WHMIS 2015). Classification:

Acute toxicity, inhalation - Category 4

Skin corrosion/irritation - Category 2

Eye damage/irritation - Category 2

Skin sensitization - Category 1A

Carcinogen - Category 1

Specific Target organ toxicity, repeated exposure- Category 1

The below U.S. OSHA Hazcom 2012 and Canadian WHMIS WHMIS 2015 labeling information, is being provided for

informational purposes, should users be exposed to damaged batteries, or if the batteries are misused.

Label elements

Hazard pictogram(s)

Summary of content (14 pages)

PAGE 1
Lithium-ion Battery Pack Page 1 of 14 SDS Preparation Date (mm/dd/yyyy): 03/13/2019 SAFETY DATA SHEET SECTION 1. IDENTIFICATION Product identifier used on the label : Lithium-ion Battery Pack Product Code(s) : MTD48RB30/MTD48RB23 Recommended use of the chemical and restrictions on use Chemical family : Lithium battery packs for lawnmowers No restrictions on use known. : Article Name, address, and telephone number of the manufacturer: MTD Consumer Products México S.A. de C.V.
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Lithium-ion Battery Pack Page 2 of 14 SDS Preparation Date (mm/dd/yyyy): 03/13/2019 SAFETY DATA SHEET Signal Word DANGER! Hazard statement(s) Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction. May cause cancer. Causes damage to organs through prolonged or repeated exposure. Precautionary statement(s) Obtain special instructions before use. Do not handle until all safety precautions have been read and understood.
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Lithium-ion Battery Pack Page 3 of 14 SDS Preparation Date (mm/dd/yyyy): 03/13/2019 SAFETY DATA SHEET Carbonate, methyl ethyl Carbonic acid, ethyl methyl ester 623-53-0 1.0 - 5.0 Not available. 21324-40-3 1.0 - 5.0 Furnace black Lamp black Thermal black 1333-86-4 1.0 - 5.0 Lithium hexafluorophosphate Carbon black The exact concentrations of the above listed chemicals are being withheld as a trade secret. SECTION 4.
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Lithium-ion Battery Pack SDS Preparation Date (mm/dd/yyyy): 03/13/2019 Page 4 of 14 SAFETY DATA SHEET Suitable extinguishing media : Fighting a fire that contains lithium batteries requires: 1. Removing external electrical power from device (if applicable). 2. Extinguishing the fire, and 3. Cooling of the remaining cells to stop the thermal runaway. Fires can be controlled by blanketing the fire with a Class D dry extinguisher or by ringing the fire with a dam of dry sand.
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Lithium-ion Battery Pack Page 5 of 14 SDS Preparation Date (mm/dd/yyyy): 03/13/2019 SAFETY DATA SHEET : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. When used correctly, these batteries provide a safe source of power. When exposed to heat, when short circuited, or when exposed to incompatible materials, the battery may rupture and release hazardous substances. These substances can explode and burn.
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Lithium-ion Battery Pack SDS Preparation Date (mm/dd/yyyy): 03/13/2019 Page 6 of 14 SAFETY DATA SHEET : No special ventilation requirements under normal use. Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. In case of insufficient ventilation wear suitable respiratory equipment. Respiratory protection : None required under normal conditions.
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Lithium-ion Battery Pack SDS Preparation Date (mm/dd/yyyy): 03/13/2019 Page 7 of 14 SAFETY DATA SHEET Absolute pressure of container : N/Ap Flame projection length : N/Ap Other physical/chemical comments : Model # - MTD48RB30 Nominal capacity-32.5Ah Rated capacity-30 Ah Wh-1,638Wh (number of cell=182) Model# - MTD48RB23 Nominal capacity-25 Ah Rated capacity- 23Ah Wh-1,260Wh (number of cell=140) SECTION 10.
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Lithium-ion Battery Pack SDS Preparation Date (mm/dd/yyyy): 03/13/2019 Page 8 of 14 SAFETY DATA SHEET : None expected, when used as intended. If the battery is damaged or misused (e.g. is short-circuited; is exposed to moisture), hazardous properties may include the following: Causes serious eye irritation. Symptoms may include severe pain, tearing, redness, swelling and blurred vision. Potential Chronic Health Effects : Causes damage to organs through prolonged or repeated exposure.
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Lithium-ion Battery Pack Page 9 of 14 SDS Preparation Date (mm/dd/yyyy): 03/13/2019 SAFETY DATA SHEET LC50(4hr) Chemical name inh, rat N/Av N/Av > 64.4 mg/L (dust) > 10 000 mg/kg N/Av N/Av 98 600 mg/kg N/Av > 5.11 mg/L (dust) (No mortality) > 2500 mg/kg > 2000 mg/kg Iron Copper (Rabbit, dermal) (Oral, rat) N/Av Lithium nickel oxide (LiNiO2) Graphite LD50 Carbonic acid, dimethyl ester Aluminum >5.36 mg/L 5000 mg/kg >2000 mg/kg > 2.
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Lithium-ion Battery Pack Page 10 of 14 SDS Preparation Date (mm/dd/yyyy): 03/13/2019 SAFETY DATA SHEET Persistence and degradability : No data is available on the product itself. Bioaccumulation potential : No data is available on the product itself. See the following data for ingredient information. Partition coefficient n-octanol/water (log Kow) Components Carbonic acid, dimethyl ester (CAS 616-38-6) Carbonate, methyl ethyl (CAS 623-53-0) Bioconcentration factor (BCF) 0.354 3.2 0.
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Lithium-ion Battery Pack Page 11 of 14 SDS Preparation Date (mm/dd/yyyy): 03/13/2019 SAFETY DATA SHEET SECTION 14. TRANSPORT INFORMATION Regulatory Information UN Number UN proper shipping name Packing Group Label 49CFR/DOT UN3480 49CFR/DOT Additional information If the battery is packaged with the equipment, then it would ship as Lithium ion batteries packed with or contained in equipment, UN3481. Refer to 49 CFR section 173.185 for additional information.
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Lithium-ion Battery Pack Page 12 of 14 SDS Preparation Date (mm/dd/yyyy): 03/13/2019 SAFETY DATA SHEET Ingredients CAS # CERCLA TSCA Reportable Inventory Quantity(RQ) (40 CFR 117.302): SARA TITLE III: Sec. 302, Extremely Hazardous Substance, 40 CFR 355: SARA TITLE III: Sec. 313, 40 CFR 372, Specific Toxic Chemical Toxic Chemical de minimus Concentration Lithium nickel oxide (LiNiO2) Graphite 12031-65-1 Yes N/Ap N/Av No N/Ap 7782-42-5 Yes None. None. No N/Ap Iron 7439-89-6 Yes None.
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Lithium-ion Battery Pack Page 13 of 14 SDS Preparation Date (mm/dd/yyyy): 03/13/2019 SAFETY DATA SHEET International Information: Components listed below are present on the following International Inventory list: CAS # European EINECs Australia AICS Philippines PICCS Japan ENCS Korea KECI/KECL China IECSC NewZealand IOC Lithium nickel oxide (LiNiO2) Graphite 12031-65-1 N/Av N/Av N/Av (1)-1235 2002-3-2046 N/Av N/Av 7782-42-5 231-955-3 Present Present Not listed KE-18101 Present Not
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Lithium-ion Battery Pack SDS Preparation Date (mm/dd/yyyy): 03/13/2019 Page 14 of 14 SAFETY DATA SHEET MN: Minnesota N/Ap: Not Applicable N/Av: Not Available NIOSH: National Institute of Occupational Safety and Health NJ: New Jersey NOEC: No observable effect concentration NTP: National Toxicology Program OECD: Organisation for Economic Co-operation and Development OSHA: Occupational Safety and Health Administration PA: Pennsylvania PEL: Permissible exposure limit PICCS: Philippine Inventory of Chemicals