SDS

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Product Safety Data Sheet (PSDS)

The battery products referenced in this PSDS document are consumer products. Batteries are considered “articles” under the Global Harmonized

System and are exempted from the GHS labeling and SDS classification criteria. This PSDS document is provided as service in response to

requests for information on battery use, safety and regulatory compliance.

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SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

Product Name: DURACELL LITHIUM MANGANESE DIOXIDE COIN CELLS

Product Identification: Lithium Manganese Dioxide Coin Cells – (lithium metal battery)

Duracell Designations: DL1216; DL1616; DL1620; DL1632; DL2016; DL2025; DL2032; DL2430; DL2450

Product Use: Energy Source

PSDS Date of Preparation: April 24, 2009 Reaffirmed: 4/08/2011; Updated: December 11, 2014

Document ID: Lithium Coin-NA

Company Identification

US Office

Canadian Office

Duracell, a P&G business

Berkshire Corporate Park

14 Research Drive

Bethel, CT USA 06401

(203) 796-4000

Duracell, a P&G business

4711Yonge Street

Toronto, Ontario

Canada M2N 6K8

(416) 730-4711

SECTION 2: HAZARDS IDENTIFICATION

Physical Appearance: Coin cells.

EMERGENCY OVERVIEW

CAUTION: For information on treatment, call the NATIONAL BUTTON BATTERY INGESTION HOTLINE collect,

day or night, at (202) 625-3333. Ingestion may lead to serious injury or death. Battery can explode or leak if heated,

disassembled, shorted, recharged, exposed to fire or high temperature or inserted incorrectly. Keep in original package

until ready to use. Do not carry batteries loose in your pocket or purse. Keep batteries away from children. If swallowed,

consult a physician at once. Under certain misuse conditions and by abusively opening the battery, exposed lithium can

react with water or moisture in the air causing potential thermal burns or fire.

Potential Health Effects:

The chemicals and metals in this product are contained in a sealed can. Exposure to the contents will not occur unless

the battery leaks, is exposed to high temperatures or is mechanically, physically, or electrically abused.

Eye Contact: Contact with battery contents may cause irritation.

Skin Contact: Contact with battery contents may cause irritation.

Inhalation: Inhalation of vapors or fumes released due to heat or a large number of leaking batteries may cause

respiratory and eye irritation.

Ingestion: Seek immediate medical advice. Batteries lodged in the esophagus should be removed immediately since

leakage, caustic burns and perforation can occur as soon as two hours after ingestion. Irritation to the internal/external

mouth areas, may occur following exposure to a leaking battery.

Summary of content (6 pages)

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Product Safety Data Sheet (PSDS) The battery products referenced in this PSDS document are consumer products. Batteries are considered “articles” under the Global Harmonized System and are exempted from the GHS labeling and SDS classification criteria. This PSDS document is provided as service in response to requests for information on battery use, safety and regulatory compliance.
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SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Manganese Dioxide Propylene Carbonate Lithium Graphite, synthetic 1,2-Dimethoxyethane Lithium Perchlorate CAS Number 1313-13-9 108-32-7 7439-93-2 7440-44-0 110-71-4 7791-03-9 Amount 65-75% 10-15% 5-10% 5-10% 1-10% <1.5% SECTION 4: FIRST AID MEASURES Eye Contact: If battery is leaking and material contacts the eye, flush thoroughly with copious amounts of running water for 30 minutes. Seek immediate medical attention.
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ventilation. Carefully collect batteries and place in an appropriate container for disposal. Remove spilled liquid with absorbent and contain for disposal. SECTION 7: HANDLING AND STORAGE Avoid mechanical or electrical abuse. DO NOT short circuit or install incorrectly. Batteries may explode, pyrolize or vent if disassembled, crushed, recharged or exposed to high temperatures. Install batteries in accordance with equipment instructions. Replace all batteries in equipment at the same time.
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SECTION 11: TOXICOLOGICAL INFORMATION Acute Toxicity Data: Manganese Dioxide: LD50 oral rat >3478 mg/kg Propylene Carbonate: LD50 oral rat 29100 uL/kg; LD50 dermal rabbit >20 mL/kg; LC50 inhalation rat >5 g/m3 1,2-Dimethoxyethane: LDLo oral rat 1000 mg/kg, LCLo inhalation rat 63 g/m3/6 hr Chronic Effects: The chemicals in this product are contained in a sealed can and exposure does not occur during normal handling and use. No chronic effects would be expected from handling a leaking battery.
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SECTION 14: TRANSPORT INFORMATION Emergency Phone Number: CHEMTREC 24-Hour Emergency Response Hotline +703-527-3887 (United States of America) The information in this section is provided for informational purposes only. DURACELL lithium metal batteries are produced and delivered in accordance with IATA 56th ICAO, IMO and US DOT Regulations.
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SECTION 15: REGULATORY INFORMATION United States OSHA Status: While the finished product(s) is considered an article and not covered by the OSHA Hazard Communication Standard, 29 CFR 1910.1200, this PSDS contains valuable information critical to the safe handling and proper use of the product". EPA TSCA Status: All intentionally-added components of this product are listed on the US TSCA Inventory.