Safety data sheet

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ProductSafetyDataSheet(PSDS)

LithiumHPLEU

Page1of6

SECTION1:IDENTIFICATIONOFTHESUBSTANCE/PREPARATIONANDOFTHECOMPANY/UNDERTAKING

ProductName:DURACELLLITHIUMMANGANESEDIOXIDEBATTERIESANDCELLS



ProductUse:EnergySource

PSDSDateofPreparation:November29,2012(replacesApril20,2009)

CompanyIdentification:



EUROPEANOFFICE     USOffice

Procter&Gamble

SwitzerlandSARL

RoutedeSaint‐Georges47

1213Petit‐Lancy,1,Geneva,

Telephone:+41‐58‐004‐6111

 Duracell,a P&Gbrand

BerkshireCorporatePark

Bethel,CT06801USA

Telephone:203‐796‐4000

SECTION2:HAZARDSIDENTIFICATION

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TheseproductsareclassifiedasArticlesunderREAC HandarenotsubjecttotherequirementsforInformationin

theSupplyChain(SafetyDataSheetsandLabels).Whilebatteriesmayreleasehazardoussubstancesifdamaged,

thisisnotanintendedreleaseasdefinedunderREACH.Batteriesarenotclassifiedashazardous

undertheCLP.



Thefollowinginformationisprovidedtoassistinthesafeuseofourproducts.



CAUTION:Batterycanexplodeorleakifheated,disassembled,shorted,recharged,exposedtofireorhigh

temperatureorinsertedincorrectly.Keepinoriginalpackageuntilreadytouse.Donotcarrybatteriesloose

inyour

pocketorpurse.Keepbatteriesawayfromchildren.Ifswallowed,consultaphysicianatonce.Undercertainmisuse

conditionsandbyabusivelyopeningthebattery,exposedlithiumcanreactwithwaterormoistureintheaircausing

potentialthermalburnsorfire.

Identity:LithiumBatteriesandCells(HPL)

Description:ConsumerProduct

Size/Designation Voltage

IEC

Designation

LithiumContent (g)

perCell/Battery

CR‐V3 3 CR‐V3 1.4g(Battery)

123/123A 3 CR17345 0.55g(Cell)

223/223A 6 CR‐P2 1.1g(Battery)

245 6 2CR5 1.1g(Battery)

CR2 3 CR17355 0.3g(Cell)

28L 6 2CR13252 .12g(Battery)

1/3N 3 CR1108 0.06g(Cell)

PL123 3 CR17345 0.55g(Cell)

DL1604 90.9g(Battery)

RepresentativeProductImage/

Packaging

Summary of content (6 pages)

PAGE 1
Product Safety Data Sheet (PSDS) SECTION 1: IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product Name: DURACELL LITHIUM MANGANESE DIOXIDE BATTERIES AND CELLS Identity: Lithium Batteries and Cells (HPL) Description: Consumer Product Size/Designation Voltage CR‐V3 123/123A 223/223A 245 CR2 28L 1/3N PL123 DL1604 3 3 6 6 3 6 3 3 9 IEC Designation CR‐V3 CR17345 CR‐P2 2CR5 CR17355 2CR13252 CR1108 CR17345 Lithium Content (g) per Cell/Battery 1.4g (Battery) 0.55g (Cell) 1.
PAGE 2
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS Number EINECS Number 1,2‐Dimethoxyethane* 110‐71‐4 203‐794‐9 Carbon Black 1333‐86‐4 215‐609‐9 Ethylene Carbonate 96‐49‐1 202‐510‐0 Graphite 7782‐42‐5 231‐955‐3 Lithium 7439‐93‐2 231‐102‐5 Lithium Perchlorate 7791‐03‐9 232‐237‐2 Lithium Trifluoromethane 33454‐82‐9 251‐528‐5 Sulfonate Manganese Dioxide 1313‐13‐9 215‐202‐6 Propylene Carbonate 108‐32‐7 203‐572‐1 *SVHC Substance per Candidate List Updated June 18, 2012 Amount 5‐10 % 0‐5% 0‐5% 0
PAGE 3
Extinguishing Media: Use any extinguishing media that is appropriate for the surrounding fire. Special Fire Fighting Procedures: Firefighters should wear positive pressure self‐contained breathing apparatus and full protective clothing. Fight fire from a distance or protected area. Cool fire exposed batteries to prevent rupture. Use caution when handling fire‐exposed containers (batteries may explode in heat of fire).
PAGE 4
Hazardous Decomposition Products: Thermal decomposition may produce hazardous fumes of lithium and manganese; oxides of carbon and other toxic by‐products. Hazardous Polymerization: Will not occur SECTION 11: TOXICOLOGICAL INFORMATION Potential Health Effects: The chemicals and metals in this product are contained in a sealed can. Exposure to the contents will not occur unless the battery leaks, is exposed to high temperatures or is mechanically, physically, or electrically abused.
PAGE 5
DURACELL Primary Lithium Metal Batteries UN3090 Primary lithium batteries – PI 968 UN3091 Primary lithium batteries with or in equipment‐ PI 969 & 970 UN 38.3: DURACELL certifies that all of its lithium batteries meet the requirements of the UN Manual of Tests and Criteria, Part III subsection 38.3. If you assemble these batteries into larger battery packs, it is recommended that you perform the UN Tests to ensure the requirements are met prior to shipment.
PAGE 6
EU Labeling: Labeling is not required because batteries are classified as articles under the both REACH and the Dangerous Preparations Directive and as such are exempt from the requirement for labeling. SECTION 16: OTHER INFORMATION P&G Hazard Rating: Health: 0 Fire: 0 Reactivity: 0 =========================================================================== Data supplied is for use only in connection with occupational safety and health.