SDS

ManualsBrandsEnerfoam ManualsCaulks & Sealants42 Professional Foam Sealant 30 oz. - 12 pk.

® ™ Trademark of The Dow Chemical Company ("Dow") or an affiliated

company of Dow

Page 1 of 18

SAFETY DATA SHEET

THE DOW CHEMICAL COMPANY

Product name: ENERFOAM™ Insulating Foam Sealant GUN 30oz

HC ES 12ct

Issue Date: 01/04/2016

Print Date: 04/20/2016

THE DOW CHEMICAL COMPANY encourages and expects you to read and understand the entire

(M)SDS, as there is important information throughout the document. We expect you to follow the

precautions identified in this document unless your use conditions would necessitate other appropriate

methods or actions.

1. IDENTIFICATION

Product name: ENERFOAM™ Insulating Foam Sealant GUN 30oz HC ES 12ct

Recommended use of the chemical and restrictions on use

Identified uses: Component(s) for the manufacture of urethane polymers. We recommend that you

use this product in a manner consistent with the listed use. If your intended use is not consistent with

the stated use, please contact your sales or technical service representative.

COMPANY IDENTIFICATION

THE DOW CHEMICAL COMPANY

2030 WILLARD H DOW CENTER

MIDLAND MI 48674-0000

UNITED STATES

Customer Information Number:

800-258-2436

SDSQuestion@dow.com

EMERGENCY TELEPHONE NUMBER

24-Hour Emergency Contact: CHEMTREC +1 703-527-3887

Local Emergency Contact: 800-424-9300

2. HAZARDS IDENTIFICATION

Hazard classification

This material is hazardous under the criteria of the Federal OSHA Hazard Communication Standard

29CFR 1910.1200.

Flammable aerosols - Category 2

Gases under pressure - Liquefied gas

Acute toxicity - Category 4 - Inhalation

Skin irritation - Category 2

Eye irritation - Category 2A

Respiratory sensitisation - Category 1

Skin sensitisation - Category 1

Effects on or via lactation

Specific target organ toxicity - single exposure - Category 3

Specific target organ toxicity - repeated exposure - Category 2 - Inhalation

Summary of content (18 pages)

PAGE 1
SAFETY DATA SHEET THE DOW CHEMICAL COMPANY Product name: ENERFOAM™ Insulating Foam Sealant GUN 30oz HC ES 12ct Issue Date: 01/04/2016 Print Date: 04/20/2016 THE DOW CHEMICAL COMPANY encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions. 1.
PAGE 2
Product name: ENERFOAM™ Insulating Foam Sealant GUN 30oz HC ES 12ct Issue Date: 01/04/2016 Label elements Hazard pictograms Signal word: DANGER! Hazards Flammable aerosol. Contains gas under pressure; may explode if heated. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. Harmful if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. May cause harm to breast-fed children.
PAGE 3
Product name: ENERFOAM™ Insulating Foam Sealant GUN 30oz HC ES 12ct Issue Date: 01/04/2016 Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F. Disposal Dispose of contents/ container to an approved waste disposal plant. Other hazards Water Reactive 3. COMPOSITION/INFORMATION ON INGREDIENTS This product is a mixture. Component CASRN Concentration Polymethylenepolyphenylisocyanate, propoxylated glycerin polymer 57029-46-6 >= 30.0 - <= 60.
PAGE 4
Product name: ENERFOAM™ Insulating Foam Sealant GUN 30oz HC ES 12ct Issue Date: 01/04/2016 Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by qualified personnel. Call a physician or transport to a medical facility. Skin contact: Remove material from skin immediately by washing with soap and plenty of water.
PAGE 5
Product name: ENERFOAM™ Insulating Foam Sealant GUN 30oz HC ES 12ct Issue Date: 01/04/2016 Hazardous combustion products: During a fire, smoke may contain the original material in addition to combustion products of varying composition which may be toxic and/or irritating. Combustion products may include and are not limited to: Nitrogen oxides. Isocyanates. Hydrogen chloride. Carbon monoxide. Carbon dioxide. Hydrogen cyanide. Unusual Fire and Explosion Hazards: Contains flammable propellant.
PAGE 6
Product name: ENERFOAM™ Insulating Foam Sealant GUN 30oz HC ES 12ct Issue Date: 01/04/2016 7. HANDLING AND STORAGE Precautions for safe handling: Keep away from heat, sparks and flame. Avoid contact with eyes. Avoid contact with skin and clothing. Avoid prolonged or repeated contact with skin. Avoid breathing vapor. Wash thoroughly after handling. Keep container closed. Use only with adequate ventilation. Keep out of reach of children.
PAGE 7
Product name: ENERFOAM™ Insulating Foam Sealant GUN 30oz HC ES 12ct Issue Date: 01/04/2016 barrier materials include: Neoprene. Nitrile/butadiene rubber ("nitrile" or "NBR"). Viton. Polyvinyl chloride ("PVC" or "vinyl").
PAGE 8
Product name: ENERFOAM™ Insulating Foam Sealant GUN 30oz HC ES 12ct Decomposition temperature Kinematic Viscosity Explosive properties Oxidizing properties Molecular weight Issue Date: 01/04/2016 No test data available Not applicable Not explosive No No data available NOTE: The physical data presented above are typical values and should not be construed as a specification. 10. STABILITY AND REACTIVITY Reactivity: No data available Chemical stability: Stable under recommended storage conditions.
PAGE 9
Product name: ENERFOAM™ Insulating Foam Sealant GUN 30oz HC ES 12ct Issue Date: 01/04/2016 Acute dermal toxicity Prolonged skin contact is unlikely to result in absorption of harmful amounts. As product: The dermal LD50 has not been determined. LD50, Rabbit, > 2,000 mg/kg Estimated. Acute inhalation toxicity In confined or poorly ventilated areas, vapor can easily accumulate and can cause unconsciousness and death due to displacement of oxygen.
PAGE 10
Product name: ENERFOAM™ Insulating Foam Sealant GUN 30oz HC ES 12ct Issue Date: 01/04/2016 Lung tumors have been observed in laboratory animals exposed to respirable aerosol droplets of MDI/Polymeric MDI (6 mg/m3) for their lifetime. Tumors occurred concurrently with respiratory irritation and lung injury. Current exposure guidelines are expected to protect against these effects reported for MDI.
PAGE 11
Product name: ENERFOAM™ Insulating Foam Sealant GUN 30oz HC ES 12ct Issue Date: 01/04/2016 LC50, Danio rerio (zebra fish), static test, 96 Hour, > 1,000 mg/l, OECD Test Guideline 203 or Equivalent Acute toxicity to aquatic invertebrates Based on information for a similar material: EC50, Daphnia magna (Water flea), static test, 24 Hour, > 1,000 mg/l, OECD Test Guideline 202 or Equivalent Acute toxicity to algae/aquatic plants Based on information for a similar material: NOEC, Desmodesmus subspicatus (green
PAGE 12
Product name: ENERFOAM™ Insulating Foam Sealant GUN 30oz HC ES 12ct Issue Date: 01/04/2016 Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
PAGE 13
Product name: ENERFOAM™ Insulating Foam Sealant GUN 30oz HC ES 12ct Issue Date: 01/04/2016 Biodegradability: Expected to degrade slowly in the environment. Diphenylmethane Diisocyanate, isomers and homologues Biodegradability: In the aquatic and terrestrial environment, material reacts with water forming predominantly insoluble polyureas which appear to be stable.
PAGE 14
Product name: ENERFOAM™ Insulating Foam Sealant GUN 30oz HC ES 12ct Issue Date: 01/04/2016 Atmospheric half-life: 6.4 d Method: Estimated. 4,4' -Methylenediphenyl diisocyanate Biodegradability: In the aquatic and terrestrial environment, material reacts with water forming predominantly insoluble polyureas which appear to be stable. In the atmospheric environment, material is expected to have a short tropospheric half-life, based on calculations and by analogy with related diisocyanates.
PAGE 15
Product name: ENERFOAM™ Insulating Foam Sealant GUN 30oz HC ES 12ct Issue Date: 01/04/2016 Propane Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Partition coefficient: n-octanol/water(log Pow): 2.36 Measured Methyl ether Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Partition coefficient: n-octanol/water(log Pow): 0.
PAGE 16
Product name: ENERFOAM™ Insulating Foam Sealant GUN 30oz HC ES 12ct Issue Date: 01/04/2016 N,N'-Dimorpholinodiethylether Potential for mobility in soil is low (Koc between 500 and 2000). Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is not expected to be an important fate process. Partition coefficient(Koc): 784 Estimated. 13. DISPOSAL CONSIDERATIONS Disposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER.
PAGE 17
Product name: ENERFOAM™ Insulating Foam Sealant GUN 30oz HC ES 12ct Issue Date: 01/04/2016 volume and may be influenced by regional or country variations in regulations. Additional transportation system information can be obtained through an authorized sales or customer service representative. It is the responsibility of the transporting organization to follow all applicable laws, regulations and rules relating to the transportation of the material. 15.
PAGE 18
Product name: ENERFOAM™ Insulating Foam Sealant GUN 30oz HC ES 12ct Issue Date: 01/04/2016 16. OTHER INFORMATION Revision Identification Number: 101216056 / A001 / Issue Date: 01/04/2016 / Version: 4.0 Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this document. Legend ACGIH Asphyxiant C NIOSH REL OSHA Z-1 STEL TWA US WEEL USA. ACGIH Threshold Limit Values (TLV) Asphyxiant Ceiling USA. NIOSH Recommended Exposure Limits USA.