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Table Of Contents

Safety Data Sheet

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Mixture identification:

Trade name: 102 EcoTank Magenta ink bottle, T03R3

1.2. Relevant identified uses of the substance or mixture and uses advised against

Recommended use:

Ink for inkjet printing

1.3. Details of the supplier of the safety data sheet

Company:

EPSON EUROPE B.V.

Azie building, Atlas ArenA, Hoogoorddreef 5,1101 BA Amsterdam

Zuidoost The Netherlands

Phone number: +31-20-314-5000

Competent person responsible for the safety data sheet:

chemicals@epson-europe.com

Date: 23/06/2017

Revision: 1.0

1.4. Emergency telephone number

Phone number: +31-20-314-5000

United Kingdom; 01952 607111 Monday to Friday 9am to 5:30pm.

Emergency Action: In the event of a medical enquiry involving

this product, please contact your doctor or local hospital

accident and emergency department.

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

EC regulation criteria 1272/2008 (CLP)

The product is not classified as dangerous according to Regulation EC 1272/2008

(CLP).

Adverse physicochemical, human health and environmental effects:

No other hazards

2.2. Label elements

The product is not classified as dangerous according to Regulation EC 1272/2008 (CLP).

Hazard pictograms:

None

Hazard statements:

None

Precautionary statements:

None

Special Provisions:

EUH210 Safety data sheet available on request.

EUH208 Contains 2,4,7,9-tetramethyldec-5-yne-4,7-diol. May produce an allergic

reaction.

EUH208 Contains 1,2-benzisothiazol-3(2H)-one; 1,2-benzisothiazolin-3-one. May

produce an allergic reaction.

Special provisions according to Annex XVII of REACH and subsequent amendments:

None

2.3. Other hazards

vPvB Substances: None - PBT Substances: None

Other Hazards:

No other hazards

T03R3_en Version 8.0

Page n. 1 of 9 Revison 1.0

Summary of content (36 pages)

PAGE 1
Safety Data Sheet SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Mixture identification: Trade name: 102 EcoTank Magenta ink bottle, T03R3 1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended use: Ink for inkjet printing 1.3. Details of the supplier of the safety data sheet Company: EPSON EUROPE B.V.
PAGE 2
Safety Data Sheet SECTION 3: Composition/information on ingredients 3.1. Substances No 3.2. Mixtures Hazardous components within the meaning of the CLP regulation and related classification: Qty 65% ~ 80% Name Water Ident. Number CAS: 7732-18-5 EC: 231-791-2 10% ~ 12.5% 2-[2-(2-butoxyethoxy)et hoxy]ethanol; TEGBE; triethylene glycol monobutyl ether Index number: CAS: EC: REACH No.: 10% ~ 12.5% Glycerol CAS: EC: 0.25% ~ 0.5% Triethanol amine CAS: EC: 0.1% ~ 0.
PAGE 3
Safety Data Sheet SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media: Water. Carbon dioxide (CO2). Extinguishing media which must not be used for safety reasons: None in particular. 5.2. Special hazards arising from the substance or mixture Do not inhale explosion and combustion gases. Burning produces heavy smoke. 5.3. Advice for firefighters Use suitable breathing apparatus . Collect contaminated fire extinguishing water separately.
PAGE 4
Safety Data Sheet 2-[2-(2-butoxyethoxy)ethoxy]ethanol; TEGBE; triethylene glycol monobutyl ether CAS: 143-22-6 Target: Fresh Water - Value: 1.5 mg/l Target: Freshwater sediments - Value: 5.77 mg/kg Target: Marine water - Value: 0.15 mg/l Target: Marine water sediments - Value: 0.13 mg/kg Target: Microorganisms in sewage treatments - Value: 200 mg/l 2,4,7,9-tetramethyldec-5-yne-4,7-diol - CAS: 126-86-3 Target: Fresh Water - Value: 0.04 mg/l Target: Marine water - Value: 0.
PAGE 5
Safety Data Sheet Fat Solubility: Conductivity: No data available No data available SECTION 10: Stability and reactivity 10.1. Reactivity Stable under normal conditions 10.2. Chemical stability Stable under normal conditions 10.3. Possibility of hazardous reactions None 10.4. Conditions to avoid Stable under normal conditions. 10.5. Incompatible materials None in particular. 10.6. Hazardous decomposition products None. SECTION 11: Toxicological information 11.1.
PAGE 6
Safety Data Sheet a) acute toxicity: Test: LD50 - Route: Dermal - Species: Rat > 2000 mg/kg b) skin corrosion/irritation: Test: Skin Irritant - Species: Rabbit Mild irritant c) serious eye damage/irritation: Test: Eye Irritant - Species: Rabbit Highly irritating d) respiratory or skin sensitisation: Test: Skin Sensitisation - Route: LLNA - Species: Mouse Sensitiser e) germ cell mutagenicity: Test: Mutagenesis - Species: Salmonella Typhimurium Negative If not differently specified, the information required
PAGE 7
Safety Data Sheet 14.2. UN proper shipping name No data available 14.3. Transport hazard class(es) No data available 14.4. Packing group No data available 14.5. Environmental hazards No data available 14.6. Special precautions for user No data available 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code No data available SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Dir.
PAGE 8
Safety Data Sheet Hazard class and hazard category Acute Tox. 4 Skin Irrit. 2 Eye Dam. 1 Skin Sens. 1,1A,1B Skin Sens. 1B Aquatic Acute 1 Aquatic Chronic 3 Code Description 3.1/4/Oral 3.2/2 3.3/1 3.4.2/1-1A-1B 3.4.2/1B 4.1/A1 4.
PAGE 9
Safety Data Sheet IATA: IATA-DGR: ICAO: ICAO-TI: IMDG: INCI: KSt: LC50: LD50: LTE: PNEC: RID: STE: STEL: STOT: TLV: TWATLV: WGK: T03R3_en Page n. 9 of 9 International Air Transport Association. Dangerous Goods Regulation by the "International Air Transport Association" (IATA). International Civil Aviation Organization. Technical Instructions by the "International Civil Aviation Organization" (ICAO). International Maritime Code for Dangerous Goods. International Nomenclature of Cosmetic Ingredients.
PAGE 10
Safety Data Sheet SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Mixture identification: Trade name: 102 EcoTank Cyan ink bottle, T03R2 1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended use: Ink for inkjet printing 1.3. Details of the supplier of the safety data sheet Company: EPSON EUROPE B.V.
PAGE 11
Safety Data Sheet SECTION 3: Composition/information on ingredients 3.1. Substances No 3.2. Mixtures Hazardous components within the meaning of the CLP regulation and related classification: Qty 65% ~ 80% Name Water Ident. Number CAS: 7732-18-5 EC: 231-791-2 10% ~ 12.5% 2-[2-(2-butoxyethoxy)et hoxy]ethanol; TEGBE; triethylene glycol monobutyl ether Index number: CAS: EC: REACH No.: 10% ~ 12.5% Glycerol CAS: EC: 0.5% ~ 1% Triethanol amine CAS: EC: 0.1% ~ 0.
PAGE 12
Safety Data Sheet SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media: Water. Carbon dioxide (CO2). Extinguishing media which must not be used for safety reasons: None in particular. 5.2. Special hazards arising from the substance or mixture Do not inhale explosion and combustion gases. Burning produces heavy smoke. 5.3. Advice for firefighters Use suitable breathing apparatus . Collect contaminated fire extinguishing water separately.
PAGE 13
Safety Data Sheet PNEC Exposure Limit Values 2-[2-(2-butoxyethoxy)ethoxy]ethanol; TEGBE; triethylene glycol monobutyl ether CAS: 143-22-6 Target: Fresh Water - Value: 1.5 mg/l Target: Freshwater sediments - Value: 5.77 mg/kg Target: Marine water - Value: 0.15 mg/l Target: Marine water sediments - Value: 0.13 mg/kg Target: Microorganisms in sewage treatments - Value: 200 mg/l 2,4,7,9-tetramethyldec-5-yne-4,7-diol - CAS: 126-86-3 Target: Fresh Water - Value: 0.04 mg/l Target: Marine water - Value: 0.
PAGE 14
Safety Data Sheet 9.2. Other information Miscibility: Fat Solubility: Conductivity: No data available No data available No data available SECTION 10: Stability and reactivity 10.1. Reactivity Stable under normal conditions 10.2. Chemical stability Stable under normal conditions 10.3. Possibility of hazardous reactions None 10.4. Conditions to avoid Stable under normal conditions. 10.5. Incompatible materials None in particular. 10.6. Hazardous decomposition products None.
PAGE 15
Safety Data Sheet 2,4,7,9-tetramethyldec-5-yne-4,7-diol - CAS: 126-86-3 a) acute toxicity: Test: LD50 - Route: Dermal - Species: Rat > 2000 mg/kg b) skin corrosion/irritation: Test: Skin Irritant - Species: Rabbit Mild irritant c) serious eye damage/irritation: Test: Eye Irritant - Species: Rabbit Highly irritating d) respiratory or skin sensitisation: Test: Skin Sensitisation - Route: LLNA - Species: Mouse Sensitiser e) germ cell mutagenicity: Test: Mutagenesis - Species: Salmonella Typhimurium Negative I
PAGE 16
Safety Data Sheet 14.2. UN proper shipping name No data available 14.3. Transport hazard class(es) No data available 14.4. Packing group No data available 14.5. Environmental hazards No data available 14.6. Special precautions for user No data available 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code No data available SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Dir.
PAGE 17
Safety Data Sheet Hazard class and hazard category Acute Tox. 4 Skin Irrit. 2 Eye Dam. 1 Skin Sens. 1,1A,1B Skin Sens. 1B Aquatic Acute 1 Aquatic Chronic 3 Code Description 3.1/4/Oral 3.2/2 3.3/1 3.4.2/1-1A-1B 3.4.2/1B 4.1/A1 4.
PAGE 18
Safety Data Sheet IATA: IATA-DGR: ICAO: ICAO-TI: IMDG: INCI: KSt: LC50: LD50: LTE: PNEC: RID: STE: STEL: STOT: TLV: TWATLV: WGK: T03R2_en Page n. 9 of 9 International Air Transport Association. Dangerous Goods Regulation by the "International Air Transport Association" (IATA). International Civil Aviation Organization. Technical Instructions by the "International Civil Aviation Organization" (ICAO). International Maritime Code for Dangerous Goods. International Nomenclature of Cosmetic Ingredients.
PAGE 19
Safety Data Sheet SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Mixture identification: Trade name: 102 EcoTank Yellow ink bottle, T03R4 1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended use: Ink for inkjet printing 1.3. Details of the supplier of the safety data sheet Company: EPSON EUROPE B.V.
PAGE 20
Safety Data Sheet SECTION 3: Composition/information on ingredients 3.1. Substances No 3.2. Mixtures Hazardous components within the meaning of the CLP regulation and related classification: Qty 65% ~ 80% Name Water Ident. Number CAS: 7732-18-5 EC: 231-791-2 10% ~ 12.5% 2-[2-(2-butoxyethoxy)et hoxy]ethanol; TEGBE; triethylene glycol monobutyl ether Index number: CAS: EC: REACH No.: 10% ~ 12.5% Glycerol CAS: EC: 0.25% ~ 0.5% Triethanol amine CAS: EC: 0.1% ~ 0.
PAGE 21
Safety Data Sheet SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media: Water. Carbon dioxide (CO2). Extinguishing media which must not be used for safety reasons: None in particular. 5.2. Special hazards arising from the substance or mixture Do not inhale explosion and combustion gases. Burning produces heavy smoke. 5.3. Advice for firefighters Use suitable breathing apparatus . Collect contaminated fire extinguishing water separately.
PAGE 22
Safety Data Sheet PNEC Exposure Limit Values 2-[2-(2-butoxyethoxy)ethoxy]ethanol; TEGBE; triethylene glycol monobutyl ether CAS: 143-22-6 Target: Fresh Water - Value: 1.5 mg/l Target: Freshwater sediments - Value: 5.77 mg/kg Target: Marine water - Value: 0.15 mg/l Target: Marine water sediments - Value: 0.13 mg/kg Target: Microorganisms in sewage treatments - Value: 200 mg/l 2,4,7,9-tetramethyldec-5-yne-4,7-diol - CAS: 126-86-3 Target: Fresh Water - Value: 0.04 mg/l Target: Marine water - Value: 0.
PAGE 23
Safety Data Sheet Miscibility: Fat Solubility: Conductivity: No data available No data available No data available SECTION 10: Stability and reactivity 10.1. Reactivity Stable under normal conditions 10.2. Chemical stability Stable under normal conditions 10.3. Possibility of hazardous reactions None 10.4. Conditions to avoid Stable under normal conditions. 10.5. Incompatible materials None in particular. 10.6. Hazardous decomposition products None. SECTION 11: Toxicological information 11.1.
PAGE 24
Safety Data Sheet a) acute toxicity: Test: LD50 - Route: Dermal - Species: Rat > 2000 mg/kg b) skin corrosion/irritation: Test: Skin Irritant - Species: Rabbit Mild irritant c) serious eye damage/irritation: Test: Eye Irritant - Species: Rabbit Highly irritating d) respiratory or skin sensitisation: Test: Skin Sensitisation - Route: LLNA - Species: Mouse Sensitiser e) germ cell mutagenicity: Test: Mutagenesis - Species: Salmonella Typhimurium Negative If not differently specified, the information required
PAGE 25
Safety Data Sheet 14.2. UN proper shipping name No data available 14.3. Transport hazard class(es) No data available 14.4. Packing group No data available 14.5. Environmental hazards No data available 14.6. Special precautions for user No data available 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code No data available SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Dir.
PAGE 26
Safety Data Sheet Hazard class and hazard category Acute Tox. 4 Skin Irrit. 2 Eye Dam. 1 Skin Sens. 1,1A,1B Skin Sens. 1B Aquatic Acute 1 Aquatic Chronic 3 Code Description 3.1/4/Oral 3.2/2 3.3/1 3.4.2/1-1A-1B 3.4.2/1B 4.1/A1 4.
PAGE 27
Safety Data Sheet IATA: IATA-DGR: ICAO: ICAO-TI: IMDG: INCI: KSt: LC50: LD50: LTE: PNEC: RID: STE: STEL: STOT: TLV: TWATLV: WGK: T03R4_en Page n. 9 of 9 International Air Transport Association. Dangerous Goods Regulation by the "International Air Transport Association" (IATA). International Civil Aviation Organization. Technical Instructions by the "International Civil Aviation Organization" (ICAO). International Maritime Code for Dangerous Goods. International Nomenclature of Cosmetic Ingredients.
PAGE 28
Safety Data Sheet SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Mixture identification: Trade name: 102 EcoTank Black ink bottle, T03R1 1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended use: Ink for inkjet printing 1.3. Details of the supplier of the safety data sheet Company: EPSON EUROPE B.V.
PAGE 29
Safety Data Sheet 3.2. Mixtures Hazardous components within the meaning of the CLP regulation and related classification: Qty 65% ~ 80% Name Water Ident. Number CAS: 7732-18-5 EC: 231-791-2 5% ~ 7% Carbon black CAS: EC: 1333-86-4 215-609-9 5% ~ 7% Glycerol CAS: EC: 56-81-5 200-289-5 3% ~ 5% 2-[2-(2-butoxyethoxy)et hoxy]ethanol; TEGBE; triethylene glycol monobutyl ether Index number: CAS: EC: REACH No.: 603-183-00-0 0.5% ~ 1% Triethanol amine CAS: EC: 0.1% ~ 0.
PAGE 30
Safety Data Sheet 5.2. Special hazards arising from the substance or mixture Do not inhale explosion and combustion gases. Burning produces heavy smoke. 5.3. Advice for firefighters Use suitable breathing apparatus . Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Move undamaged containers from immediate hazard area if it can be done safely. SECTION 6: Accidental release measures 6.1.
PAGE 31
Safety Data Sheet PNEC Exposure Limit Values 2-[2-(2-butoxyethoxy)ethoxy]ethanol; TEGBE; triethylene glycol monobutyl ether CAS: 143-22-6 Target: Fresh Water - Value: 1.5 mg/l Target: Freshwater sediments - Value: 5.77 mg/kg Target: Marine water - Value: 0.15 mg/l Target: Marine water sediments - Value: 0.13 mg/kg Target: Microorganisms in sewage treatments - Value: 200 mg/l 2,4,7,9-tetramethyldec-5-yne-4,7-diol - CAS: 126-86-3 Target: Fresh Water - Value: 0.04 mg/l Target: Marine water - Value: 0.
PAGE 32
Safety Data Sheet 9.2. Other information Miscibility: Fat Solubility: Conductivity: No data available No data available No data available SECTION 10: Stability and reactivity 10.1. Reactivity Stable under normal conditions 10.2. Chemical stability Stable under normal conditions 10.3. Possibility of hazardous reactions None 10.4. Conditions to avoid Stable under normal conditions. 10.5. Incompatible materials None in particular. 10.6. Hazardous decomposition products None.
PAGE 33
Safety Data Sheet Test: LD50 - Route: Oral - Species: Guinea pig = 2200 mg/kg - Source: "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 114, 1982. Test: LD50 - Route: Oral - Species: Mouse = 5846 mg/kg - Source: Science Reports of the Research Institutes, Tohoku University, Series C: Medicine. Vol. 36(1-4), Pg. 10, 1989.
PAGE 34
Safety Data Sheet 12.5. Results of PBT and vPvB assessment vPvB Substances: None - PBT Substances: None 12.6. Other adverse effects None SECTION 13: Disposal considerations 13.1. Waste treatment methods Recover if possible. In so doing, comply with the local and national regulations currently in force. SECTION 14: Transport information 14.1. UN number Not classified as dangerous in the meaning of transport regulations. 14.2. UN proper shipping name No data available 14.3.
PAGE 35
Safety Data Sheet 15.2. Chemical safety assessment No SECTION 16: Other information Full text of phrases referred to in Section 3: H318 Causes serious eye damage. H317 May cause an allergic skin reaction. H412 Harmful to aquatic life with long lasting effects. Hazard class and hazard category Eye Dam. 1 Skin Sens. 1B Aquatic Chronic 3 Code Description 3.3/1 3.4.2/1B 4.
PAGE 36
Safety Data Sheet DNEL: EINECS: GefStoffVO: GHS: IATA: IATA-DGR: ICAO: ICAO-TI: IMDG: INCI: KSt: LC50: LD50: LTE: PNEC: RID: STE: STEL: STOT: TLV: TWATLV: WGK: T03R1_en Page n. 9 of 9 Derived No Effect Level. European Inventory of Existing Commercial Chemical Substances. Ordinance on Hazardous Substances, Germany. Globally Harmonized System of Classification and Labeling of Chemicals. International Air Transport Association.