FILA Chemicals USA Revision nr. 4 Dated 18/5/2015 FORMULA MARMO Printed on 18/05/2015 Page n. 1/13 Safety data sheet according to U.S.A. Federal Hazcom 2012 SECTION 1. Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name FORMULA MARMO 1.2. Relevant identified uses of the substance or mixture and uses advised against Marble Cleaner and Protector Intended use 1.3.
Revision nr. 4 FILA Chemicals USA Dated 18/5/2015 Printed on 18/05/2015 FORMULA MARMO Page n. 2/13 Precautionary statements: Prevention: P261 P271 Response: P304+P340 P312 Storage: P403+P233 P405 Disposal: P501 Avoid breathing dust / fume / gas / mist / vapours / spray. Use only outdoors or in a well-ventilated area. IF INHALED: remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER / doctor / . . . / if you feel unwell. Store in a well-ventilated place.
FILA Chemicals USA Revision nr. 4 Dated 18/5/2015 FORMULA MARMO Printed on 18/05/2015 Page n. 3/13 4.1. Description of first aid measures. EYES: Remove contact lenses, if present. Wash immediately with plenty of water for at least 15 minutes, opening the eyelids fully. If problem persists, seek medical advice. SKIN: Remove contaminated clothing. Rinse skin with a shower immediately. Get medical advice/attention immediately. Wash contaminated clothing before using it again.
FILA Chemicals USA Revision nr. 4 Dated 18/5/2015 FORMULA MARMO Printed on 18/05/2015 Page n. 4/13 6.1. Personal precautions, protective equipment and emergency procedures. Block the leakage if there is no hazard. Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency procedures. 6.
Revision nr. 4 FILA Chemicals USA Dated 18/5/2015 Printed on 18/05/2015 FORMULA MARMO Page n. 5/13 USA OSHA-PEL USA CAL/OSHA-PEL EU OEL EU TLV-ACGIH Occupational Exposure Limits - Limits for Air Contaminants TABLE Z-11910.1000. California Division of Occupational Safety and Health (Cal-OSHA) Permissible Exposure Limits (PELs). Directive 2009/161/EU; Directive 2006/15/EC; Directive 2004/37/EC; Directive 2000/39/EC. ACGIH 2014 1-METHOXY-2-PROPANOL Threshold Limit Value.
FILA Chemicals USA Revision nr. 4 Dated 18/5/2015 FORMULA MARMO Printed on 18/05/2015 Page n. 6/13 RESPIRATORY PROTECTION If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, wear a mask with a NIOSH certified filter, whose class must be chosen according to the limit of use concentration (NIOSH 42 CFR 84, OSHA 29 CFR 1910.134).
FILA Chemicals USA Revision nr. 4 Dated 18/5/2015 FORMULA MARMO Printed on 18/05/2015 Page n. 7/13 10.2. Chemical stability. The product is stable in normal conditions of use and storage. 10.3. Possibility of hazardous reactions. The vapours may also form explosive mixtures with the air. 10.4. Conditions to avoid. Avoid overheating. Avoid bunching of electrostatic charges. Avoid all sources of ignition. 10.5. Incompatible materials. Information not available. 10.6. Hazardous decomposition products.
FILA Chemicals USA Revision nr. 4 Dated 18/5/2015 FORMULA MARMO Printed on 18/05/2015 Page n. 8/13 contaminate soil or vegetation. 12.1. Toxicity. NAPHTA (PETROL.) HYDROTREATED HEAVY LC50 - for Fish. EC50 - for Crustacea. EC50 - for Algae / Aquatic Plants. 8,2 mg/l/96h Pimephales promelas 4,5 mg/l/48h Daphnia magna 3,1 mg/l/72h Pseudokirchnerella subcapitata 12.2. Persistence and degradability. DIPROPYLENE GLYCOL MONOMETHYL ETHER Solubility in water. mg/l 1000 - 10000 Rapidly biodegradable.
FILA Chemicals USA Revision nr. 4 Dated 18/5/2015 FORMULA MARMO Printed on 18/05/2015 Page n. 9/13 12.6. Other adverse effects. Information not available. SECTION 13. Disposal considerations. 13.1. Waste treatment methods. Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this product should be evaluated according to applicable regulations.
FILA Chemicals USA Revision nr. 4 Dated 18/5/2015 FORMULA MARMO Printed on 18/05/2015 Page n. 10/13 34590-94-8 107-98-2 DIPROPYLENE GLYCOL MONOMETHYL ETHER (Glycol ethers) 1-METHOXY-2-PROPANOL (Glycol ethers) Clean Air Act Section 602 Class I Substances: No component(s) listed. Clean Air Act Section 602 Class II Substances: No component(s) listed. Clean Water Act – Priority Pollutants: No component(s) listed. Clean Water Act – Toxic Pollutants: No component(s) listed.
FILA Chemicals USA Revision nr. 4 Dated 18/5/2015 FORMULA MARMO Printed on 18/05/2015 Page n. 11/13 34590-94-8 107-98-2 DIPROPYLENE GLYCOL MONOMETHYL ETHER (Glycol ethers) 1-METHOXY-2-PROPANOL (Glycol ethers) RCRA Code: No component(s) listed. CAA 112 (r) RMP TQ: No component(s) listed. State Regulations.
FILA Chemicals USA Revision nr. 4 Dated 18/5/2015 FORMULA MARMO Printed on 18/05/2015 Page n. 12/13 Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012: None. Substances subject to the Rotterdam Convention: None. Substances subject to the Stockholm Convention: None. Canadian WHMIS. Information not available. SECTION 16. Other information. Current Issue Date Previous Issue Date Previous rev.
FILA Chemicals USA Revision nr. 4 Dated 18/5/2015 FORMULA MARMO Printed on 18/05/2015 Page n. 13/13 - OEL: Occupational Exposure Level - PEL: Predicted exposure level - RCRA Code: Resource Conservation and Recovery Act Code - REL: Recommended exposure limit - RID: Regulation concerning the international transport of dangerous goods by train - TLV: Threshold Limit Value - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure.
FILA Chemicals USA Revision nr 3 Dated 11/5/2015 FILA MARBLE SHINE Printed on 11/05/2015 Page n. 1/12 Safety data sheet according to U.S.A. Federal Hazcom 2012 SECTION 1. Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name FILA MARBLE SHINE 1.2. Relevant identified uses of the substance or mixture and uses advised against Marble Polish and Restorer Intended use 1.3.
Revision nr 3 FILA Chemicals USA Dated 11/5/2015 Printed on 11/05/2015 FILA MARBLE SHINE Page n. 2/12 H314 Causes severe skin burns and eye damage. Precautionary statements: Prevention: P260 P264 P280 Response: P301+P330+P331 P303+P361+P353 P304+P340 P305+P351+P338 P310 P363 Storage: P405 Disposal: P501 Do not breathe dust / fume / gas / mist / vapours / spray. Wash hands thoroughly after handling. Wear protective gloves / protective clothing / eye protection / face protection.
FILA Chemicals USA Revision nr 3 Dated 11/5/2015 FILA MARBLE SHINE Printed on 11/05/2015 Page n. 3/12 doctor. INHALATION: Get medical advice/attention immediately. Remove victim to fresh air, away from the accident scene. If the subject stops breathing, administer artificial respiration. Take suitable precautions for rescue workers. 4.2. Most important symptoms and effects, both acute and delayed. For symptoms and effects caused by the contained substances, see chap. 11. 4.3.
Revision nr 3 FILA Chemicals USA Dated 11/5/2015 Printed on 11/05/2015 FILA MARBLE SHINE Page n. 4/12 The product must not penetrate into the sewer system or come into contact with surface water or ground water. 6.3. Methods and material for containment and cleaning up. Collect the leaked product into a suitable container. Evaluate the compatibility of the container to be used, by checking section 10. Absorb the remainder with inert absorbent material. Make sure the leakage site is well aired.
FILA Chemicals USA Revision nr 3 Dated 11/5/2015 FILA MARBLE SHINE Printed on 11/05/2015 Page n. 5/12 OSHA USA 1 CAL/OSHA USA 1 2 NIOSH USA 1 2 8.2. Exposure controls. As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is well aired through effective local aspiration. When choosing personal protective equipment, ask your chemical substance supplier for advice.
FILA Chemicals USA Revision nr 3 Dated 11/5/2015 FILA MARBLE SHINE Printed on 11/05/2015 Page n. 6/12 Lower inflammability limit. Upper inflammability limit. Lower explosive limit. Upper explosive limit. Vapour pressure. Vapour density Relative density. Solubility Partition coefficient: n-octanol/water Auto-ignition temperature. Decomposition temperature. Viscosity Explosive properties Oxidising properties 9.2. Other information. Solid content: VOC (volatile carbon) : Not available. Not available.
FILA Chemicals USA Revision nr 3 Dated 11/5/2015 FILA MARBLE SHINE Printed on 11/05/2015 Page n. 7/12 11.1. Information on toxicological effects. In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it contains, using the criteria specified in the applicable regulation for classification.
Revision nr 3 FILA Chemicals USA Dated 11/5/2015 Printed on 11/05/2015 FILA MARBLE SHINE Page n. 8/12 evaluated according to applicable regulations. Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations. Avoid littering. Do not contaminate soil, sewers and waterways. Il trasporto dei rifiuti può essere soggetto ai regolamenti di trasporto per le merci pericolose.
FILA Chemicals USA Revision nr 3 Dated 11/5/2015 FILA MARBLE SHINE Printed on 11/05/2015 Page n. 9/12 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code. Information not relevant. SECTION 15. Regulatory information. 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture. U.S. Federal Regulations. Clean Air Act Section 112(b): No component(s) listed. Clean Air Act Section 602 Class I Substances: No component(s) listed.
FILA Chemicals USA Revision nr 3 Dated 11/5/2015 FILA MARBLE SHINE Printed on 11/05/2015 Page n. 10/12 No component(s) listed. CERCLA RQ: No component(s) listed. EPCRA 313 TRI: No component(s) listed. RCRA Code: No component(s) listed. CAA 112 (r) RMP TQ: No component(s) listed. State Regulations. Massachussetts: 144-62-7 Minnesota: 144-62-7 New Jersey: 144-62-7 New York: No component(s) listed. Pennsylvania: 144-62-7 California: 144-62-7 Proposition 65: International Regulations.
FILA Chemicals USA Revision nr 3 Dated 11/5/2015 FILA MARBLE SHINE Printed on 11/05/2015 Page n. 11/12 Substances subject to the Stockholm Convention: None. Canadian WHMIS. Information not available. SECTION 16. Other information. Current Issue Date Previous Issue Date Previous rev. number Changes in current issue 05-11-2015 11-05-2014 2 Revision according to Federal Hazcom 2012. Text of hazard (H) indications mentioned in section 2-3 of the sheet: Acute Tox.
FILA Chemicals USA Revision nr 3 Dated 11/5/2015 FILA MARBLE SHINE Printed on 11/05/2015 Page n. 12/12 - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. - TSCA: Toxic Substances Control Act - TWA STEL: Short-term exposure limit - TWA: Time-weighted average exposure limit - VOC: Volatile organic Compounds - WHMIS: Workplace Hazardous Materials Information System. GENERAL BIBLIOGRAPHY: - GHS rev. 3 - The Merck Index.
