SAFETY DATA SHEET DDP Specialty Electronic Materials US, LLC Product name: FROTH-PAK™ POLYOL HFO Issue Date: 00/00/0000 Print Date: 01/11/2022 DDP Specialty Electronic Materials US, LLC encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions. 1.
Product name: FROTH-PAK™ POLYOL HFO Issue Date: 00/00/0000 Signal word: WARNING! Hazards Contains gas under pressure; may explode if heated. May cause an allergic skin reaction. Suspected of damaging fertility or the unborn child. May displace oxygen and cause rapid suffocation. Precautionary statements Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
Product name: FROTH-PAK™ POLYOL HFO Issue Date: 00/00/0000 Polyester polyol Not available Trade Secret Diethylene glycol 111-46-6 >= 1.0 - < 10.0 % Dimethylbis((1-oxoneodecyl)oxy)stannane 68928-76-7 >= 0.25 - < 1.0 % Nitrogen 7727-37-9 >= 0.1 - <= 0.5 % >= 20.0 - <= 80.0 % 4. FIRST AID MEASURES Description of first aid measures General advice: First Aid responders should pay attention to self-protection and use the recommended protective clothing (chemical resistant gloves, splash protection).
Product name: FROTH-PAK™ POLYOL HFO Issue Date: 00/00/0000 Hazardous combustion products: During a fire, smoke may contain the original material in addition to combustion products of varying composition which may be toxic and/or irritating. Combustion products may include and are not limited to: Carbon monoxide. Carbon dioxide. Hydrogen halides. Unusual Fire and Explosion Hazards: Container may rupture from gas generation in a fire situation. Blowing agent vaporizes quickly at room temperature.
Product name: FROTH-PAK™ POLYOL HFO Issue Date: 00/00/0000 7. HANDLING AND STORAGE Precautions for safe handling: Avoid contact with eyes. Avoid breathing vapor. Do not enter confined spaces unless adequately ventilated. Wash thoroughly after handling. Keep container closed. Use with adequate ventilation. This material is hygroscopic in nature. See Section 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION.
Product name: FROTH-PAK™ POLYOL HFO Issue Date: 00/00/0000 Further information: A4: Not classifiable as a human carcinogen; Skin: Danger of cutaneous absorption CAL PEL PEL 0.1 mg/m3 , Tin STEL 0.
Product name: FROTH-PAK™ POLYOL HFO Color Issue Date: 00/00/0000 yellow Odor No information available. Odor Threshold No data available pH No data available Melting point/range No data available Freezing point Boiling point (760 mmHg) No data available No data available Flash point > 200 °C ( > 392 °F) Evaporation Rate (Butyl Acetate = 1) Not available Flammability (solid, gas) Not applicable to liquids Not expected to form explosive dustair mixtures.
Product name: FROTH-PAK™ POLYOL HFO Issue Date: 00/00/0000 Incompatible materials: Avoid contact with oxidizing materials. Avoid contact with: Strong acids. Strong bases. Avoid unintended contact with isocyanates. The reaction of polyols and isocyanates generates heat. Hazardous decomposition products: Decomposition products depend upon temperature, air supply and the presence of other materials. Decomposition products can include and are not limited to: Carbon dioxide. Alcohols. Ethers. Hydrocarbons.
Product name: FROTH-PAK™ POLYOL HFO Issue Date: 00/00/0000 Product test data not available. Refer to component data. COMPONENTS INFLUENCING TOXICOLOGY: 2-Ethylhexanoic acid potassium salt Acute oral toxicity Information given is based on data obtained from similar substances. LC50, Rat, 2,043 mg/kg OECD Test Guideline 401 Acute dermal toxicity Information given is based on data obtained from similar substances.
Product name: FROTH-PAK™ POLYOL HFO Issue Date: 00/00/0000 Aspiration Hazard No aspiration toxicity classification Tris(1-chloro-2-propyl) phosphate Acute oral toxicity LD50, Rat, male and female, >1,000 mg/kg Acute dermal toxicity LD50, Rabbit, > 5,000 mg/kg Acute inhalation toxicity No deaths occurred at this concentration. LC50, Rat, 4 Hour, dust/mist, > 7 mg/l Skin corrosion/irritation Prolonged contact may cause slight skin irritation with local redness.
Product name: FROTH-PAK™ POLYOL HFO Issue Date: 00/00/0000 LD50, Guinea pig, > 21,400 mg/kg Acute inhalation toxicity LC50, Rat, 4 Hour, dust/mist, > 2.35 mg/l No deaths occurred at this concentration. Skin corrosion/irritation Prolonged contact may cause slight skin irritation with local redness. Serious eye damage/eye irritation May cause moderate eye irritation. May cause slight corneal injury. Sensitization Did not cause allergic skin reactions when tested in guinea pigs.
Product name: FROTH-PAK™ POLYOL HFO Issue Date: 00/00/0000 Skin corrosion/irritation No hazard from gas. Skin contact with the solid ("dry ice") may cause frostbite. Liquid may cause frostbite upon skin contact. Serious eye damage/eye irritation No hazard from gas. Eye contact with the solid ("dry ice") may cause freeze burns. Liquid may cause frostbite. Sensitization No relevant data found. For respiratory sensitization: No relevant data found.
Product name: FROTH-PAK™ POLYOL HFO Issue Date: 00/00/0000 No relevant data found. Sensitization Did not cause allergic skin reactions when tested in humans. For respiratory sensitization: No relevant data found. Specific Target Organ Systemic Toxicity (Single Exposure) Evaluation of available data suggests that this material is not an STOT-SE toxicant.
Product name: FROTH-PAK™ POLYOL HFO Issue Date: 00/00/0000 For respiratory sensitization: No relevant data found. Specific Target Organ Systemic Toxicity (Single Exposure) Evaluation of available data suggests that this material is not an STOT-SE toxicant. Specific Target Organ Systemic Toxicity (Repeated Exposure) Recent findings of kidney failure and death in burn patients, as well as some studies using animal burn models, suggest that polyethylene glycol may have been a factor.
Product name: FROTH-PAK™ POLYOL HFO Issue Date: 00/00/0000 Sensitization Did not cause allergic skin reactions when tested in humans. Did not cause allergic skin reactions when tested in guinea pigs. For respiratory sensitization: No relevant data found. Specific Target Organ Systemic Toxicity (Single Exposure) The substance or mixture is not classified as specific target organ toxicant, single exposure.
Product name: FROTH-PAK™ POLYOL HFO Issue Date: 00/00/0000 Specific Target Organ Systemic Toxicity (Single Exposure) Available data are inadequate to determine single exposure specific target organ toxicity. Specific Target Organ Systemic Toxicity (Repeated Exposure) No relevant data found. Carcinogenicity No relevant data found. Teratogenicity No relevant data found. Reproductive toxicity No relevant data found.
Product name: FROTH-PAK™ POLYOL HFO Issue Date: 00/00/0000 Carcinogenicity No relevant data found. Teratogenicity No relevant data found. Reproductive toxicity No relevant data found. Mutagenicity No relevant data found. Aspiration Hazard Based on physical properties, not likely to be an aspiration hazard. 12. ECOLOGICAL INFORMATION Ecotoxicological information appears in this section when such data is available.
Product name: FROTH-PAK™ POLYOL HFO Issue Date: 00/00/0000 Toxicity to bacteria EC50, activated sludge, Respiration inhibition, 3 Hour, 784 mg/l, OECD 209 Test Chronic toxicity to aquatic invertebrates NOEC, Daphnia magna (Water flea), semi-static test, 21 d, number of offspring, 32 mg/l Triethyl phosphate Acute toxicity to fish Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
Product name: FROTH-PAK™ POLYOL HFO Issue Date: 00/00/0000 Acute toxicity to aquatic invertebrates LC50, Daphnia magna (Water flea), 48 Hour, > 10,000 mg/l Acute toxicity to algae/aquatic plants ErC50, Skeletonema costatum (marine diatom), 72 Hour, Growth rate, > 100 mg/l Diethylene glycol Acute toxicity to fish Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
Product name: FROTH-PAK™ POLYOL HFO Issue Date: 00/00/0000 Biodegradability: Readily biodegradable. Information given is based on data obtained from similar substances. Biodegradation: 99 % Exposure time: 28 d Tris(1-chloro-2-propyl) phosphate Biodegradability: Material is expected to biodegrade very slowly (in the environment). Fails to pass OECD/EEC tests for ready biodegradability. Material is ultimately biodegradable (reaches > 70% mineralization in OECD test(s) for inherent biodegradability).
Product name: FROTH-PAK™ POLYOL HFO Issue Date: 00/00/0000 Theoretical Oxygen Demand: 1.67 mg/mg Diethylene glycol Biodegradability: Material is readily biodegradable. Passes OECD test(s) for ready biodegradability. 10-day Window: Pass Biodegradation: 90 - 100 % Exposure time: 20 d Method: OECD Test Guideline 301A or Equivalent 10-day Window: Not applicable Biodegradation: 82 - 98 % Exposure time: 28 d Method: OECD Test Guideline 302C or Equivalent Theoretical Oxygen Demand: 1.
Product name: FROTH-PAK™ POLYOL HFO Issue Date: 00/00/0000 Bioaccumulation: Bioaccumulation is unlikely. Partition coefficient: n-octanol/water(log Pow): -1.98 at 20 °C Bioconcentration factor (BCF): 100 Fish Measured Dimethylbis((1-oxoneodecyl)oxy)stannane Partition coefficient: n-octanol/water(log Pow): 5.503 Nitrogen Bioaccumulation: Partitioning from water to n-octanol is not applicable.
Product name: FROTH-PAK™ POLYOL HFO Issue Date: 00/00/0000 13. DISPOSAL CONSIDERATIONS Disposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local laws and regulations. Regulations may vary in different locations. Waste characterizations and compliance with applicable laws are the responsibility solely of the waste generator.
Product name: FROTH-PAK™ POLYOL HFO Issue Date: 00/00/0000 15.
Product name: FROTH-PAK™ POLYOL HFO Issue Date: 00/00/0000 Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this document. Legend ACGIH CAL PEL Dow IHG OSHA Z-1 PEL STEL TWA US WEEL USA. ACGIH Threshold Limit Values (TLV) California permissible exposure limits for chemical contaminants (Title 8, Article 107) Dow Industrial Hygiene Guideline USA.
Product name: FROTH-PAK™ POLYOL HFO Issue Date: 00/00/0000 DDP Specialty Electronic Materials US, LLC urges each customer or recipient of this (M)SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this (M)SDS and any hazards associated with the product. The information herein is provided in good faith and believed to be accurate as of the effective date shown above.
SAFETY DATA SHEET DDP Specialty Electronic Materials US, LLC Product name: FROTH-PAK™ ISO AF HFO Issue Date: 00/00/0000 Print Date: 01/11/2022 DDP Specialty Electronic Materials US, LLC encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions. 1.
Product name: FROTH-PAK™ ISO AF HFO Issue Date: 00/00/0000 Signal word: DANGER! Hazards Contains gas under pressure; may explode if heated. Causes skin and eye irritation. May cause an allergic skin reaction. Harmful if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. May cause damage to organs (Respiratory Tract) through prolonged or repeated exposure if inhaled. May displace oxygen and cause rapid suffocation.
Product name: FROTH-PAK™ ISO AF HFO This product is a mixture. Component Issue Date: 00/00/0000 CASRN Concentration Diphenylmethane Diisocyanate, isomers and homologues 9016-87-9 > 60.0 - <= 80.0 % 4,4' -Methylenediphenyl diisocyanate 101-68-8 > 20.0 - <= 40.0 % trans-1-Chloro-3,3,3-trifluoropropene 102687-65-0 > 0.0 - < 20.0 % Carbon dioxide 124-38-9 >= 1.0 - < 5.0 % Nitrogen 7727-37-9 >= 0.1 - < 0.5 % Note Note: CAS 101-68-8 is an MDI isomer that is part of CAS 9016-87-9. 4.
Product name: FROTH-PAK™ ISO AF HFO Issue Date: 00/00/0000 Aside from the information found under Description of first aid measures (above) and Indication of immediate medical attention and special treatment needed (below), any additional important symptoms and effects are described in Section 11: Toxicology Information. Indication of any immediate medical attention and special treatment needed Notes to physician: Maintain adequate ventilation and oxygenation of the patient.
Product name: FROTH-PAK™ ISO AF HFO Issue Date: 00/00/0000 not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight fire from a remote location. For protective equipment in post-fire or non-fire clean-up situations, refer to the relevant sections. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures: Isolate area. Keep unnecessary and unprotected personnel from entering the area.
Product name: FROTH-PAK™ ISO AF HFO Dow IHG ACGIH Issue Date: 00/00/0000 STEL TWA 0.02 ppm 0.005 ppm Further information: resp sens: Respiratory sensitization OSHA Z-1 C 0.2 mg/m3 0.02 ppm Further information: (b): The value in mg/m3 is approximate.; ©: Ceiling limit is to be determined from breathing-zone air samples. trans-1-Chloro-3,3,3trifluoropropene Carbon dioxide OSHA P0 US WEEL C TWA 0.2 mg/m3 0.
Product name: FROTH-PAK™ ISO AF HFO Issue Date: 00/00/0000 Respiratory protection: Atmospheric levels should be maintained below the exposure guideline. When atmospheric levels may exceed the exposure guideline, use an approved air-purifying respirator equipped with an organic vapor sorbent and a particle filter.
Product name: FROTH-PAK™ ISO AF HFO Issue Date: 00/00/0000 NOTE: The physical data presented above are typical values and should not be construed as a specification. 10. STABILITY AND REACTIVITY Reactivity: No data available Chemical stability: Stable under recommended storage conditions. See Storage, Section 7. Possibility of hazardous reactions: Can occur. Elevated temperatures can cause hazardous polymerization. Polymerization can be catalyzed by: Strong bases. Water.
Product name: FROTH-PAK™ ISO AF HFO Issue Date: 00/00/0000 Serious eye damage/eye irritation Product test data not available. Refer to component data. Sensitization Product test data not available. Refer to component data. Specific Target Organ Systemic Toxicity (Single Exposure) Product test data not available. Refer to component data.
Product name: FROTH-PAK™ ISO AF HFO Issue Date: 00/00/0000 Prolonged contact may cause slight skin irritation with local redness. May stain skin. Serious eye damage/eye irritation May cause moderate eye irritation. May cause slight temporary corneal injury. Sensitization Skin contact may cause an allergic skin reaction. Animal studies have shown that skin contact with isocyanates may play a role in respiratory sensitization. May cause allergic respiratory reaction.
Product name: FROTH-PAK™ ISO AF HFO Issue Date: 00/00/0000 MDI concentrations below the exposure guidelines may cause allergic respiratory reactions in individuals already sensitized. Asthma-like symptoms may include coughing, difficult breathing and a feeling of tightness in the chest. Occasionally, breathing difficulties may be life threatening. Specific Target Organ Systemic Toxicity (Single Exposure) May cause respiratory irritation.
Product name: FROTH-PAK™ ISO AF HFO Issue Date: 00/00/0000 Acute inhalation toxicity LC50, Rat, 4 hrs, gas, 58750 ppm Skin corrosion/irritation No hazard from gas. Skin contact with the solid ("dry ice") may cause frostbite. Liquid may cause frostbite upon skin contact. Serious eye damage/eye irritation No hazard from gas. Eye contact with the solid ("dry ice") may cause freeze burns. Liquid may cause frostbite. Sensitization No relevant data found. For respiratory sensitization: No relevant data found.
Product name: FROTH-PAK™ ISO AF HFO Issue Date: 00/00/0000 For respiratory sensitization: No relevant data found. Reproductive toxicity No relevant data found. Aspiration Hazard Based on physical properties, not likely to be an aspiration hazard. 12. ECOLOGICAL INFORMATION Ecotoxicological information appears in this section when such data is available.
Product name: FROTH-PAK™ ISO AF HFO Issue Date: 00/00/0000 Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
Product name: FROTH-PAK™ ISO AF HFO Issue Date: 00/00/0000 Persistence and degradability Diphenylmethane Diisocyanate, isomers and homologues Biodegradability: In the aquatic and terrestrial environment, material reacts with water forming predominantly insoluble polyureas which appear to be stable. In the atmospheric environment, material is expected to have a short tropospheric half-life, based on calculations and by analogy with related diisocyanates.
Product name: FROTH-PAK™ ISO AF HFO Issue Date: 00/00/0000 Carbon dioxide Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Partition coefficient: n-octanol/water(log Pow): 0.83 Measured Nitrogen Bioaccumulation: Partitioning from water to n-octanol is not applicable.
Product name: FROTH-PAK™ ISO AF HFO Reportable Quantity Issue Date: 00/00/0000 MDI Classification for SEA transport (IMO-IMDG): Proper shipping name CHEMICAL UNDER PRESSURE, N.O.S.(Carbon dioxide, Nitrogen) UN number UN 3500 Class 2.2 Packing group Marine pollutant No Transport in bulk Consult IMO regulations before transporting ocean bulk according to Annex I or II of MARPOL 73/78 and the IBC or IGC Code Classification for AIR transport (IATA/ICAO): Proper shipping name Chemical under pressure, n.o.s.
Product name: FROTH-PAK™ ISO AF HFO Issue Date: 00/00/0000 4,4' -Methylenediphenyl diisocyanate 101-68-8 Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) Section 103 Calculated RQ exceeds reasonably attainable upper limit.
Product name: FROTH-PAK™ ISO AF HFO Issue Date: 00/00/0000 Full text of other abbreviations AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the Testing of Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Substances List (Canada); ECx - Concentration asso
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