SDS

Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
11/11/2014 EN (English US) 4/6
1980 Vol.1, P.12, B-9, 10. Hydrogen gas may be flammable or explosive when mixed with air, oxygen, chlorine. Avoid open flames/
sparks/other sources of ignition near battery. To avoid risk of fire or explosion, keep sparks or other sources of ignition away from batteries
and do not allow metallic materials to simultaneously contact negative and positive teminals of cells and batteries. SULFURIC
ACID REACTS VIOLENTLY WITH WATER/ORGANICS.
5.3. Advice for firefighters
Firefighting instructions : Lead-acid batteries do not burn or burn with difficulty. Do not use water on fires where molten
metal is present. Extinguish fire with agent suitable for surrounding combustible materials. Cool
exterior of battery if exposed to fire to prevent rupture. The acid mist and vapors generated by
heat or fire are corrosive. Use NIOSH approved self-contained breathing apparatus (SCBA)
and full protective equipment ioerated in positive-pressure mode.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Acid resistant aprons, boots and protective clothing. ANSI approved safety glasses with side shields/face shield recommended. Ventilate enclosed
areas.
6.2. Environmental precautions
Lead and its compounds and sulfuric acid can pose a severe threat to the environment. Contamination of water, soil, and air should be prevented.
6.3. Methods and material for containment and cleaning up
Stop release, if possible. Anoid contact with any spilled material. Contain spill, isolate harzard area, and deny endry. Limit site access to emergency
reponders. Neutralize with sodium bicarbonate, soda ash, lime or other neutralizing agent. Place battery in suitable container for disposal. Dispose
of contaminated material in accordance with applicable local, state and federal regulations. Sodium bicarbonate, soda ash, sand, lime or other
neutralizing agent should be kept on-site for spill remediation.
SECTION 7: Handling and storage
7.1. Precautions for safe handling and storage
Keep away from flames during and immediately after charging. Combustion or overcharging may create or liberate toxic and hazardous gases and
liquids including hydrogen, sulfuric acid mist, sulfur dioxide, sulfur trioxide, stibine, arsine and sulfuric acid. Store batteries in cool, dry, well
ventilated area. Do not short circuit battery terminals, or remove vent caps during storage or recharging. Protect battery from physical damage.
7.2. Other Precautions
GOOD PERSONAL HYGIENE AND WORK PRACTICES ARE MANDATORY. Refrain from eating, drinking or smoking in work areas. Thoroughly
wash hands, face, neck, and arms before eating, drinking or smoking. Launder soiled clothing before reuse. Emptied batteries contain hazardous
sulfuric acid residue.
SECTION 8: Exposure controls/personal protection
Respiratory Protection(Specify Type) : Acid/gas NIOSH approved respirator is required when the PEL is exceeded or employee experiences
respiratory irritation. When exposure levels are unknown or when firefighting, wear a self-contained breathing apparatus with a full face piece
operated in a positive pressure mode.
Ventilation : Must be provided when charging in an enclosed area. Change air every 15min.
Local Exhaust : When PEL is exceeded.
Mechanical(General) : Normal mechanical ventilation recommended for stationary applications.
Protective Gloves : Wear rubber or plastic acid resistant gloves with elbow length gauntlet when filling batteries.
Eye Protection : ANSI approved safety glasses with side shields/face shield recommended safety goggles.
Other Protective Clothing or Equipment : Ventilation as described in the Industrial Ventilation Manual produced by the American Conference of
Govemmental Industrial Hygienists, shall be provided in areas where exposures are above the PEL or TLV specified by OSHA or other local, state
and federal regulations. Acid-resistant rubber or plastic apron, boots and protective clothing. Safety shower and eyewash.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Boiling Point
: Electrolyte Approx. 235
Specific Gravity
: Electrolyte 1.250-1.320 pH<2
Percent Volatile by Volume
: Not Applicable
Evaporation Rate
: Note Applicable
Reactivity in Water
: Electrolyte - water reactive(1)
Apperance and Odor
: Battery : Polypropylene or hard rubber case, solid.
Lead : Gray, metallic, solid
Electrolyte : Liquid, colorless, oily fluid; nuissance odor when got or charging battery.
Vapor Pressure
: Electrolyte 1mm Hg @ 145.8
Melting Point
: Polypropylene <320