Safety Data Sheet BLACK PVC 325 SDS Revision Date: 05/18/2015 1. Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product Identity BLACK PVC 325 Alternate Names BLACK PVC 325 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use See Technical Data Sheet. Application Method See Technical Data Sheet. 1.3.
[Disposal]: No GHS disposal statements 3. Composition/information on ingredients This product contains the following substances that present a hazard within the meaning of the relevant State and Federal Hazardous Substances regulations. Ingredient/Chemical Designations Weight % GHS Classification Notes Pigment Black 7 CAS Number: 0001333-86-4 25 - 50 Not Classified [1][2] Polyvinyl Chloride CAS Number: 0009002-86-2 25 - 50 Skin Irrit. 2;H315 Eye Dam.
5. Fire-fighting measures 5.1. Extinguishing media Extinguish with foam or water spray. 5.2. Special hazards arising from the substance or mixture Hazardous decomposition: Thermal decomposition is a function of both processing temperature and time at that temperature. Thermal decomposition can begin at 350F. Decomposition byproducts include oxides of carbon and nitrogen and hydrogen chloride. 5.3.
8. Exposure controls and personal protection 8.1. Control parameters Exposure CAS No. 0000471-34-1 0001333-86-4 0006422-86-2 0008013-07-8 0009002-86-2 0447451-00-5 Ingredient Source Calcium Carbonate Pigment Black 7 Di-octyl Terephthalate Epoxidized Soybean Oil Polyvinyl Chloride Polymer Additive 1 Value OSHA TWA 10 mg/m3 (total) TWA 5 mg/m3 (resp) ACGIH No Established Limit NIOSH TWA 10 mg/m3 (total) TWA 5 mg/m3 (resp) Supplier No Established Limit OSHA TWA 3.
0009002-86-2 0447451-00-5 Polyvinyl Chloride Polymer Additive 1 8.2.
Viscosity (cSt) Not Measured 9.2. Other information No other relevant information. 10. Stability and reactivity 10.1. Reactivity Hazardous Polymerization will not occur. 10.2. Chemical stability Stable under normal circumstances. 10.3. Possibility of hazardous reactions No data available. 10.4. Conditions to avoid No data available. 10.5. Incompatible materials No data available. 10.6.
Classification Category Hazard Description Acute toxicity (oral) --- Not Applicable Acute toxicity (dermal) --- Not Applicable Acute toxicity (inhalation) --- Not Applicable Skin corrosion/irritation --- Not Applicable Serious eye damage/irritation --- Not Applicable Respiratory sensitization --- Not Applicable Skin sensitization --- Not Applicable Germ cell mutagenicity --- Not Applicable Carcinogenicity --- Not Applicable Reproductive toxicity --- Not Applicable STOT-singl
No data available. 13. Disposal considerations 13.1. Waste treatment methods Observe all federal, state and local regulations when disposing of this substance. 14. Transport information 14.1. UN number 14.2. UN proper shipping name 14.3. Transport hazard class(es) 14.4.
Proposition 65 - Developmental Toxins (>0.0%): (No Product Ingredients Listed) Proposition 65 - Female Repro Toxins (>0.0%): (No Product Ingredients Listed) Proposition 65 - Male Repro Toxins (>0.0%): (No Product Ingredients Listed) N.J. RTK Substances (>1%): Pigment Black 7 Penn RTK Substances (>1%): Pigment Black 7 16. Other information The information and recommendations contained herein are based upon data believed to be correct.
Hoffman Plastic Compounds, Inc. ISO 9001:2008 Company Safety Data Sheet (SDS) In compliance with 1907 / 2006 / EC, Article 31 1. Product Identification Product Name: V0-412 NATURAL Effective Date: JUNE 23, 2015 Product Type: Flexible Polyvinyl Chloride (PVC) Compound Synonyms: chloroethylene homopolymer compound Chemical formula: (C2H3Cl)n CAS: N/A (Mixture) Product Use: Extrusion and compounding, injection molded parts, extruded parts, films, coatings.
(323) 636-3346
2. Hazard(s) Identification PRECAUTIONARY INFORMATION Caution: If proper procedures for processing PVC compounds are not followed, processing vapors can be liberated at elevated temperatures. The presence of these vapors may result in exposure. Additionally, the composition of these fumes or vapors may vary widely according to the individual processing procedures and materials used. Processors must determine for themselves the appropriate equipment and procedures for their operation.
2. Hazard(s) Identification (continued) HAZARD CLASSIFICATION 1 Acute Effects 1.1. Dust associated with the handling of PVC powder as well as vapors or fumes liberated from PVC compound at high temperatures may be irritating to the eyes, skin and respiratory tract if not adequately ventilated. 2 Chronic Effects 2.1.
3. Composition / Information on Ingredients Compounded PVC is in inert material in its normal state in either pellets, or granules.
5. Fire Fighting Measures Properties Flashpoint Auto-ignition temperature (ASTM D1929) Flammable limits in air (% by volume) Upper: Lower: Extinguishing Media Description > 600ºF +850ºF N/A N/A Water, Dry Chemical Special Firefighting Procedures: Wear NIOSH/MSHA approved self-contained breathing apparatus & full protective clothing in fire conditions. Unusual Fire Hazards: Decomposition by burning (generating HCL gas). 6. Accidental Release Measures 1 Protect People 1.1.
7. Handling and Storage 1 Advice on Safe Handling 1.1. Use the proper personal protective equipment during handling. Minimize dust generation and accumulation. Use good housekeeping practices. 2 Protective measures 2.1. Use methods to minimize generation of dust. Wash thoroughly after handling. PVC resin and compound processing under extreme temperatures beyond normal processing temperatures may result in the release of hydrogen chloride (HCl). Use only in well-ventilated areas. 3 Storage 3.1.
8. Exposure Controls / Personal Protection (continued) Exposure Guidelines No exposure limits have been established for this material. It is recommended that exposure be kept below the limits for particulates not otherwise classified. OSHA-PEL: 15 mg/M3 8 hr-TWA (total dust) 5 mg/M3 8 hr-TWA (respirable) The American Conference of Governmental Industrial Hygienist (ACGIH) has established a Threshold Limit Value (TLV) (based on an 8-HR TWA exposure) of 1 mg/m3 for the respirable fraction.
10. Stability & Reactivity 1 Stability 1.1. Stable under normal conditions. 2 Polymerization 2.1. Hazardous polymerization does not occur. 3 Conditions to Avoid 3.1. Instantaneous temperatures above 235 C(455 F), prolonged heating at processing temperatures, or excessive shear/heat combinations during processing can generate hazardous decomposition products. 4 Hazardous Decomposition Products 4.1. Overheating may cause thermal degradation of PVC compound.
12. Ecological Information Environmental Concerns 1. Aquatic a. No data available. 2. Biodegradation a. Not subject to biodegradation. 3. Ecological toxicity a. Based on the high molecular weight of this polymeric material, transport of this compound across biological membranes is unlikely. b. Accordingly, the probability of environmental toxicity or bioaccumulation in organisms is remote. c. Due caution should be exercised to prevent the accidental release of this material to the environment. 13.
15. Regulatory Information Regulatory information is not meant to be all-inclusive. It is the user’s responsibility to ensure compliance with federal, state or provincial and local laws. SARA Title III Section 302 and 304 of the Act; Extremely Hazardous Substances (40 CFR 355) Component None CAS No.
Canadian Regulations This product has been classified according to the hazard criteria of the Canadian Controlled Products Regulations, Section 33 and the SDS contains all information required by this regulation. WHMIS Classification- Not a Controlled Product.
15. Regulatory Information (continued) OSHA 29 CFR 1910.1017 This compound may contain trace levels (<0.001%) of VCM. Under normal working conditions with adequate ventilation, neither the OSHA-PEL of 1 ppm (8-hr TWA), nor the OSHA-STEL (5.0 ppm) should be exceeded. The workplace should be monitored and if the level exceeds any of the PELs or action levels, refer to 29 CFR 1910.1017. 16.
