SAFETY DATA SHEET Issuing Date 15-Jun-2015 Revision Date 13-Apr-2016 Revision Number 2 _____________________________________________________________________________________________ The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS, and all information in this SDS was provided by the supplier or was reproduced from publically available regulatory data sources.
1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W Revision Date 13-Apr-2016 _____________________________________________________________________________________________ Acute toxicity - Oral Acute toxicity - Inhalation (Gases) Acute toxicity - Inhalation (Vapors) Acute toxicity - Inhalation (Dusts/Mists) Skin corrosion/irritation Serious eye damage/eye irritation Skin sensitization Carcinogenicity Reproductive Toxicity Specific target organ toxicity (single exposure) Specific target organ toxic
1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W Revision Date 13-Apr-2016 _____________________________________________________________________________________________ Specific treatment (see supplemental first aid instructions on this label) Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W Revision Date 13-Apr-2016 _____________________________________________________________________________________________ First aid measures General Advice This is a battery. In case of rupture:. Immediate medical attention is required. Show this safety data sheet to the doctor in attendance. Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing.
1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W Revision Date 13-Apr-2016 _____________________________________________________________________________________________ 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media CAUTION: Use of water spray when fighting fire may be inefficient.
Revision Date 13-Apr-2016 1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W _____________________________________________________________________________________________ 7. HANDLING AND STORAGE Precautions for safe handling Handling In case of rupture. Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Use personal protection equipment.
Revision Date 13-Apr-2016 1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W _____________________________________________________________________________________________ (vacated) TWA: 2.
Revision Date 13-Apr-2016 1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W _____________________________________________________________________________________________ Lower flammability limit No data available Vapor pressure No data available Vapor density No data available Specific Gravity No data available Water Solubility Insoluble in water Solubility in other solvents No data available Partition coefficient: n-octanol/water No data available Autoignition temperature No data available Decom
Revision Date 13-Apr-2016 1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W _____________________________________________________________________________________________ Eye contact Specific test data for the substance or mixture is not available. Causes burns. (based on components). Corrosive to the eyes and may cause severe damage including blindness. Causes serious eye damage. May cause irreversible damage to eyes.
04983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W Revision Date 13-Apr-2016 _____________________________________________________________________________________________ cause chronic conditions. Contains a known or suspected carcinogen. Contains a known or suspected reproductive toxin. Possible risk of irreversible effects. Avoid repeated exposure. Prolonged exposure may cause chronic effects. Target Organ Effects Aspiration Hazard Eyes. Respiratory system. Skin. Gastrointestinal tract (GI).
Revision Date 13-Apr-2016 1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W _____________________________________________________________________________________________ 12. ECOLOGICAL INFORMATION Ecotoxicity Harmful to aquatic life. Very toxic to aquatic life with long lasting effects. Chemical name Toxicity to Algae Zinc 7440-66-6 Toxicity to Fish Toxicity to Microorganisms 96h EC50: 0.11 - 0.271 96h LC50: = 3.
Revision Date 13-Apr-2016 1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W _____________________________________________________________________________________________ 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal methods This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261).
Revision Date 13-Apr-2016 1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W _____________________________________________________________________________________________ TSCA DSL Complies All components are listed either on the DSL or NDSL.
Revision Date 13-Apr-2016 1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W _____________________________________________________________________________________________ Zinc 7440-66-6 Potassium hydroxide 1310-58-3 Manganese dioxide 1313-13-9 Graphite 7782-42-5 X X X X X X X X X X X X X X International Regulations Chemical name Manganese dioxide Carcinogen Status Exposure Limits Mexico: TWA= 0.2 mg/m3 Steel manufacture, chemicals A3 A2 Mexico: TWA 0.15 mg/m3 Mexico: TWA 0.
Page 1 of 5 Coin/Button Lithium Manganese Dioxide Batteries March 2015 PRODUCT SAFETY DATA SHEET PRODUCT NAME: Energizer Battery Type No.: TRADE NAMES: Coin/Button Lithium Manganese Dioxide Batteries CHEMICAL SYSTEM: Lithium Manganese Dioxide Volts: 3.0 Approximate Weight: 0.6 – 7.0 g Designed for Recharge: No Energizer has prepared copyrighted Product Safety Datasheets to provide information on the different Eveready/Energizer battery systems.
Page 2 of 5 Coin/Button Lithium Manganese Dioxide Batteries March 2015 Lithium Perchlorate (CAS# 7791-03-9) None established None established 0-3 Lithium Trifluoromethanesulfonate (CAS# 33454-82-9) None established None established 0-3 Lithium Trifluoromethanesulfonimide (CAS# 90076-65-6) None established None established 0-3 Manganese Dioxide (CAS# 1313-13-9) 5 mg/m3 Ceiling (as Mn) 0.
Page 3 of 5 Coin/Button Lithium Manganese Dioxide Batteries March 2015 Handling: Accidental short circuit for a few seconds will not seriously affect the battery. Prolonged short circuit will cause the battery to lose energy, generate significant heat and can cause the safety release vent to open. Sources of short circuits include jumbled batteries in bulk containers, metal jewelry, metal covered tables or metal belts used for assembly of batteries into devices.
Page 4 of 5 Coin/Button Lithium Manganese Dioxide Batteries March 2015 Density (g/cm3) 2.0-3.
Page 5 of 5 Coin/Button Lithium Manganese Dioxide Batteries March 2015 Energizer is registered with CHEMTREC. In the event of an incident during transport call 1-800-424-9300 (North America) or 1-703-527-3887 (International). A global lithium label chart is provided below to summarize the current global labeling requirements. Label Summary Chart Shipping Mode AIR Land/ Sea only Li content Net quantity wt. of batteries per package Battery Type 0.3g to <1g/cell 0.3g to <2g/ battery <2.