MSDS

Toluene
CAS:
108-88-3
EINECS:
203-
625-9
20%
TO
40%
Ingestion/Oral
-
Rat
LD50
636 mg/kg
Inhalation
-
Rat LC50
49 g/m
³ 4 Hour(s)
Skin
-
Rabbit LD50
14100 µ
L/kg
EU DSD/DPD:
Annex VI, Table 3.2 -
F; R11; Repr. 3;
R63; Xn; R48/20
-
65; Xi; R38; R67
EU CLP:
Annex VI, Table 3.1 -
Flam. Liq. 2, H225;
Repr. 2, H361d; Asp. Tox. 1, H304; STOT RE 2*, H373;
Skin Irrit. 2, H315; STOT SE 3: Narc., H336
OSHA HCS 2012:
Flam. Liq. 2; Repr. 2; Acute Tox. 4
(Oral); STOT SE 3: Narc.; Asp. Tox. 1; Eye Irrit. 2; Skin
Irrit. 2
NDA
Silica,
amorphous
fumed
CAS:
112945-
52-5
< 5%
Ingestion/Oral
-
Rat
LD50
3160 mg/kg
EU DSD/DPD:
Not Classified
EU CLP:
Not Classified
OSHA HCS 2012:
Not Classified
NDA
Section 4
-
First Aid Measures
4.1 Description of first aid measures
Inhalation
Move victim to fresh air.
Administer oxygen if breathing is difficult.
Give artificial
respiration if victim is not breathing. Get medical attention.
Skin
Remove and isolate contaminated clothing. Wash skin with soap and water. If irritation
develops and persists, get medical attention.
Eye
In case of contact with substance, immediately flush eyes with running water for at
least 20 minutes. If eye irritation persists: Get medical advice/attention.
Ingestion
Get medical attention immediately.
4.2 Most important symptoms and effects, both acute and delayed
Refer to Section 11
-
Toxicological Information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to Physician
All treatments should be based on observed signs and symptoms of distress in the
patient. Consideration should be given to the possibility that overexposure to materials
other than this product may have occurred.
Section 5
-
Firefighting Measures
5.1 Extinguishing media
Suitable Extinguishing Media
Carbon dioxide, sand, extinguishing powder.
Unsuitable Extinguishing
Media
Water
5.2 Special hazards arising from the substance or mixture
Unusual Fire and Explosion
Hazards
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
Containers may explode when heated.
Vapor explosion hazard indoors, outdoors or in sewers.
Many liquids are lighter than water.
Most vapors are heavier than air. They will spread along ground and collect in low or
confined areas (sewers, basements, tanks).
Runoff to sewer may create fire or explosion hazard.
Vapors may form explosive mixtures with air.
Vapors may travel to source of ignition and flash back.
Hazardous Combustion
Products
Carbon oxides, nitrogen oxides, silicon oxides.
5.3 Advice for firefighters
Structural firefighters' protective clothing will only provide limited protection.
Wear positive pressure self
-
contained breathing apparatus (SCBA).
Move containers from fire area if you can do it without risk.
LARGE FIRES: Fight fire from maximum distance or use unmanned hose holders or
All Purpose PrimerAll Purpose PrimerAll Purpose PrimerAll Purpose Primer
Preparation Date:Preparation Date:Preparation Date:Preparation Date:
Revision Date:Revision Date:Revision Date:Revision Date:
Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)
WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012
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