SAFETY DATA SHEET THE DOW CHEMICAL COMPANY Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 Print Date: 06/11/2018 THE DOW CHEMICAL COMPANY encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions. 1.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 Signal word: DANGER! Hazards Flammable aerosol. Contains gas under pressure; may explode if heated. Causes skin and eye irritation. May cause an allergic skin reaction. Harmful if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. May cause harm to breast-fed children.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 Disposal Dispose of contents/ container to an approved waste disposal plant. Other hazards No data available 3. COMPOSITION/INFORMATION ON INGREDIENTS This product is a mixture. Component CASRN Concentration Diphenylmethane Diisocyanate, isomers and homologues 9016-87-9 >= 10.0 - <= 30.0 % 4,4'-Methylenediphenyl diisocyanate 101-68-8 >= 10.0 - <= 30.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by qualified personnel. Call a physician or transport to a medical facility. Skin contact: Remove material from skin immediately by washing with soap and plenty of water.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 Unusual Fire and Explosion Hazards: Contains flammable propellant. Aerosol cans exposed to fire can rupture and become flaming projectiles. Propellant release may result in a fireball. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Dense smoke is produced when product burns.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 prolonged or repeated contact with skin. Avoid breathing vapor. Never use air pressure for transferring product. Wash thoroughly after handling. Keep container closed. Use only with adequate ventilation. Keep out of reach of children. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Contents under pressure.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 Eye/face protection: Use safety glasses (with side shields). Skin protection Hand protection: Use gloves chemically resistant to this material. Examples of preferred glove barrier materials include: Butyl rubber. Chlorinated polyethylene. Polyethylene. Ethyl vinyl alcohol laminate ("EVAL"). Examples of acceptable glove barrier materials include: Neoprene.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Relative Vapor Density (air = 1) Relative Density (water = 1) Water solubility Partition coefficient: noctanol/water Auto-ignition temperature Decomposition temperature Kinematic Viscosity Explosive properties Oxidizing properties Molecular weight Issue Date: 06/07/2018 No test data available 1.06 Estimated.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal handling operations are not likely to cause injury; however, swallowing larger amounts may cause injury. Observations in animals include: Gastrointestinal irritation. As product: Single dose oral LD50 has not been determined. LD50, Rat, > 2,000 mg/kg Estimated.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 Tissue injury in the upper respiratory tract and lungs has been observed in laboratory animals after repeated excessive exposures to MDI/polymeric MDI aerosols. Carcinogenicity Lung tumors have been observed in laboratory animals exposed to respirable aerosol droplets of MDI/Polymeric MDI (6 mg/m3) for their lifetime. Tumors occurred concurrently with respiratory irritation and lung injury.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 The LC50 has not been determined. Tris(1-chloro-2-propyl) phosphate Acute inhalation toxicity No deaths occurred at this concentration. LC50, Rat, 4 Hour, dust/mist, > 7 mg/l Paraffin waxes and Hydrocarbon waxes, chlorinated Acute inhalation toxicity The LC50 has not been determined.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 Based on information for a similar material: NOEC, Desmodesmus subspicatus (green algae), static test, 72 Hour, Growth rate inhibition, 1,640 mg/l, OECD Test Guideline 201 or Equivalent Toxicity to bacteria Based on information for a similar material: EC50, activated sludge, static test, 3 Hour, Respiration rates.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol copolymer Acute toxicity to fish Not expected to be acutely toxic to aquatic organisms. Tris(1-chloro-2-propyl) phosphate Acute toxicity to fish Material is slightly toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and 100 mg/L in the most sensitive species tested).
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 Persistence and degradability Diphenylmethane Diisocyanate, isomers and homologues Biodegradability: In the aquatic and terrestrial environment, material reacts with water forming predominantly insoluble polyureas which appear to be stable. In the atmospheric environment, material is expected to have a short tropospheric half-life, based on calculations and by analogy with related diisocyanates.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 Biodegradation: 5 % Exposure time: 28 d Method: OECD Test Guideline 301D Theoretical Oxygen Demand: 2.89 mg/mg Isobutane Biodegradability: Biodegradation may occur under aerobic conditions (in the presence of oxygen). Theoretical Oxygen Demand: 3.58 mg/mg Photodegradation Test Type: Half-life (indirect photolysis) Sensitization: OH radicals Atmospheric half-life: 4.4 d Method: Estimated.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 4,4'-Methylenediphenyl diisocyanate Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Reacts with water. In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 Potential for mobility in soil is slight (Koc between 2000 and 5000). Partition coefficient (Koc): 1300 Estimated. Paraffin waxes and Hydrocarbon waxes, chlorinated Expected to be relatively immobile in soil (Koc > 5000). Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is not expected to be an important fate process.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Marine pollutant Transport in bulk according to Annex I or II of MARPOL 73/78 and the IBC or IGC Code Issue Date: 06/07/2018 Paraffin waxes and Hydrocarbon waxes, chlorinated Consult IMO regulations before transporting ocean bulk Classification for AIR transport (IATA/ICAO): Proper shipping name Aerosols, flammable UN number UN 1950 Class 2.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Propane Issue Date: 06/07/2018 74-98-6 California Prop. 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. United States TSCA Inventory (TSCA) All components of this product are in compliance with the inventory listing requirements of the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. 16.
Product name: GREAT STUFF™ Gaps & Cracks Insulating Foam Sealant 12oz HC ES SASTW 12ct Issue Date: 06/07/2018 MSHA - Mine Safety and Health Administration; n.o.s.
