MSDS

Product Name: GREAT STUFF(TM) Gaps & Cracks Insulating
Foam Sealant 16oz HC QP
Issue Date: 12/11/2012
Page 9 of 13
Persistence and Degradability
Data for Component: Diphenylmethane Diisocyanate, isomers and homologues
In the aquatic and terrestrial environment, material reacts with water forming predominantly
insoluble polyureas which appear to be stable. In the atmospheric environment, material is
expected to have a short tropospheric half-life, based on calculations and by analogy with
related diisocyanates.
OECD Biodegradation Tests: Based on information for a similar material:
Biodegradation
Exposure Time
Method
10 Day Window
0 %
28 d
OECD 302C Test
Not applicable
Data for Component: 4,4 -Methylenediphenyl diisocyanate
In the aquatic and terrestrial environment, material reacts with water forming predominantly
insoluble polyureas which appear to be stable. In the atmospheric environment, material is
expected to have a short tropospheric half-life, based on calculations and by analogy with
related diisocyanates.
OECD Biodegradation Tests: Based on information for a similar material:
Biodegradation
Exposure Time
Method
10 Day Window
0 %
28 d
OECD 302C Test
Not applicable
Data for Component: Isocyanic acid, polymethylenepolyphenylene ester, polymer with
.alpha.,.alpha.,.alpha.-1,2,3-propanetriyltris[.omega.-hydroxypoly
Expected to degrade only slowly in the environment.
Data for Component: Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol copolymer
Expected to degrade only slowly in the environment.
Data for Component: Tris(1-chloro-2-propyl) phosphate
Material is expected to biodegrade only very slowly (in the environment). Fails to pass
OECD/EEC tests for ready biodegradability.
OECD Biodegradation Tests:
Biodegradation
Exposure Time
Method
10 Day Window
14 %
28 d
OECD 301E Test
fail
95 %
64 d
OECD 302A Test
Not applicable
Indirect Photodegradation with OH Radicals
Rate Constant
Atmospheric Half-life
Method
4.47E-11 cm3/s
0.24 d
Estimated.
Theoretical Oxygen Demand: 1.17 mg/mg
Data for Component: Paraffin waxes and Hydrocarbon waxes, chlorinated
Expected to degrade only slowly in the environment.
Theoretical Oxygen Demand: 2.89 mg/mg
Data for Component: Isobutane
Biodegradation may occur under aerobic conditions (in the presence of oxygen).
Indirect Photodegradation with OH Radicals
Rate Constant
Atmospheric Half-life
Method
2.44E-12 cm3/s
4.4 d
Estimated.
Theoretical Oxygen Demand: 3.58 mg/mg
Data for Component: Methyl ether
Material is expected to biodegrade only very slowly (in the environment). Fails to pass
OECD/EEC tests for ready biodegradability.
OECD Biodegradation Tests:
Biodegradation
Exposure Time
Method
10 Day Window
5 %
28 d
OECD 301A Test
fail
Indirect Photodegradation with OH Radicals
Rate Constant
Atmospheric Half-life
Method
1.66E-12 cm3/s
6.4 d
Estimated.
Theoretical Oxygen Demand: 2.08 mg/mg