SDS

Legend:
– Data available but does not fill the criteria for classification
– Data available to make classification
– Data Not Available to make classification
test data Test Type: DNA damage and repair, unscheduled DNA synthesis in mammalian cells (in vitro) Result: negative Remarks: Based on test data
Genotoxicity in vivo : Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay) Species: Rat Application Route: inhalation (vapor)
Result: negative Remarks: Based on test data Test Type: Rodent dominant lethal test (germ cell) (in vivo) Species: Rat Application Route: Ingestion Result:
negative Remarks: Based on test data Germ cell mutagenicity - Assessment : Animal testing did not show any mutagenic effects Effects on fertility : Test
Type: Two-generation reproduction toxicity study Species: Rat, male and female Application Route: inhalation (vapor) Symptoms: Effects on fertility.
Remarks: Based on test data Effects on fetal development : Test Type: Prenatal development toxicity study (teratogenicity) Species: Rabbit Application
Route: inhalation (vapor) Symptoms: No effects on fetal development. Remarks: Based on test data Reproductive toxicity - Assessment : Some evidence of
adverse effects on sexual function and fertility, based on animal experiments. STOT-single exposure May cause damage to organs (Eyes, Central nervous
system Routes of exposure: Ingestion Assessment: No significant health effects observed in animals at concentrations of 100 mg/kg bw or less. Routes of
exposure: inhalation (vapor) Assessment: No significant health effects observed in animals at concentrations of 1 mg/l/6h/d or less. Routes of exposure:
Skin contact Assessment: No significant health effects observed in animals at concentrations of 200 mg/kg bw or less. Results from a 2 year repeated vapor
inhalation exposure study to rats of octamethylcyclotetrasiloxane (D4) indicate effects (benign uterine adenomas) in the uterus of female animals. This
finding occurred at the highest exposure dose (700 ppm) only. Studies to date have not demonstrated if these effects occur through pathways that are
relevant to humans. Repeated exposure in rats to D4 resulted in protoporphyrin accumulation in the liver.
propane & octyltriethoxysilane
& titanium(IV) butoxide
No significant acute toxicological data identified in literature search.
methyltrimethoxysilane &
titanium(IV) butoxide &
octamethylcyclotetrasiloxane
The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated or prolonged exposure to irritants may produce
conjunctivitis.
The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles,
scaling and thickening of the skin.
octyltriethoxysilane &
titanium(IV) butoxide &
dimethoxydimethylsilane
Asthma-like symptoms may continue for months or even years after exposure to the material ends. This may be due to a non-allergic condition known as
reactive airways dysfunction syndrome (RADS) which can occur after exposure to high levels of highly irritating compound. Main criteria for diagnosing
RADS include the absence of previous airways disease in a non-atopic individual, with sudden onset of persistent asthma-like symptoms within minutes to
hours of a documented exposure to the irritant. Other criteria for diagnosis of RADS include a reversible airflow pattern on lung function tests, moderate to
severe bronchial hyperreactivity on methacholine challenge testing, and the lack of minimal lymphocytic inflammation, without eosinophilia.
Acute Toxicity Carcinogenicity
Skin Irritation/Corrosion Reproductivity
Serious Eye Damage/Irritation STOT - Single Exposure
Respiratory or Skin
sensitisation
STOT - Repeated Exposure
Mutagenicity Aspiration Hazard
SECTION 12 ECOLOGICAL INFORMATION
Toxicity
GUARDSMAN WEATHER
DEFENCE FABRIC
PROTECTOR 284g AEROSOL
ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE
Not
Available
Not Available Not Available
Not
Available
Not
Available
butane
ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE
Not
Available
Not Available Not Available
Not
Available
Not
Available
propane
ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE
Not
Available
Not Available Not Available
Not
Available
Not
Available
naphtha petroleum, heavy,
hydrotreated
ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE
Not
Available
Not Available Not Available
Not
Available
Not
Available
methyltrimethoxysilane
ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE
LC50 96 Fish >110mg/L 2
EC50 48 Crustacea >122mg/L 2
EC50 72 Algae or other aquatic plants >3.6mg/L 2
NOEC 72 Algae or other aquatic plants >=3.6mg/L 2
octyltriethoxysilane
ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE
LC50 96 Fish >0.055mg/L 2
EC50 48 Crustacea >0.049mg/L 2
EC50 72 Algae or other aquatic plants >1.2mg/L 2
NOEC 48 Crustacea >=0.049mg/L 2
titanium(IV) butoxide
ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE
LC50 96 Fish 1-740mg/L 2
EC50 48 Crustacea 590mg/L 2
Chemwatch: 9-521064
Version No: 3.10
Page 7 of 10
GUARDSMAN WEATHER DEFENCE FABRIC PROTECTOR 284g AEROSOL
Issue Date: 15/03/2018
Print Date: 17/10/2018
Continued...