ANSI Material Safety Data Sheet

ManualsBrandsHarris ManualsPlumbing Supplies1/16"x 18" Flux Coated Safety-Silv High-Silver (45%), 4 Oz (Pack of 9 Sticks)

Revision Date: 10/03/2018

SDS_North America - 200000007372

1/19

SAFETY DATA SHEET

1. PRODUCT AND COMPANY IDENTIFICATION

Product Name: Safety Silv® 45 Flux Coated

Product Size: ALL

Other means of identification

SDS number:

200000007372

Recommended use and restriction on use

Recommended use: Metal Brazing

Restrictions on use: Not known. Read this SDS before using this product.

Manufacturer/Importer/Supplier/Distributor Information

Company Name:

The Harris Products Group

Address:

4501 Quality Place

Mason, OH 45040-1971

USA

Telephone:

+1 (513) 754-2000

Contact Person:

Safety Data Sheet Questions: custservmason@jwharris.com

Emergency telephone number:

USA/Canada/Mexico +1 (888) 609-1762

Americas/Europe +1 (216) 383-8962

Asia Pacific +1 (216) 383-8966

Middle East/Africa +1 (216) 383-8969

3E Company Access Code: 333988

2. HAZARDS IDENTIFICATION

Classified according to the criteria of the Globally Harmonized System of Classification and Labeling of Chemicals

(GHS), The United States Occupational Safety and Health Administration’s Hazard Communication Standard (29

CFR 1910.1200), Canada’s Hazardous Product Regulations and Mexico’s Harmonized System for the Identification

and Communication of Hazards and Risks from Hazardous Chemicals in the Workplace.

Hazard Classification Not classified as hazardous according to applicable GHS hazard classification

criteria.

Hazard Symbol:

No symbol

Signal Word:

No signal word.

Hazard Statement:

Not applicable

Precautionary

Statements:

Not applicable

Other hazards which do not

result in GHS classification:

Heat rays (infrared radiation) from flame or hot metal can injure eyes.

Overexposure to brazing fumes and gases can be hazardous. Read and

understand the manufacturer’s instructions, Safety Data Sheets and the

precautionary labels before using this product.

Label Elements

Summary of content (19 pages)

PAGE 1
Revision Date: 10/03/2018 SAFETY DATA SHEET 1. PRODUCT AND COMPANY IDENTIFICATION Product Name: Safety Silv® 45 Flux Coated Product Size: ALL Other means of identification SDS number: 200000007372 Recommended use and restriction on use Recommended use: Metal Brazing Restrictions on use: Not known. Read this SDS before using this product.
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Revision Date: 10/03/2018 Substance(s) formed under the conditions of use: Fumes produced from use of this product may contain the following constituent(s) and/or their complex metallic oxides as well as solid particles or other constituents from the solder, brazing consumable, flux material or base metal, or base metal coating not listed below. Chemical Identity CAS-No. Carbon dioxide 124-38-9 Carbon monoxide 630-08-0 Nitrogen dioxide 10102-44-0 Ozone 10028-15-6 3.
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Revision Date: 10/03/2018 Symptoms: Short-term (acute) overexposure to fumes and gases from welding and allied processes may result in discomfort such as metal fume fever, dizziness, nausea, or dryness or irritation of nose, throat, or eyes. May aggravate pre-existing respiratory problems (e.g. asthma, emphysema).
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Revision Date: 10/03/2018 Environmental Precautions: Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water sources or sewer. Environmental manager must be informed of all major spillages. 7. HANDLING AND STORAGE Precautions for safe handling: Prevent abrading consumable materials or creating dust. Provide appropriate exhaust ventilation at places where fume or dust is formed. Wear appropriate personal protective equipment.
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Revision Date: 10/03/2018 Chemical Identity Type Silver TWA 0.1 mg/m3 Silver - as Ag TWA 0.01 mg/m3 STEL 0.03 mg/m3 TWA 0.1 mg/m3 TWA 0.1 mg/m3 8 HR ACL 0.1 mg/m3 15 MIN ACL 0.3 mg/m3 TWA 0.1 mg/m3 Copper and/or copper alloys and compounds (as Cu) Fume. Copper and/or copper alloys and compounds (as Cu) Dust and mist. - as Cu Copper and/or copper alloys and compounds (as Cu) Fume. - as Cu TWA 0.2 mg/m3 TWA 1 mg/m3 TWA 0.
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Revision Date: 10/03/2018 and compounds (as Cu) Fume. - as Cu TWA 0.2 mg/m3 Potassium fluoroborate - as F TWA 2.5 mg/m3 Potassium fluoroborate Inhalable fraction. TWA 2 mg/m3 Boric acid - Inhalable STEL 6 mg/m3 TWA 2 mg/m3 STEL 6 mg/m3 TWA 2 mg/m3 TWA 2 mg/m3 STEL 6 mg/m3 8 HR ACL 2 mg/m3 15 MIN ACL 6 mg/m3 Boric acid - Inhalable fraction. - Regulation Respecting the Quality of the Work Environment) (09 2017) Canada. Ontario OELs.
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Revision Date: 10/03/2018 Carbon monoxide Nitrogen dioxide Ozone STEL 30,000 ppm 54,000 mg/m3 REL 5,000 ppm 9,000 mg/m3 TWA 25 ppm PEL 50 ppm 55 mg/m3 REL 35 ppm 40 mg/m3 Ceil_Time 200 ppm 229 mg/m3 TWA 0.2 ppm Ceiling 5 ppm 9 mg/m3 STEL 1 ppm 1.8 mg/m3 PEL 0.1 ppm 0.2 mg/m3 Ceil_Time 0.1 ppm 0.2 mg/m3 TWA 0.05 ppm TWA 0.20 ppm TWA 0.10 ppm TWA 0.08 ppm US. NIOSH: Pocket Guide to Chemical Hazards (2005) US. NIOSH: Pocket Guide to Chemical Hazards (2005) US.
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Revision Date: 10/03/2018 Carbon monoxide TWA 5,000 ppm 9,000 mg/m3 STEL 30,000 ppm 54,000 mg/m3 TWA 25 ppm 29 mg/m3 TWA 25 ppm STEL 100 ppm TWA 25 ppm TWA 25 ppm 8 HR ACL 25 ppm 15 MIN ACL Nitrogen dioxide Ozone 190 ppm TWA 35 ppm 40 mg/m3 STEL 200 ppm 230 mg/m3 STEL 5 ppm 9.4 mg/m3 TWA 3 ppm 5.6 mg/m3 CEILING 1 ppm TWA 0.2 ppm STEL 5 ppm TWA 3 ppm 8 HR ACL 3 ppm 15 MIN ACL 5 ppm TWA 3 ppm 5.6 mg/m3 STEL 0.3 ppm 0.6 mg/m3 TWA 0.1 ppm 0.
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Revision Date: 10/03/2018 TWA 0.05 ppm TWA 0.1 ppm TWA 0.08 ppm TWA 0.2 ppm TWA 0.1 ppm 0.2 mg/m3 STEL 0.3 ppm 0.6 mg/m3 15 MIN ACL 0.15 ppm 8 HR ACL 0.05 ppm CEILING 0.1 ppm TWA 0.20 ppm TWA 0.05 ppm TWA 0.08 ppm TWA 0.10 ppm 0.2 mg/m3 Health & Safety Code, Schedule 1, Table 2) (07 2009) Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007) Canada. British Columbia OELs.
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Revision Date: 10/03/2018 Appropriate Engineering Controls Ventilation: Use enough ventilation and local exhaust at the arc, flame or heat source to keep the fumes and gases from the worker's breathing zone and the general area. Train the operator to keep their head out of the fumes. Keep exposure as low as possible.
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Revision Date: 10/03/2018 other dry insulation. Respiratory Protection: Keep your head out of fumes. Use enough ventilation and local exhaust to keep fumes and gases from your breathing zone and the general area. An approved respirator should be used unless exposure assessments are below applicable exposure limits. Hygiene measures: Do not eat, drink or smoke when using the product.
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Revision Date: 10/03/2018 Reactivity: The product is non-reactive under normal conditions of use, storage and transport. Chemical Stability: Material is stable under normal conditions. Possibility of hazardous reactions: None under normal conditions. Conditions to avoid: Avoid heat or contamination. Incompatible Materials: Strong acids. Strong oxidizing substances. Strong bases.
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Revision Date: 10/03/2018 Skin Contact: Moderately irritating to skin with prolonged exposure. Eye contact: HEAT RAYS (INFRARED RADIATION) from flame or hot metal can injure eyes. Ingestion: Avoid ingestion - wear gloves and other appropriate personal protection wash hands thoroughly following use or handling.
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Revision Date: 10/03/2018 Product: Carcinogenicity Product: Not classified Arc rays: Skin cancer has been reported. IARC Monographs on the Evaluation of Carcinogenic Risks to Humans: No carcinogenic components identified US. National Toxicology Program (NTP) Report on Carcinogens: No carcinogenic components identified US. OSHA Specifically Regulated Substances (29 CFR 1910.
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Revision Date: 10/03/2018 Silver Zinc Copper and/or copper alloys and compounds (as Cu) Boric acid Aquatic Invertebrates Product: Specified substance(s): Silver Zinc Copper and/or copper alloys and compounds (as Cu) Boric acid LC 50 (Rainbow trout,donaldson trout (Oncorhynchus mykiss), 96 h): 0.013 mg/l LC 50 (Fathead minnow (Pimephales promelas), 96 h): 1.277 - 3.649 mg/l LC 50 (Fathead minnow (Pimephales promelas), 96 h): 1.6 mg/l LC 50 (Pimephales promelas, 96 h): 79.
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Revision Date: 10/03/2018 collection point. Contaminated Packaging: Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. 14. TRANSPORT INFORMATION DOT UN Number: UN Proper Shipping Name: Transport Hazard Class(es) Class: Label(s): Packing Group: Marine Pollutant: IMDG UN Number: UN Proper Shipping Name: Transport Hazard Class(es) Class: Label(s): EmS No.
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Revision Date: 10/03/2018 CERCLA Hazardous Substance List (40 CFR 302.4): Chemical Identity Silver Zinc Copper and/or copper alloys and compounds (as Cu) Reportable quantity 1000lbs. 1000lbs. 5000lbs. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Not classified Not classified SARA 302 Extremely Hazardous Substance None present or none present in regulated quantities. SARA 304 Emergency Release Notification Chemical Identity Reportable quantity Silver 1000 lbs.
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Revision Date: 10/03/2018 Copper and/or copper alloys and compounds (as Cu) Boric acid US. Massachusetts RTK - Substance List No ingredient regulated by MA Right-to-Know Law present. US. Pennsylvania RTK - Hazardous Substances Chemical Identity Silver Zinc Copper and/or copper alloys and compounds (as Cu) US. Rhode Island RTK No ingredient regulated by RI Right-to-Know Law present.
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Revision Date: 10/03/2018 China Inv. Existing Chemical Substances: Korea Existing Chemicals Inv. (KECI): Canada NDSL Inventory: Philippines PICCS: New Zealand Inventory of Chemicals: Japan ISHL Listing: Japan Pharmacopoeia Listing: US TSCA Inventory: Mexico INSQ: Ontario Inventory: Taiwan Chemical Substance Inventory: On or in compliance with the inventory One or more components are not listed or are exempt from listing. One or more components are not listed or are exempt from listing.