SAFETY DATA SHEET according to US Regulation 29 CFR 1910.1200 and the Canadian HPA HTH Super 3" Chlorinating Tablets Version 1.3 Revision Date 2019.04.16 Print Date 2019.07.12 SECTION 1. IDENTIFICATION Product name : HTH Super 3" Chlorinating Tablets Manufacturer or supplier's details Company : Arch Chemicals, Inc. 1200 Bluegrass Lakes Parkway Alpharetta, GA 30004 United States of America (USA) E-mail address Emergency telephone number : : sds@lonza.
HTH Super 3" Chlorinating Tablets Precautionary statements Prevention: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
HTH Super 3" Chlorinating Tablets trol center or doctor, or going for treatment. If inhaled : IF INHALED: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice. In case of skin contact : IF ON SKIN OR CLOTHING: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes.
HTH Super 3" Chlorinating Tablets Protection concerns must also address the following: If this material becomes damp/wet or contaminated in a container, the formation of nitrogen trichloride gas may occur and an explosive condition may exist. FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC: 1-800-424-9300 Hazardous concentrations in air may be found in local spill area and immediately downwind. If spill material is still dry, do not put water directly on this product as a gas evolution may occur.
HTH Super 3" Chlorinating Tablets normally required when handling or using this product to keep airborne exposures below the TLV, PEL or other recommended exposure limit. Personal protective equipment Respiratory protection : Wear a NIOSH approved respirator if levels above the exposure limits are possible. A NIOSH approved full-face air purifying respirator equipped with combination chlorine/P100 cartridges.
HTH Super 3" Chlorinating Tablets Upper explosion limit : Not applicable Lower explosion limit : Not applicable Vapour pressure : Not applicable Relative vapour density : no data available Relative density : > 1 (68 °F / 20 °C) Water solubility : 12 g/l (77 °F / 25 °C) Partition coefficient: n-octanol/water : no data available Auto-ignition temperature : no data available Decomposition temperature : 437 °F / 225 °C Viscosity, dynamic : no data available Viscosity, kinematic :
HTH Super 3" Chlorinating Tablets cyanates Carbon dioxide (CO2) SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation, skin, eyes, ingestion Acute toxicity Acute oral toxicity : LD50 (Rat): 490 mg/kg Acute inhalation toxicity : LC50 (Rat): approximately 0.54 mg/l Exposure time: 4 h Test atmosphere: dust/mist Remarks: (Nose Only) LC50 (Rat): approximately 2.
HTH Super 3" Chlorinating Tablets SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 0.32 mg/l Exposure time: 96 h LC50 (Lepomis macrochirus (Bluegill sunfish)): 0.30 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : LC50 (Daphnia magna (Water flea)): 0.
HTH Super 3" Chlorinating Tablets Disposal methods Waste from residues : If this product becomes a waste, it will be a nonhazardous waste. As a nonhazardous solid waste it should be disposed of in accordance with local, state and federal regulations. SECTION 14. TRANSPORT INFORMATION DOT UN number Proper shipping name Transport hazard class Packing group Labels Emergency Response Guidebook Number Environmental hazards : 3077 : Environmentally hazardous substance, solid, n.o.s.
HTH Super 3" Chlorinating Tablets ADR UN number Proper shipping name : 3077 : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Trichloro-s-triazinetrione, zinc sulphate) : 9 : III : M7 : 90 : 9 : yes Transport hazard class Packing group Classification Code Hazard Identification Number Labels Environmental hazards RID UN number Proper shipping name : 3077 : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
HTH Super 3" Chlorinating Tablets zinc sulphate 7446-19-7 (lbs) product RQ (lbs) 1000 28571 SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards See above: SECTION 2. Hazard Identification-GHS Classification SARA 313 Components zinc sulphate CAS-No. 7446-19-7 Concentration 2- 4% Clean Air Act This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S.
HTH Super 3" Chlorinating Tablets 1,3,5-Trichloro-1,3,5-triazinane-2,4,6-trione zinc sulphate Proprietary Filter Aid 87-90-1 7446-19-7 Not Assigned Pennsylvania Right To Know Components 1,3,5-Trichloro-1,3,5-triazinane-2,4,6-trione zinc sulphate CAS-No. 87-90-1 7446-19-7 New Jersey Right To Know Components 1,3,5-Trichloro-1,3,5-triazinane-2,4,6-trione zinc sulphate Proprietary Filter Aid CAS-No. 87-90-1 7446-19-7 Not Assigned California Prop.
HTH Super 3" Chlorinating Tablets (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR (Quantitative) Structure Activity Relationship; RCRA - Resource Conservation an
