MSDS

ManualsBrandsHTH ManualsKitchen5 lb. Super Select Shock Treatment

MATERIAL SAFETY

DATA SHEET

REVISION DATE : 04/23/2012 Page 1 of 16

FOR ANY EMERGENCY, 24 HOURS / 7 DAYS, CALL:

FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC®:

FOR ALL MSDS QUESTIONS & REQUESTS, CALL:

1-800-654-6911 (OUTSIDE

USA: 1-423-780-2970)

1-800-424-9300 (OUTSIDE

USA: 1-703-527-3887)

1-800-511-MSDS (OUTSIDE

USA: 1-423-780-2347)

PRODUCT NAME: HTH

SUPER PREMIUM SHOCK TREATMENT

1258-1343 pending EPA approval

1. PRODUCT AND COMPANY IDENTIFICATION

Arch Chemicals, Inc.

501 Merritt 7 PO Box 5204

Norwalk, CT 06856-5204

REVISION DATE: 04/23/2012

SUPERCEDES:

MSDS Number: 000000015122

SYNONYMS: None

CHEMICAL FAMILY: Hypochlorite

DESCRIPTION / USE THIS MATERIAL SAFETY DATA

SHEET (MSDS) IS SENT TO YOU

FOR RESEARCH AND

DEVELOPMENT PURPOSES ONLY.

THE INFORMATION PROVIDED ON

THIS MSDS IS THE BEST ESTIMATE

OF TECHNICALLY QUALIFIED

INDIVIDUALS BUT MAY NOT BE

BASED ON DIRECT TOXICOLOGY

TESTING OR EXPERIENCE IN

EMERGENCY SITUATIONS. IT MUST

BE USED BY OR UNDER THE

DIRECT SUPERVISION OF

TECHNICALLY QUALIFIED

INDIVIDUALS (AS DEFINED IN 40

CFR 710.2).

FORMULA: NOT APPLICABLE/MIXTURE

2. HAZARDS IDENTIFICATION

OSHA Hazard

Classification:

Toxic by inhalation., Corrosive to eyes and skin, Lung toxin, Oxidizer

Routes of Entry: Inhalation, skin, eyes, ingestion

Chemical Interactions: No known or reported interactions.

Pending EPA Approval-Not Final

Summary of content (16 pages)

PAGE 1
MATERIAL SAFETY DATA SHEET Pe FOR ANY EMERGENCY, 24 HOURS / 7 DAYS, CALL: FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC®: in nd FOR ALL MSDS QUESTIONS & REQUESTS, CALL: 1-800-654-6911 (OUTSIDE USA: 1-423-780-2970) 1-800-424-9300 (OUTSIDE USA: 1-703-527-3887) 1-800-511-MSDS (OUTSIDE USA: 1-423-780-2347) g EP PRODUCT NAME: HTH SUPER PREMIUM SHOCK TREATMENT 1258-1343 pending EPA approval A 1. PRODUCT AND COMPANY IDENTIFICATION Ap REVISION DATE: SUPERCEDES: o pr Arch Chemicals, Inc.
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MATERIAL SAFETY DATA SHEET Medical Conditions Aggravated: Asthma, respiratory and cardiovascular disease Pe Human Threshold Response Data Approximately 1.
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MATERIAL SAFETY DATA SHEET Acute Target Organ Toxicity: in nd Pe This product is corrosive to all tissues contacted and upon inhalation, may cause irritation to mucous membranes and respiratory tract., The dry material is irritating to the skin. However when wet, it will produce burns to the skin.
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MATERIAL SAFETY DATA SHEET 10043-52-4 0- 4 CALCIUM HYDROXIDE Pe 1305-62-0 0- 4 CALCIUM CARBONATE 471-34-1 0- 4 7732-18-5 4- 8 g in nd CALCIUM CHLORIDE A EP Water 4. FIRST AID MEASURES Ap Call a poison control center or doctor for treatment advice. For 24-hour emergency medical assistance, call Arch Chemical Emergency Action Network at 1-800-654-6911. Have the product container or label with you when calling a poison control center or doctor, or going for treatment.
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MATERIAL SAFETY DATA SHEET Pe 5. FIRE FIGHTING MEASURES Flammability Summary (OSHA): g in nd This product is chemically reactive with many substances. Any contamination of the product with other substances by spill or otherwise may result in a chemical reaction and fire., This product is a strong oxidizer which is capable of intensifying a fire once started., Product is not known to be flammable, combustible or pyrophoric.
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MATERIAL SAFETY DATA SHEET Land Release: g in nd Pe Additional Spill Information : A EP Contact 1-800-654-6911 immediately. DANGER: All spills of this product should be treated as contaminated. Contaminated product may initiate a chemical reaction that may spontaneously ignite any combustible material present, resulting in a fire of great intensity. In case of a spill, separate all spilled product from packaging, debris and other material.
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MATERIAL SAFETY DATA SHEET Shelf Life Limitations: g in nd Pe Do not store product where the average daily temperature exceeds 95° F. Storage above this temperature may result in rapid decomposition, evolution of chlorine gas and heat sufficient to ignite combustible products. Shelf life (that is, the period of time before the product goes below stated label strength) is determined by storage time and temperatures. Store in a cool, dry and well ventilated area.
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MATERIAL SAFETY DATA SHEET CALCIUM HYPOCHLORITE 7778-54-3 ARCH-ROEG* 1 mg/m3 TWA Pe 7778-54-3 CALCIUM HYDROXIDE 1305-62-0 ACGIH CALCIUM HYDROXIDE 1305-62-0 OSHA Z1 15 mg/m3 1305-62-0 OSHA Z1 5 mg/m3 TWA respirable fraction 471-34-1 OSHA Z1 15 mg/m3 TWA Total dust 471-34-1 OSHA Z1 CALCIUM HYPOCHLORITE g in nd CALCIUM HYDROXIDE A CALCIUM CARBONATE EP CALCIUM CARBONATE NIOSH-IDLH 37 - 48 mg/m3 based on IDLH concentration of chlorine 5 mg/m3 TWA 5 mg/m3 TWA total dust TWA res
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MATERIAL SAFETY DATA SHEET Pe 10. STABILITY AND REACTIVITY Stability and Reactivity Summary: g in nd A EP Conditions to Avoid: Product is not sensitive to mechanical shock or impact. Product is not sensitive to electrical static discharge. Product will not undergo hazardous polymerization. Product is an NFPA Class 1 oxidizer. Not pyrophoric. Not an organic peroxide.
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teratogen. CALCIUM CHLORIDE MATERIAL SAFETY Calcium hypochlorite has been tested in the Dominant lethal assay in male mice, and it did not induce a dominant lethal response. Calcium hypochlorite DATA SHEET has been reported to produce mutagenic activity in two in vitro assays. It has, however, been shown to lack the capability to produce mutations in animals based on results from the micronucleus assay.
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MATERIAL SAFETY DATA SHEET in nd Pe produces mutations in these in vitro assays is significantly greater than the concentrations used for disinfection. Based on high cellular toxicity in in vitro assays and the lack of mutagenicity in animals, the risk of genetic damage to humans is judged not significant. CALCIUM CHLORIDE This product was determined to be non-mutagenic in the Ames assay. It was also shown to be nonclastogenic in the chromosomal aberration test.
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MATERIAL SAFETY DATA SHEET in nd Pe Rainbow trout (Salmo gairdneri), Daphnia magna, Bobwhite quail Mallard ducklings Bobwhite quail - (nominal, static). 96 h LC50 0.16 mg/l (nominal, static). 48 h LC50 0.11 mg/l Dietary LC50 > 5,000 ppm Dietary LC50 > 5,000 ppm Oral LD50 3,474 mg/kg g Ecological Toxicity Values for: CALCIUM CHLORIDE Bluegill - (nominal, static). 96 h LC50 = 10,650 mg/l Mosquito fish - (nominal, static). 96 h LC50 = 13,400 mg/l - (nominal, static).
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MATERIAL SAFETY DATA SHEET in nd Pe Flash Point: Not applicable Air (IATA): UN1748 CALCIUM HYPOCHLORITE, DRY MIXTURE, 5.1 III Emergency Response Guide Number: ERG # 140 Transportation Notes: g A EP REPORTABLE QUANTITY: 10 lbs. (Per 49 CFR 172.101, Appendix) Under specific circumstances, this product can ship under two transport exceptions, Limited Quantity or Consumer Commodity. See Bill of Lading for proper shipping description.
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MATERIAL SAFETY DATA SHEET Pe Supplier Notification Requirements (40 CFR 372.45), 313 Reportable Components De minimis concentration in nd ZUS_SAR313 None established Clean Air Act Toxic ARP Section 112r: CAA 112R None established g None established EP Clean Air Act Socmi: HON SOC A Clean Air Act VOC Section 111: CAA 111 None established Ap Clean Air Act Haz.
PAGE 15
MATERIAL SAFETY DATA SHEET in nd Pe New Jersey: CAS # 10137-74-3 1305-62-0 7778-54-3 ZUSNJ_RTK COMPONENT NAME CALCIUM CHLORATE CALCIUM HYDROXIDE CALCIUM HYPOCHLORITE g New Jersey Right to Know Hazardous Substance List (RTK-HSL) 2007-03-01 CALCIUM CHLORATE CHLORIC ACID, CALCIUM SALT EP A New Jersey Right to Know Hazardous Substance List (RTK-HSL) 2007-03-01 CALCIUM HYDROXIDE CALCIUM HYDROXIDE (Ca(OH)2) HYDRATED LIME Ap ot l-N va o pr New Jersey Right to Know Hazardous Substance List (RTK-HSL) 20
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MATERIAL SAFETY DATA SHEET CAS # COMPONENT NAME Pe ZUSCA_P65 None established in nd WHMIS Hazard Classification: g A EP Ingredient Disclosure List (WHMIS) 2007-08-24 Threshold limits: 1 Weight percent 991 Calcium hydroxide o pr MSDS REVISION STATUS : Major References : Ap 16. OTHER INFORMATION Available upon request. ot l-N va THIS MATERIAL SAFETY DATA SHEET (MSDS) HAS BEEN PREPARED IN COMPLIANCE WITH THE FEDERAL OSHA HAZARD COMMUNICATION STANDARD, 29 CFR 1910.1200.