SAFETY DATA SHEET FOR ANY EMERGENCY, 24 HOURS / 7 DAYS, CALL: FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC®: FOR ALL SDS QUESTIONS & REQUESTS, CALL: 1-800-654-6911 (OUTSIDE USA: 1-423-780-2970) 1-800-424-9300 (OUTSIDE USA: 1-703-527-3887) 1-800-511-MSDS (OUTSIDE USA: 1-423-780-2347) PRODUCT NAME: HTH Algae Guard Granules EPA Registration Number: 1258-1328 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Arch Chemicals, Inc.
SAFETY DATA SHEET H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. Precautionary statements : Prevention: P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear eye protection/ face protection. P280 Wear protective gloves. Response: P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell. Rinse mouth.
SAFETY DATA SHEET SECTION 4. FIRST AID MEASURES General Advice: Call a poison control center or doctor for treatment advice. For 24-hour emergency medical assistance, call Arch Chemical Emergency Action Network at 1-800-654-6911. Have the product container or label with you when calling a poison control center or doctor, or going for treatment. Inhalation: IF INHALED: Move person to fresh air.
SAFETY DATA SHEET Personal Protection for Emergency Situations: Spill Mitigation Procedures Air Release: Use the personal protective equipment recommended in Section 8 and a NIOSH approved self-contained breathing apparatus. Dusting from this product could occur. Contain all solids for treatment or disposal. Knock down dust with water spray jet.Contain all solids for treatment or disposal. Notify all downstream users of possible contamination. Divert water flow around spill if possible and safe to do so.
SAFETY DATA SHEET Eye Protection: Protective Clothing Type: General Protective Measures: Use chemical goggles. Impervious Emergency eyewash should be provided in the immediate work area. Components with workplace control parameters no data available SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Form Color: Odor: Molecular Weight: Relative density solid Free flowing powder white No data 179.46 g/mol 3.
SAFETY DATA SHEET thermal decomposition or combustion. 500 °C - , Decomposition Temperature: SECTION 11.
SAFETY DATA SHEET Ecological Toxicity Values for: ZINC SULFATE Rainbow trout (Oncorhynchus - 96 h LC50 = 2.4 mg/l mykiss) Pimephales promelas (fathead - (static). 96 h LC50 = 3.1 mg/l minnow) Daphnia magna, - (static). 48 h LC50= 0.690 mg/l SECTION 13. DISPOSAL CONSIDERATIONS CARE MUST BE TAKEN TO PREVENT ENVIRONMENTAL CONTAMINATION FROM THE USE OF THE MATERIAL.
SAFETY DATA SHEET Class Packing group Labels IATA UN number Description of the goods Class Packing group Labels Packing instruction (cargo aircraft) Packing instruction (passenger aircraft) Packing instruction (passenger aircraft) IMDG-CODE UN number Description of the goods : 9 : III : 9 : 3077 : Environmentally hazardous substance, solid, n.o.s.
SAFETY DATA SHEET zinc sulphate 7446-19-7 1000 1000 SARA 302 No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 The following components are subject to reporting levels established by SARA Title III, Section 313: zinc sulphate 7446-19-7 Clean Air Act This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61). This product does not contain any chemicals listed under the U.
SAFETY DATA SHEET California Prop 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. The components of this product are reported in the following inventories: : This is an EPA registered pesticide. Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA) SECTION 16.
SAFETY DATA SHEET FOR ANY EMERGENCY, 24 HOURS / 7 DAYS, CALL: FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC®: FOR ALL SDS QUESTIONS & REQUESTS, CALL: 1-800-654-6911 (OUTSIDE USA: 1-423-780-2970) 1-800-424-9300 (OUTSIDE USA: 1-703-527-3887) 1-800-511-MSDS (OUTSIDE USA: 1-423-780-2347) PRODUCT NAME: HTH Ultimate Shock Treatment EPA Registration Number: 1258-1346 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Arch Chemicals, Inc.
SAFETY DATA SHEET Hazard statements : H272 May intensify fire; oxidiser. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H331 Toxic if inhaled. H335 May cause respiratory irritation. Precautionary statements : Prevention: P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P220 Keep/Store away from clothing/ combustible materials. P221 Take any precaution to avoid mixing with combustibles. P260 Do not breathe vapours.
SAFETY DATA SHEET SODIUM CHLORIDE 7647-14-5 15 - 25 MAGNESIUM SULFATE HEPTAHYDRATE 10034-99-8 14 - 18 CALCIUM HYDROXIDE 1305-62-0 0- 6 CALCIUM CARBONATE 471-34-1 0- 4 Calcium chloride 10035-04-8 0- 4 CALCIUM CHLORATE 10137-74-3 0- 4 Hexametaphosphate 68915-31-1 0- 1 ALUMINUM SULFATE, ANHYDROUS 10043-01-3 0- 1 Water 7732-18-5 10 - 16 SECTION 4. FIRST AID MEASURES General Advice: Call a poison control center or doctor for treatment advice.
SAFETY DATA SHEET SECTION 5. FIREFIGHTING MEASURES Flammability Summary (OSHA): This product is chemically reactive with many substances. Any contamination of the product with other substances by spill or otherwise may result in a chemical reaction and fire., This product is a strong oxidizer which is capable of intensifying a fire once started., Product is not known to be flammable, combustible or pyrophoric.
SAFETY DATA SHEET Land Release: Additional Spill Information : Contact 1-800-654-6911 immediately. DANGER: All spills of this product should be treated as contaminated. Contaminated product may initiate a chemical reaction that may spontaneously ignite any combustible material present, resulting in a fire of great intensity. In case of a spill, separate all spilled product from packaging, debris and other material.
SAFETY DATA SHEET Incompatible Materials for Storage: Do Not Store At temperatures Above: Do not allow product to come in contact with other materials, including e.g. other pool treatment products, acids, organic materials, nitrogen-containing compounds, dry powder fire extinguishers (containing mono-ammonium phosphate), oxidizers, all corrosive liquids, flammable or combustible materials, etc A chemical reaction with such substances can cause a fire. Average daily temperature of 35° C / 95° F.
SAFETY DATA SHEET Physical State: Form Color: Odor: Molecular Weight: pH : Boiling Point: Melting point/freezing point Density: Vapor Pressure: Vapor Density: Viscosity: Fat Solubility: Solubility in Water: Partition coefficient noctanol/water: Evaporation Rate: Oxidizing: Volatiles, % by vol.: VOC Content HAP Content solid Free flowing, powder white Chlorine-like (Active ingredient)143.00 g/mol 10 - 10.7 solution Not applicable Not applicable 0.9 - 1.1g/cc (@ 25 Deg.
SAFETY DATA SHEET SECTION 11. TOXICOLOGICAL INFORMATION Component Animal Toxicology Oral LD50 value: CALCIUM LD50 (65% calcium hypochlorite) HYPOCHLORITE SODIUM CHLORIDE LD50 = 3,000 mg/kg Rat CALCIUM HYDROXIDE LD50 = 7,340 mg/kg Rat Calcium chloride > 1,000.
SAFETY DATA SHEET Product Animal Toxicity Oral LD50 value: Dermal LD50 value: Inhalation LC50 value: Skin Irritation: Eye Irritation: Skin Sensitization: Acute Toxicity: Subchronic / Chronic Toxicity: LD50 Approximately 850 mg/kg Rat LD50 > 2,000 mg/kg Rabbit Inhalation LC50 1 h (Nose Only) > 2.04 mg/l Rat Inhalation LC50 4 h (Nose Only) > 0.51 mg/l Rat DRY MATERIAL CAUSES MODERATE SKIN IRRITATION., WET MATERIAL CAUSES SKIN BURNS. Corrosive to eyes.
SAFETY DATA SHEET Rainbow trout (Salmo gairdneri), - Daphnia magna, - Bobwhite quail - Mallard ducklings - Bobwhite quail - (nominal, static). 96 h LC50 Approximately 0.22 mg/l Based on extrapolation from studies using calcium hypochlorite. (nominal, static). 48 h LC50Approximately 0.15 mg/l Based on extrapolation from studies using calcium hypochlorite. LC50 > 7,000 ppm Based on extrapolation from studies using calcium hypochlorite.
SAFETY DATA SHEET SECTION 14.
SAFETY DATA SHEET This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. Signal word Hazard statements : : DANGER! Harmful if swallowed. Harmful if absorbed through skin. Harmful if inhaled. Corrosive.
SAFETY DATA SHEET magnesium sulphate heptahydrate Calcium dihydroxide Calcium carbonate Calcium chlorate Aluminium sulphate 10034-99-8 1305-62-0 471-34-1 10137-74-3 10043-01-3 California Prop 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. The components of this product are reported in the following inventories: TSCA : This is an EPA registered pesticide.
SAFETY DATA SHEET FOR ANY EMERGENCY, 24 HOURS / 7 DAYS, CALL: FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC®: FOR ALL SDS QUESTIONS & REQUESTS, CALL: 1-800-654-6911 (OUTSIDE USA: 1-423-780-2970) 1-800-424-9300 (OUTSIDE USA: 1-703-527-3887) 1-800-511-MSDS (OUTSIDE USA: 1-423-780-2347) PRODUCT NAME: HTH METAL & STAIN DEFENSE GRANULES SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Arch Chemicals, Inc.
SAFETY DATA SHEET P280 Wear protective gloves. Response: P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 Call a POISON CENTER or doctor/ physician if you feel unwell.
SAFETY DATA SHEET SECTION 5. FIREFIGHTING MEASURES Flammability Summary (OSHA): Combustible above 93 deg. C / 200 deg. F. Flammable Properties Flash Point: Autoignition Temperature: Fire / Explosion Hazards: > 200 °C Closed Cup No data Material may be ignited if preheated to temperatures above the flash point in the presence of a source of ignition. Closed containers may explode (due to the build up of steam pressure) when exposed to extreme heat.
SAFETY DATA SHEET Additional Spill Information : Remove all sources of ignition. Stop source of spill as soon as possible and notify appropriate personnel. Utilize emergency response personal protection equipment prior to the start of any response. Evacuate all non-essential personnel. Dispose of spill residues per guidelines under Section 13, Disposal Consideration. SECTION 7. HANDLING AND STORAGE Handling: Storage: Incompatible Materials for Storage: Empty Container Warning: Do not take internally.
SAFETY DATA SHEET SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Form Color: Odor: Molecular Weight: Relative density solid powder white Characteristic 298 g/mol 0.7 pH : 11 - 12 () 1% solution Not applicable 428 °F (220 °C) Approximately Boiling Point: Density Vapor Pressure: Vapor Density: Viscosity: Fat Solubility: Solubility in Water: Partition coefficient noctanol/water: Evaporation Rate: Oxidizing: Volatiles, % by vol.: VOC Content HAP Content 0.
SAFETY DATA SHEET Component Animal Toxicology Dermal LD50 value: Tetrasodium Etidronate LD50 Believed to be > 5,000 mg/kg Rabbit Component Animal Toxicology Inhalation LC50 value: Tetrasodium Etidronate no data available Product Animal Toxicity Oral LD50 value: Dermal LD50 value: Inhalation LC50 value: Skin Irritation: Eye Irritation: Skin Sensitization: Acute Toxicity: Subchronic / Chronic Toxicity: LD50 Believed to be > 2,850 mg/kg Rat LD50 Believed to be > 5,000 mg/kg Rabbit no data available no
SAFETY DATA SHEET Overview: No aquatic toxicity data is available for this product., This product is expected to have low toxicity to fish and other aquatic organisms. SECTION 13. DISPOSAL CONSIDERATIONS CARE MUST BE TAKEN TO PREVENT ENVIRONMENTAL CONTAMINATION FROM THE USE OF THE MATERIAL.
SAFETY DATA SHEET Packing instruction (cargo aircraft) Packing instruction (passenger aircraft) Packing instruction (passenger aircraft) IMDG-CODE UN number Description of the goods Class Packing group Labels EmS Number 1 EmS Number 2 : 864 : 860 : Y845 : 3263 : CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. (Tetrasodium (1-hydroxyethylidene)bisphosphonate) : 8 : III : 8 : F-A : S-B SECTION 15.
SAFETY DATA SHEET This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. The components of this product are reported in the following inventories: TSCA : The components of this product are listed on the TSCA Inventory of Existing Chemical Substances.
