Page: 1 Revision Date: 05/26/2015 SAFETY DATA SHEET Print Date: 1/13/2016 SDS Number: R0292627 Version: 1.1 Pliogrip™ 7655T CART ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 134447 29 CFR 1910.1200 (OSHA HazCom 2012) SECTION 1.
Page: 2 Revision Date: 05/26/2015 SAFETY DATA SHEET Print Date: 1/13/2016 SDS Number: R0292627 Version: 1.1 Pliogrip™ 7655T CART ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 134447 Storage: Store locked up. Disposal: Dispose of contents/ container to an approved waste disposal plant. Other hazards None known. SECTION 3.
Page: 3 Revision Date: 05/26/2015 SAFETY DATA SHEET Pliogrip™ 7655T CART ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 134447 Print Date: 1/13/2016 SDS Number: R0292627 Version: 1.1 SECTION 4. FIRST AID MEASURES General advice : Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. If inhaled : If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician.
Page: 4 Revision Date: 05/26/2015 SAFETY DATA SHEET Pliogrip™ 7655T CART ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 134447 products Specific extinguishing methods Print Date: 1/13/2016 SDS Number: R0292627 Version: 1.1 Aldehydes Ketones carbon dioxide and carbon monoxide halogenated hydrocarbons nitrogen oxides (NOx) : Product is compatible with standard fire-fighting agents.
Page: 5 Revision Date: 05/26/2015 SAFETY DATA SHEET Print Date: 1/13/2016 SDS Number: R0292627 Version: 1.1 Pliogrip™ 7655T CART ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 134447 place. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No.
Page: 6 Revision Date: 05/26/2015 SAFETY DATA SHEET Pliogrip™ 7655T CART ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 134447 Print Date: 1/13/2016 SDS Number: R0292627 Version: 1.1 with the producers of the protective gloves. Eye protection : Not required under normal conditions of use. Wear splashproof safety goggles if material could be misted or splashed into eyes.
Page: 7 Revision Date: 05/26/2015 SAFETY DATA SHEET Pliogrip™ 7655T CART ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 134447 Solubility(ies) Water solubility Solubility in other solvents : No data available : No data available Partition coefficient: noctanol/water : No data available Thermal decomposition : No data available Viscosity Viscosity, dynamic : No data available Viscosity, kinematic Oxidizing properties Print Date: 1/13/2016 SDS Number: R0292627 Ve
Page: 8 Revision Date: 05/26/2015 SAFETY DATA SHEET Pliogrip™ 7655T CART ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 134447 Acute toxicity Not classified based on available information. Components: PIPERAZINE: : LD50 (Rat): ca. 2,600 mg/kg Acute oral toxicity Method: OECD Test Guideline 401 Acute inhalation toxicity : LC0 (Rat, male and female): 1.
Page: 9 Revision Date: 05/26/2015 SAFETY DATA SHEET Print Date: 1/13/2016 SDS Number: R0292627 Version: 1.1 Pliogrip™ 7655T CART ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 134447 Carcinogenicity Not classified based on available information. Reproductive toxicity Suspected of damaging fertility or the unborn child.
Page: 10 Revision Date: 05/26/2015 SAFETY DATA SHEET Pliogrip™ 7655T CART ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 134447 aquatic invertebrates (Chronic toxicity) Print Date: 1/13/2016 SDS Number: R0292627 Version: 1.
Page: 11 Revision Date: 05/26/2015 SAFETY DATA SHEET Print Date: 1/13/2016 SDS Number: R0292627 Version: 1.1 Pliogrip™ 7655T CART ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 134447 ID NUMBER PROPER SHIPPING NAME *HAZARD CLASS SUBSIDIARY HAZARDS PACKING GROUP U.S. DOT - ROAD Not dangerous goods U.S. DOT - RAIL Not dangerous goods U.S.
Page: 12 Revision Date: 05/26/2015 SAFETY DATA SHEET Pliogrip™ 7655T CART ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 134447 Print Date: 1/13/2016 SDS Number: R0292627 Version: 1.1 Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. SECTION 15.
Page: 13 Revision Date: 05/26/2015 SAFETY DATA SHEET Print Date: 1/13/2016 SDS Number: R0292627 Version: 1.1 Pliogrip™ 7655T CART ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 134447 SECTION 16. OTHER INFORMATION Further information Revision Date: 05/26/2015 NFPA: HMIS III: Flammability Health 2 0 Instability 1 HEALTH 2 FLAMMABILITY 1 PHYSICAL HAZARD 0 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Special hazard.
Page: 14 Revision Date: 05/26/2015 SAFETY DATA SHEET Pliogrip™ 7655T CART ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 134447 Print Date: 1/13/2016 SDS Number: R0292627 Version: 1.1 CAS : Chemical Abstracts Service (Division of the American Chemical Society). CMR : Carcinogenic, Mutagenic or Toxic for Reproduction FG : Food grade GHS : Globally Harmonized System of Classification and Labeling of Chemicals.
Page: 1 Revision Date: 05/26/2015 SAFETY DATA SHEET Print Date: 1/13/2016 SDS Number: R0279263 Version: 1.1 Pliogrip™ 7400 ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 148949 29 CFR 1910.1200 (OSHA HazCom 2012) SECTION 1.
Page: 2 Revision Date: 05/26/2015 SAFETY DATA SHEET Pliogrip™ 7400 ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 148949 Print Date: 1/13/2016 SDS Number: R0279263 Version: 1.1 Hazard pictograms : Signal Word : Danger Hazard Statements : Precautionary Statements : Prevention: Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. Wash skin thoroughly after handling. Use only outdoors or in a well-ventilated area.
Page: 3 Revision Date: 05/26/2015 SAFETY DATA SHEET Print Date: 1/13/2016 SDS Number: R0279263 Version: 1.1 Pliogrip™ 7400 ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 148949 Hazardous components Chemical Name POLYMER CAS-No. 254504001-5759 Classification Acute Tox. 4; H332 Concentration (%) >= 10.00 - < 15.00 Skin Irrit. 2; H315 Resp. Sens. 1A; H334 Skin Sens. 1A; H317 STOT SE 3; H335 STOT RE 2; H373 SCAVENGER 254504001-5709 This material is not >= 10.
Page: 4 Revision Date: 05/26/2015 SAFETY DATA SHEET Print Date: 1/13/2016 SDS Number: R0279263 Version: 1.1 Pliogrip™ 7400 ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 148949 considered hazardous under the OSHA Hazard Communication Standard (HazCom 2012). PROPYLENE CARBONATE 108-32-7 Eye Irrit. 2A; H319 1.49 SECTION 4. FIRST AID MEASURES General advice : Move out of dangerous area. Call a POISON CENTRE or doctor/physician if exposed or you feel unwell.
Page: 5 Revision Date: 05/26/2015 SAFETY DATA SHEET Pliogrip™ 7400 ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 148949 Print Date: 1/13/2016 SDS Number: R0279263 Version: 1.1 lung edema (fluid buildup in the lung tissue) Difficulty in breathing Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation.
Page: 6 Revision Date: 05/26/2015 SAFETY DATA SHEET Print Date: 1/13/2016 SDS Number: R0279263 Version: 1.1 Pliogrip™ 7400 ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 148949 emergency procedures Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so.
Page: 7 Revision Date: 05/26/2015 SAFETY DATA SHEET Print Date: 1/13/2016 SDS Number: R0279263 Version: 1.1 Pliogrip™ 7400 ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 148949 5709 4,4'-DIPHENYLMETHANE DIISOCYANATE 101-68-8 TWA REL Ceil_Time Ceiling TALC 14807-96-6 TWA REL TWA TWA Engineering measures Respirable fraction. 0.005 ppm 0.005 ppm 0.05 mg/m3 0.020 ppm 0.2 mg/m3 0.02 ppm 0.2 mg/m3 2 mg/m3 Respirable fraction. 2 mg/m3 Respirable. 0.1 mg/m3 Respirable.
Page: 8 Revision Date: 05/26/2015 SAFETY DATA SHEET Pliogrip™ 7400 ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 148949 Print Date: 1/13/2016 SDS Number: R0279263 Version: 1.1 Eye protection : Wear chemical splash goggles when there is the potential for exposure of the eyes to liquid, vapor or mist.
Page: 9 Revision Date: 05/26/2015 SAFETY DATA SHEET Pliogrip™ 7400 ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 148949 Density : 1.288 g/cm3 (20 °C) Solubility(ies) Water solubility : practically insoluble Solubility in other solvents : No data available Partition coefficient: noctanol/water : No data available Thermal decomposition : No data available Viscosity Viscosity, dynamic : ca. 20,000 mPa.
Page: 10 Revision Date: 05/26/2015 SAFETY DATA SHEET Pliogrip™ 7400 ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 148949 Print Date: 1/13/2016 SDS Number: R0279263 Version: 1.1 Hydrogen cyanide (hydrocyanic acid) Isocyanates Nitrogen oxides (NOx) SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation Skin contact Eye Contact Ingestion Acute toxicity Not classified based on available information.
Page: 11 Revision Date: 05/26/2015 SAFETY DATA SHEET Pliogrip™ 7400 ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 148949 Print Date: 1/13/2016 SDS Number: R0279263 Version: 1.1 Components: POLYMER: Result: Irritating to skin Remarks: Information given is based on data obtained from similar substances.
Page: 12 Revision Date: 05/26/2015 SAFETY DATA SHEET Pliogrip™ 7400 ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 148949 Print Date: 1/13/2016 SDS Number: R0279263 Version: 1.1 Respiratory or skin sensitisation Skin sensitisation: May cause an allergic skin reaction. Respiratory sensitisation: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Page: 13 Revision Date: 05/26/2015 SAFETY DATA SHEET Pliogrip™ 7400 ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 148949 Print Date: 1/13/2016 SDS Number: R0279263 Version: 1.1 Carcinogenicity Not classified based on available information. Product: : Methylene bisphenylisocyanate (MDI) aerosol has been Carcinogenicity Assessment reported to be irritating to lungs at a concentration of 1 mg/m3 with no effect observed at 0.2 mg/m3.
Page: 14 Revision Date: 05/26/2015 SAFETY DATA SHEET Print Date: 1/13/2016 SDS Number: R0279263 Version: 1.1 Pliogrip™ 7400 ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 148949 Carcinogenicity: IARC Group 2B: Possibly carcinogenic to humans TALC 14807-96-6 OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.
Page: 15 Revision Date: 05/26/2015 SAFETY DATA SHEET Pliogrip™ 7400 ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 148949 Print Date: 1/13/2016 SDS Number: R0279263 Version: 1.1 Test Type: static test Method: OECD Test Guideline 202 Remarks: Information given is based on data obtained from similar substances.
Page: 16 Revision Date: 05/26/2015 SAFETY DATA SHEET Pliogrip™ 7400 ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 148949 PROPYLENE CARBONATE: Biodegradability Print Date: 1/13/2016 SDS Number: R0279263 Version: 1.1 : Result: Readily biodegradable Biodegradation: 87.1 % Exposure time: 29 d Method: OECD Test Guideline 301B Bioaccumulative potential Components: PROPYLENE CARBONATE: Partition coefficient: noctanol/water : log Pow: -0.
Page: 17 Revision Date: 05/26/2015 SAFETY DATA SHEET Print Date: 1/13/2016 SDS Number: R0279263 Version: 1.1 Pliogrip™ 7400 ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 148949 ID NUMBER PROPER SHIPPING NAME *HAZARD CLASS SUBSIDIARY HAZARDS PACKING GROUP U.S. DOT - ROAD Not dangerous goods U.S. DOT - RAIL Not dangerous goods U.S.
Page: 18 Revision Date: 05/26/2015 SAFETY DATA SHEET Print Date: 1/13/2016 SDS Number: R0279263 Version: 1.1 Pliogrip™ 7400 ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 148949 Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. SECTION 15.
Page: 19 Revision Date: 05/26/2015 SAFETY DATA SHEET Print Date: 1/13/2016 SDS Number: R0279263 Version: 1.1 Pliogrip™ 7400 ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 148949 SCAVENGER URETHANE PREPOLYMER 254504001-5709 800986-5572P SECTION 16.
Page: 20 Revision Date: 05/26/2015 SAFETY DATA SHEET Pliogrip™ 7400 ADHESIVE ™ Trademark, Ashland or its subsidiaries, registered in various countries 148949 Print Date: 1/13/2016 SDS Number: R0279263 Version: 1.1 information is current, applicable, and suitable to their circumstances. This SDS has been prepared by Ashland's Environmental Health and Safety Department (1-800-325-3751).
