SAFETY DATA SHEET Issuing Date 27-Oct 2014 Revision Date 20-Oct-2014 Revision Number 1 1.
Hazard pictograms Signal word Hazard statements Warning! Harmful if swallowed or if inhaled. Causes serious eye irritation. Precautionary statements General Prevention Response Storage Disposal Hazards not otherwise classified Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Wear eye or face protection. Use only outdoors or in a well-ventilated area. Avoid breathing dust. Do not eat, drink or smoke when using this product.
4. FIRST AID MEASURES Description of necessary first aid measures Inhalation Skin contact Eye contact Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
5. FIRE-FIGHTING MEASURES Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Use an extinguishing agent suitable for the surrounding fire. None known. Specific hazards arising No specific fire or explosion hazard. from the chemical National Fire Protection Association (U.S.A.
6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures For non-emergency No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from personnel entering. Do not touch or walk through spilled material. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Occupational exposure limits Ingredient name CAS # Exposure limits benzyl alcohol 100-51-6 AIHA WEEL (United States, 10/2011). TWA: 10 ppm 8 hours. titanium dioxide 13463-67-7 ACGIH TLV (United States, 3/2012). TWA: 10 mg/m³ 8 hours. OSHA PEL 1989 (United States, 3/1989). TWA: 10 mg/m³ 8 hours. Form: Total dust OSHA PEL (United States, 6/2010). TWA: 15 mg/m³ 8 hours.
Hand protection Body protection Other skin protection Eye/face protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties.
10. STABILITY AND REACTIVITY Reactivity No specific test data related to reactivity available for this product or its ingredients. Chemical stability The product is stable. Possibility of hazardous reactions Under normal conditions of storage and use, hazardous reactions will not occur. Conditions to avoid No specific data. Incompatible materials No specific data. Hazardous decomposition Under normal conditions of storage and use, hazardous decomposition products should products not be produced.
Carcinogenicity No specific data. Classification Product/ingredient name titanium dioxide OSHA IARC NTP - 2B - Reproductive toxicity No specific data. Teratogenicity No specific data. Specific target organ toxicity (single exposure) No specific data. Specific target organ toxicity (repeated exposure) No specific data. Aspiration hazard No specific data. Information on the likely Not available. routes of exposure Potential acute health effects Eye contact Inhalation Causes serious eye irritation.
Mutagenicity Teratogenicity Developmental effects Fertility effects Numerical measures of toxicity Acute toxicity estimates Route Oral Dermal Inhalation (dusts and mists) No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. ATE Value 1703.4 mg/kg 8503.5 mg/kg 3.367 mg/l 12.
13. DISPOSAL CONSIDERATIONS Disposal methods The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.
15. REGULATORY INFORMATION United States U.S. Federal regulations Siloxanes and Silicones, di-Me, reaction products with silica TSCA 8(a) PAIR: TSCA 8(a) CDR Exempt/Partial exemption: Not determined All components are listed or United States inventory (TSCA 8b): exempted.
Canada WHMIS (Canada) Class D-1B: Material causing immediate and serious toxic effects (Toxic). Class D-2A: Material causing other toxic effects (Very toxic). Class D-2B: Material causing other toxic effects (Toxic). Class E: Corrosive material Canadian lists Canadian NPRI None of the components are listed. CEPA Toxic substances None of the components are listed. Canada inventory All components are listed or exempted.
Evaluation Warning : The document was created with Spire.PDF for .NET. SAFETY DATA SHEET Issuing Date 27-Oct 2014 Revision Date 20-Oct-2014 Revision Number 1 1.
Prevention Response Storage Disposal Hazards not otherwise classified Wear protective gloves. Wear eye or face protection. Avoid breathing dust. Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes.
Skin contact Causes skin irritation. May cause an allergic skin reaction. Eye contact Causes serious eye irritation. Ingestion Irritating to mouth, throat and stomach. Over-exposure signs/symptoms Inhalation No specific data. Skin contact Adverse symptoms may include the following: irritation redness Adverse symptoms may include the Eye contact following: pain or irritation watering redness No specific data.
6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures For non-emergency No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from personnel entering. Do not touch or walk through spilled material. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION Control parameters Occupational exposure limits Ingredient name CAS # Exposure limits carbon black respirable 1333-86-4 OSHA PEL 1989 (United States, 3/1989). TWA: 3.5 mg/m³ 8 hours. ACGIH TLV (United States, 6/2013). TWA: 3 mg/m³ 8 hours. Form: Inhalable fraction NIOSH REL (United States, 10/2013). TWA: 3.5 mg/m³ 10 hours. TWA: 0.1 mg of PAHs/cm³ 10 hours. OSHA PEL (United States, 2/2013). TWA: 3.5 mg/m³ 8 hours.
9. PHYSICAL AND CHEMICAL PROPERTIES Physical state Color Odor Odor threshold Solid. Black. Ethereal. Not available. pH Not available. Not available. Not available. [Product does not sustain combustion.] Melting point Boiling point Flash point Evaporation rate Flammability (solid, gas) Lower and upper explosive (flammable) limits Vapor pressure Vapor density Relative density Solubility Solubility in water Auto-ignition temperature Decomposition temperature Viscosity VOC (% content) Not available.
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Symptoms related to the physical, chemical and toxicological characteristics Eye contact Adverse symptoms may include the following: pain or irritation watering redness Inhalation Skin contact No specific data. Adverse symptoms may include the following: irritation redness No specific data. Ingestion Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate Not effects available. Potential delayed effects Not available.
Mobility in soil Soil/water partition coefficient (KOC) Other adverse effects Not available. No known significant effects or critical hazards. 13. DISPOSAL CONSIDERATIONS Disposal methods The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements.
Special provisions 8, 146, 335, B54, IB8, IP3, N20, T1, TP33 Packaging instructions: 956 Cargo Aircraft Only Quantity limitation: 400 kg Packaging instructions: 956 Limited Quantities – Passenger Aircraft Quantity limitation: 30 kg Packaging instructions: Y956 Special provisions 16 Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
State regulations Massachusetts New York New Jersey Pennsylvania Minnesota Hazardous Substances California Prop. 65 None of the components are listed. None of the components are listed. The following components are listed: CARBON BLACK The following components are listed: CARBON BLACK None of the components are listed. WARNING: This product contains a chemical known to the State of California to cause cancer.
