SAFETY DATA SHEET PRODUCT NAME: Mercury Free Carbon Zinc Battery Series Model No: R6 R03 R14 R20 6F22 Volts: 1.5 / cell Document Number: PAKKO2017Rseries Batteries are articles as defined under the GHS and exempt from GHS classification criteria (Section 1.3.2.1.1 of the GHS). The information and recommendations set forth herein are made in good faith, for information only, and are believed to be accurate as of the date of preparation.
Zinc (CAS# 7440-66-6) Zinc Chloride (CAS# 7646-85-7) Iron (CAS# 7439-89-6) 15 mg/m3 TWA Particulates not otherwise regulated (total dust) 5 mg/m3 TWA Particulates not otherwise regulated (respirable fraction) 1 mg/m3 TWA (fume) None established 10 mg/m3 TWA Particulates not otherwise classified (inhalable particulate) 3 mg/m3 TWA Particulates not otherwise classified (respirable particulate) 1 mg/m3 TWA (fume) 2 mg/m3 STEL (fume) None established 33 6 24 SECTION 4 – FIRST AID MEASURES Ingestion: Do no
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION Ventilation Requirements: Not necessary under normal conditions. Respiratory Protection: Not necessary under normal conditions. Eye Protection: Not necessary under normal conditions. Gloves: Not necessary under normal conditions. SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES Appearance (physical state, color, etc.
Viscosity Not applicable for an Article SECTION 10 – STABILITY AND REACTIVITY Zinc manganese dioxide batteries do not meet any of the criteria established in 40 CFR 261.2 for reactivity. SECTION 11 – TOXICOLOGICAL INFORMATION Under normal conditions of use, zinc manganese dioxide batteries are non-toxic. SECTION 12 – ECOLOGICAL INFORMATION Issues such as ecotoxicity, persistence and bioaccumulation are not applicable for articles.
SECTION 15 - REGULATORY INFORMATION Zinc manganese dioxide batteries are not classified as dangerous goods by the US Department of Transportation or the major international regulatory bodies and are therefore not regulated. SARA/TITLE III - As an article, this battery and its contents are not subject to the requirements of the Emergency Planning and Community Right-To-Know Act. SECTION 16 - OTHER INFORMATION None.
Page 1 of 6 Safety Data Sheet for Cylindrical Alkaline Battery Document Number: SDS100 Revision: 00 Date of prepared: 26 May 2015 Section I – Product and Company Identification Information of Product Product Identity (used on the label) Cylindrical Alkaline Battery – LR20, LR14, LR6, LR03 Information of Manufacturer Manufacturer’s Name Emergency Telephone Number GPI International Ltd.
Page 2 of 6 Safety Data Sheet for Cylindrical Alkaline Battery Document Number: SDS100 Revision: 00 Date of prepared: 26 May 2015 Section III – Composition/Information on Ingredients Chemical Nature: Alkaline zinc-manganese dioxide batteries Ingredient CAS No. Manganese Dioxide (MnO2) Zinc (Zn) Water (H2O) Potassium Hydroxide (KOH) Graphite Brass Steel Ni-plating Nylon-66 Fiber Mercury (Hg) Lead (Pb) Cadmium (Cd) Arsenic (As) Approximate %/wt LR03 LR6 LR14 LR20 1313-13-9 40.9 42.6 40.6 41.
Page 3 of 6 Safety Data Sheet for Cylindrical Alkaline Battery Document Number: SDS100 Revision: 00 Date of prepared: 26 May 2015 Section V – Fire-fighting Measures Suitable extinguishing media: Carbon dioxide (CO2), foam, dry chemical powder. Extinguishing media not to be used: Never use a direct water jet. Exposure hazards from combustion products: In case of fire, carbon dioxide, carbon monoxide and other toxic organic substances will be generated. Do not inhale fumes and smoke.
Page 4 of 6 Safety Data Sheet for Cylindrical Alkaline Battery Document Number: SDS100 Revision: 00 Date of prepared: 26 May 2015 Section IX – Physical and Chemical Properties Physical state: Stainless steel top battery Colour: Contents dark and gray in colour Odour: N.A. Melting point: N.A. Boiling point: N.A. Flash point: N.A. Explosion limit: Not available Ignition temperature: Not available Vapour pressure: Not available Specific gravity: N.A. Solubility in water: N.A.
Page 5 of 6 Safety Data Sheet for Cylindrical Alkaline Battery Document Number: SDS100 Revision: 00 Date of prepared: 26 May 2015 Section XIV – Transport Information Road (ADR/RID): Not regulated Air (ICAO/IATA): IATA DGR(55th): Special Provision A123: “Examples of such batteries are: alkali-manganese, zinc-carbon, nickelmetal hydride and nickel-cadmium batteries. Any electrical battery ...
Page 6 of 6 Safety Data Sheet for Cylindrical Alkaline Battery Document Number: SDS100 Revision: 00 Date of prepared: 26 May 2015 Section XVI – Other Information The information on this Safety Date Sheet (SDS) was obtained form current and reputable sources. However, the data is provided without any warranty; expressed or implied, regarding its correctness or accuracy. It is the user’s responsibility to assume liability on loss, injury, damage, or expense resulting from improper use of this product.
SAFETY DATA SHEET HCS-2012 APPENDIX D TO §1910.1200 Version 1 Product Name Alkaline battery LR03 AAA AM4 (Mercury free) Issue Date 14-May-2015 Revision date 14-May-2015 _____________________________________________________________________________________________ 1.
Product Name Alkaline battery LR03 AAA AM4 (Mercury free) Revision date 14-May-2015 _____________________________________________________________________________________________ Chemical nature Article Chemical Name Manganese dioxide Zinc Steel Sheet Water Potassium hydroxide Graphite Copper Nail Zinc Oxide CAS No 1313-13-9 7440-66-6 7439-89-6 7732-18-5 1310-58-3 7782-42-5 7440-50-8 1314-13-2 Weight-% 36 - 41 15 - 20 17.08 9.36 6.99 3.30 1.91 0.70 4.
Product Name Alkaline battery LR03 AAA AM4 (Mercury free) Revision date 14-May-2015 _____________________________________________________________________________________________ Do not touch or walk through spilled material Caustic potassium hydroxide may be released from leaking or ruptured batteries. Avoid breathing vapors or mists Methods and material for containment and cleaning up Pick up and transfer to properly labeled containers 7.
Product Name Alkaline battery LR03 AAA AM4 (Mercury free) Revision date 14-May-2015 _____________________________________________________________________________________________ mg/m3 fume Chemical Name Latvia Manganese dioxide (CAS #: TWA: 0.3 mg/m3 1313-13-9) Zinc (CAS #: 7440-66-6) Potassium hydroxide (CAS #: 1310-58-3) Graphite (CAS #: 7782-42-5) TWA: 2 mg/m3 France - Finland TWA: 0.2 mg/m3 TWA: 0.
Product Name Alkaline battery LR03 AAA AM4 (Mercury free) Revision date 14-May-2015 _____________________________________________________________________________________________ Individual protection measures, such as personal protective equipment Respiratory protection None required for normal use. Hand Protection None required for normal use. Use neoprene, rubber or latex gloves when handling leaking batteries. Eye/face protection None required for normal use.
Product Name Alkaline battery LR03 AAA AM4 (Mercury free) Revision date 14-May-2015 _____________________________________________________________________________________________ Hazardous Decomposition Products Carbon monoxide, carbon dioxide, lithium oxide fumes. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Inhalation of vapors or fumes released due to heat or a large number of leaking batteries may cause respiratory and eye irritation.
Product Name Alkaline battery LR03 AAA AM4 (Mercury free) Revision date 14-May-2015 _____________________________________________________________________________________________ Chemical Name Steel Sheet (CAS #: 7439-89-6) Algae/aquatic plants EC50 - Zinc (CAS #: 7440-66-6) 0.11 - 0.271 mg/L/96h Pseudokirchneriella subcapitata static 0.09 - 0.125 mg/L/72h Pseudokirchneriella subcapitata static Potassium hydroxide (CAS #: 1310-58-3) Copper Nail (CAS #: 7440-50-8) 0.031 - 0.
Product Name Alkaline battery LR03 AAA AM4 (Mercury free) Revision date 14-May-2015 _____________________________________________________________________________________________ Contaminated packaging Dispose of in accordance with federal, state and local regulations 14. TRANSPORT INFORMATION DOT UN/ID No. Proper shipping name Hazard Class Packing Group Special precautions Marine pollutant Not regulated Not regulated Not regulated Not regulated No information available Not applicable 15.
Product Name Alkaline battery LR03 AAA AM4 (Mercury free) Revision date 14-May-2015 _____________________________________________________________________________________________ Zinc 7440-66-6 Potassium hydroxide 1310-58-3 1000 lb - 1000 lb - RQ 454 kg final RQ RQ 1000 lb final RQ RQ 1000 lb final RQ RQ 454 kg final RQ US State Regulations California Proposition 65 Not apply U.S.
Safety Data Sheet According to HCS-2012 APPENDIX D TO §1910.1200 Version: 1.0/EN Product name: ALKALINE BATTERY Revision date: 29/04/2015 Issue date: 25/05/2015 1. Identification (a) Product identifier Product name: ALKALINE BATTERY (b) Other means of identification Product description: Model: LR03, LR6, LR14, LR20, LR1, 6LR61 Nominal Voltage:1.5V (c) Recommended use of the chemical and restrictions on use Recommended use: Restriction on use: ALKALINE BATTERY No information available.
Safety Data Sheet According to HCS-2012 APPENDIX D TO §1910.1200 Version: 1.0/EN Product name: ALKALINE BATTERY Revision date: 29/04/2015 Issue date: 25/05/2015 article as sold. Intended use of the product should not result in exposure to the chemical substance. This is a battery. In case of rupture: the above hazards exist.
Safety Data Sheet According to HCS-2012 APPENDIX D TO §1910.1200 Version: 1.0/EN Product name: ALKALINE BATTERY Revision date: 29/04/2015 Issue date: 25/05/2015 3. Composition/information on ingredients (a) Mixtures information Chemical name Manganese dioxide Graphite Potassium hydroxide Zinc Iron brass Water CAS No. 1313-13-9 7782-42-5 1310-58-3 7440-66-6 7439-89-6 12597-71-6 7732-18-5 Concentration% 36 4 6 20 20 3 11 4.
Safety Data Sheet According to HCS-2012 APPENDIX D TO §1910.1200 Version: 1.0/EN Product name: ALKALINE BATTERY Revision date: 29/04/2015 Issue date: 25/05/2015 CO2, Metal oxides, Irritating fumes. (c) Special protective equipment and precautions for fire-fighters Firefighters must wear fire resistant protective equipment and appropriate breathing apparatus. The staff must equip with filter mask (full mask) or isolated breathing apparatus.
Safety Data Sheet According to HCS-2012 APPENDIX D TO §1910.1200 Version: 1.
Safety Data Sheet According to HCS-2012 APPENDIX D TO §1910.1200 Version: 1.0/EN Product name: ALKALINE BATTERY Revision date: 29/04/2015 Issue date: 25/05/2015 (n) Solubility(ies) (o) Partition coefficient: n-octanol/water (p) Auto-ignition temperature (q) Decomposition temperature (r) Viscosity Insoluble in water. Not available. 130℃ Not available. Not available. 10. Stability and reactivity (a) Reactivity Stable under recommended storage and handling conditions.
Safety Data Sheet According to HCS-2012 APPENDIX D TO §1910.1200 Version: 1.0/EN Product name: ALKALINE BATTERY Germ Cell Mutagenicity: Reproductive Toxicity: STOT-Single Exposure: STOT-Repeated Exposure: Aspiration Hazard: Revision date: 29/04/2015 Issue date: 25/05/2015 No data available. No data available. No data available. No data available. No data available.
Safety Data Sheet According to HCS-2012 APPENDIX D TO §1910.1200 Version: 1.0/EN Product name: ALKALINE BATTERY Revision date: 29/04/2015 Issue date: 25/05/2015 14. Transport information Alkaline battery are unregulated for purpose of transportation by the U.S. Department of Transportation(DOT), International Civil Aviation Administration(ICAO), International Air Transport Association(IATA) and International maritime Dangerous Goods Regulations(IMDG).