Certifications 2

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SAFETY DATA SHEET

1,0

Version #: Issue date: Revision date:

25-March-2022 25-March-2022

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Trade name or designation

of the mixture

ZINK 62

Registration number

Austria: U25X-R867-500C-KKRR

Belgium: U25X-R867-500C-KKRR

Bulgaria: U25X-R867-500C-KKRR

Croatia: U25X-R867-500C-KKRR

Cyprus: U25X-R867-500C-KKRR

Czech Republic: U25X-R867-500C-KKRR

Denmark: U25X-R867-500C-KKRR

Estonia: U25X-R867-500C-KKRR

EU: U25X-R867-500C-KKRR

Finland: U25X-R867-500C-KKRR

France: U25X-R867-500C-KKRR

Germany: U25X-R867-500C-KKRR

Great Britain: U25X-R867-500C-KKRR

Greece: U25X-R867-500C-KKRR

Hungary: U25X-R867-500C-KKRR

Iceland: U25X-R867-500C-KKRR

Italy: U25X-R867-500C-KKRR

Latvia: U25X-R867-500C-KKRR

Lithuania: U25X-R867-500C-KKRR

Luxembourg: U25X-R867-500C-KKRR

Malta: U25X-R867-500C-KKRR

Netherlands: U25X-R867-500C-KKRR

Norway: U25X-R867-500C-KKRR

Poland: U25X-R867-500C-KKRR

Portugal: U25X-R867-500C-KKRR

Romania: U25X-R867-500C-KKRR

Slovakia: U25X-R867-500C-KKRR

Slovenia: U25X-R867-500C-KKRR

Spain: U25X-R867-500C-KKRR

Sweden: U25X-R867-500C-KKRR

UFI:

None.

Synonyms

BDS002608AE

Product code

1.2. Relevant identified uses of the substance or mixture and uses advised against

Paints

Identified uses

None known.

Uses advised against

1.3. Details of the supplier of the safety data sheet

CRC Industries Europe bv

Company name

Touwslagerstraat 1

Address

9240 Zele

Belgium

+32(0)52/45.60.11

Telephone

+32(0)52/45.00.34

Fax

hse@crcind.com

E-mail

www.crcind.com

Website

Tel.: +32(0)52/45.60.11 (office hours: 9-17h CET)

1.4. Emergency telephone

number

112 (Available 24 hours a day. SDS/Product information may not be available for

the Emergency Service.)

General in EU

+431 406 4343 (Available 24 hours a day. SDS/Product information may not be

available for the Emergency Service.)

Austria National Poisons

Information Centre

070 245 245 (Available 24 hours a day. SDS/Product information may not be

available for the Emergency Service.)

Belgium National Poisons

Control Center

SDS EU

Material name: ZINK 62 - Kontakt chemie - Europe

BDS002608AE Version #: 1,0 Revision date: 25-March-2022 Issue date: 25-March-2022

1 / 22

Summary of content (22 pages)

PAGE 1
SAFETY DATA SHEET Version #: Issue date: Revision date: 1,0 25-March-2022 25-March-2022 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1.
PAGE 2
Bulgaria National Toxicological Information Centre +359 2 9154233 (Available 24 hours a day. SDS/Product information may not be available for the Emergency Service.) Czech Republic National Poisons Information Centre +420 224 919 293, or +420 224 915 402 (Hours of operation not provided. SDS/Product information may not be available for the Emergency Service.) Denmark National Poisons Control Center +45 82 12 12 12 (Available 24 hours a day.
PAGE 3
Environmental hazards Hazardous to the aquatic environment, acute Category 1 aquatic hazard Hazardous to the aquatic environment, long-term aquatic hazard H400 - Very toxic to aquatic life. Category 1 H410 - Very toxic to aquatic life with long lasting effects. 2.2. Label elements Label according to Regulation (EC) No.
PAGE 4
Chemical name % Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, < 2% aromatics CAS-No. / EC No. REACH Registration No. 5 - 10 919-857-5 Index No. 01-2119463258-33 Notes - Classification: Flam. Liq. 3;H226, STOT SE 3;H336, Asp. Tox. 1;H304 Zinc oxide 1-5 1314-13-2 215-222-5 01-2119463881-32 030-013-00-7 Classification: Aquatic Acute 1;H400, Aquatic Chronic 1;H410 calcium;2-ethylhexanoate <0,5 136-51-6 205-249-0 01-2119978297-19 - Classification: Eye Dam. 1;H318, Repr.
PAGE 5
6.2. Environmental precautions 6.3. Methods and material for containment and cleaning up 6.4. Reference to other sections Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable.
PAGE 6
Belgium. Exposure Limit Values Components Dimethyl ether (CAS 115-10-6) Type Value TWA 1920 mg/m3 Form 1000 ppm Zinc oxide (CAS 1314-13-2) STEL 10 mg/m3 Respirable fraction. TWA 2 mg/m3 Respirable fraction. Bulgaria. OELs.
PAGE 7
Denmark. Exposure Limit Values Components Type Value Zinc oxide (CAS 1314-13-2) TLV 4 mg/m3 Estonia. OELs. Occupational Exposure Limits of Hazardous Substances (Regulation No.
PAGE 8
France.
PAGE 9
Greece. OELs (Decree No. 90/1999, as amended) Components Type Value TWA Form 600 mg/m3 200 ppm Dimethyl ether (CAS 115-10-6) TWA 1920 mg/m3 Zinc oxide (CAS 1314-13-2) STEL 10 mg/m3 Fume. TWA 5 mg/m3 Fume. Value Form 1000 ppm Hungary. OELs. Joint Decree on Chemical Safety of Workplaces Components Type butanone; ethyl methyl ketone (CAS 78-93-3) Dimethyl ether (CAS 115-10-6) Zinc oxide (CAS 1314-13-2) STEL 900 mg/m3 TWA 600 mg/m3 TWA 1920 mg/m3 TWA 5 mg/m3 Fume. 5 mg/m3 Dust.
PAGE 10
Latvia. OELs. Occupational exposure limit values of chemical substances in work environment Components Type Value butanone; ethyl methyl ketone (CAS 78-93-3) STEL 900 mg/m3 300 ppm TWA 200 mg/m3 67 ppm Dimethyl ether (CAS 115-10-6) TWA 1920 mg/m3 1000 ppm Zinc oxide (CAS 1314-13-2) TWA 0,5 mg/m3 Lithuania. OELs.
PAGE 11
Norway Components Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, < 2% aromatics Type Value TWA 275 mg/m3 Norway. Administrative Norms for Contaminants in the Workplace Components Type butanone; ethyl methyl ketone (CAS 78-93-3) TLV Value Form 220 mg/m3 75 ppm Dimethyl ether (CAS 115-10-6) TLV 384 mg/m3 200 ppm Zinc oxide (CAS 1314-13-2) TLV 5 mg/m3 Dust. 5 mg/m3 Respirable dust. 10 mg/m3 Total dust. Poland.
PAGE 12
Slovakia. OELs. Regulation No. 300/2007 concerning protection of health in work with chemical agents Form Components Type Value butanone; ethyl methyl ketone (CAS 78-93-3) STEL 900 mg/m3 300 ppm TWA 600 mg/m3 200 ppm Dimethyl ether (CAS 115-10-6) TWA 1920 mg/m3 1000 ppm zinc (CAS 7440-66-6) TWA Zinc oxide (CAS 1314-13-2) STEL TWA 2 mg/m3 Inhalable fraction. 0,1 mg/m3 Respirable fraction. 1 mg/m3 Respirable fume. 1 mg/m3 Respirable fume. Slovenia. OELs.
PAGE 13
Sweden. OELs. Work Environment Authority (AV), Occupational Exposure Limit Values (AFS 2015:7) Form Components Type Value 800 ppm TWA 950 mg/m3 500 ppm Zinc oxide (CAS 1314-13-2) TWA 5 mg/m3 Switzerland Components Type Value TWA 500 ppm STEL 6000 mg/m3 TWA 300 mg/m3 Hydrocarbons, C6-C7, n-alkanes,isoalkanes,cyclic s,< 5% n-hexane Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, < 2% aromatics Switzerland.
PAGE 14
Biological limit values Croatia. BLV. Dangerous Substance Exposure Limit Values at Workplace, Annexes 4 (as amended) Components Value Determinant Specimen Sampling Time butanone; ethyl methyl ketone (CAS 78-93-3) 2,6 mg/g methyl ethyl ketone Creatinine in urine * methyl ethyl ketone * - For sampling details, please see the source document. Creatinine in urine * 4,08 mmol/mol France.
PAGE 15
Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, < 2% aromatics (CAS -) Long-term, Systemic, Dermal 300 mg/kg Long-term, Systemic, Inhalation 900 mg/m3 Long-term, Systemic, Oral 300 mg/kg Workers Components Value butanone; ethyl methyl ketone (CAS 78-93-3) Long-term, Systemic, Dermal 1161 mg/kg bw/day Long-term, Systemic, Inhalation 600 mg/m3 Assessment factor Notes 1 1 Repeated dose toxicity Repeated dose toxicity calcium;2-ethylhexanoate (CAS 136-51-6) Long-term, Systemic, Dermal 5,67 mg/kg bw/
PAGE 16
Slovenia. OELs. Regulations concerning protection of workers against risks due to exposure to chemicals while working (Official Gazette of the Republic of Slovenia) butanone; ethyl methyl ketone (CAS 78-93-3) Can be absorbed through the skin. Switzerland SUVA Limit Values at the Workplace: Skin designation butanone; ethyl methyl ketone (CAS 78-93-3) Can be absorbed through the skin. UK EH40 WEL: Skin designation butanone; ethyl methyl ketone (CAS 78-93-3) Can be absorbed through the skin. 8.2.
PAGE 17
9.2. Other information 9.2.1. Information with regard to physical hazard classes No relevant additional information available. 9.2.2. Other safety characteristics Not explosive. Explosive properties Heat of combustion (NFPA 30B) 15,55 kJ/g estimated Oxidising properties Not oxidising. VOC 640 g/l SECTION 10: Stability and reactivity 10.1. Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. 10.2.
PAGE 18
Components Species Test Results Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, < 2% aromatics Acute Dermal LD50 Rabbit > 5000 mg/kg Oral LD50 Rat > 5000 mg/kg Dermal LD50 Rabbit > 2000 mg/l Inhalation LC50 Mammal 2500 mg/m³ Oral LD50 Mouse 7950 mg/kg Zinc oxide (CAS 1314-13-2) Acute Skin corrosion/irritation Causes skin irritation. Serious eye damage/eye irritation Causes serious eye irritation.
PAGE 19
Components Species Test Results Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, < 2% aromatics Acute Other LC50 Pseudokirchnerella subcapitata Aquatic Acute Fish > 1000 mg/l, 72 h LC50 Oncorhynchus mykiss > 1000 mg/l EC50 Selenastrum capricornutum (new name Pseudokirchnerella subca 0,137 mg/l, 72 hours Aquatic Acute Crustacea EC50 Daphnia magna 0,413 mg/l, 48 hours Chronic Crustacea NOEC Daphnia magna 82 µg/l, 7 days Zinc oxide (CAS 1314-13-2) Acute 12.2.
PAGE 20
Disposal methods/information Special precautions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Dispose in accordance with all applicable regulations.
PAGE 21
Marine pollutant SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulations Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I and II, as amended Not listed. Regulation (EU) 2019/1021 On persistent organic pollutants (recast), as amended Not listed. Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 1 as amended Not listed.
PAGE 22
References Information on evaluation method leading to the classification of mixture Full text of any H-statements not written out in full under Sections 2 to 15 ADN: European Agreement Concerning the International Carriage of Dangerous Goods by Inland Waterways. ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road. ADR: European Agreement Concerning the International Carriage of Dangerous Goods by Road.