SAFETY DATA SHEET 4402 Section 1. Identification Product name Product code Other means of identification : Industrial WORK DAY™ Enamel Spray Paint Gloss Black : 4402 : Not available. Product type : Aerosol. Relevant identified uses of the substance or mixture and uses advised against Not applicable.
Section 2. Hazards identification Hazard statements : Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes serious eye irritation. Causes skin irritation. Suspected of damaging the unborn child. Suspected of causing cancer. May be fatal if swallowed and enters airways. May cause respiratory irritation. May cause drowsiness and dizziness. May cause damage to organs through prolonged or repeated exposure.
Section 3. Composition/information on ingredients Ingredient name % by weight CAS number Acetone Propane Butane Toluene Lt. Aliphatic Hydrocarbon Solvent 1,2,4-Trimethylbenzene Carbon Black Cumene 28.7 17.9 17.2 14.5 9.5 1.2 0.6 0.
Section 4.
Section 5. Fire-fighting measures Special protective equipment for fire-fighters : Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency personnel : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas.
Section 7. Handling and storage Conditions for safe storage, including any incompatibilities : Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination. Section 8.
Section 8. Exposure controls/personal protection NIOSH REL (United States, 10/2013). Absorbed through skin. TWA: 50 ppm 10 hours. TWA: 245 mg/m³ 10 hours. OSHA PEL (United States, 2/2013). Absorbed through skin. TWA: 50 ppm 8 hours. TWA: 245 mg/m³ 8 hours. Appropriate engineering controls Environmental exposure controls : Use only with adequate ventilation.
Section 9. Physical and chemical properties Appearance Physical state : Liquid. Color : Not available. Odor Odor threshold pH : Not available. : Not available. Melting point : 7 : Not available. Boiling point : Not available. Flash point : Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup] Evaporation rate : 5.6 (butyl acetate = 1) Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Lower: 0.9% Upper: 12.8% Vapor pressure : 13.5 kPa (101.
Section 11.
Section 11. Toxicological information Product/ingredient name OSHA IARC NTP Toluene Carbon Black Cumene - 3 2B 2B - Reproductive toxicity Not available. Teratogenicity Not available. Specific target organ toxicity (single exposure) Name Category Route of exposure Target organs Acetone Category 3 Not applicable. Propane Category 3 Not applicable. Butane Category 3 Not applicable. Toluene Category 3 Not applicable. Lt. Aliphatic Hydrocarbon Solvent Category 3 Not applicable.
Information on the likely routes of exposure : Not available. Potential acute health effects Eye contact : Causes serious eye irritation. Inhalation Skin contact Ingestion : Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. May cause respiratory irritation. : Causes skin irritation. : Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach.
Teratogenicity : Suspected of damaging the unborn child. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Numerical measures of toxicity Acute toxicity estimates Route ATE value Oral Inhalation (vapors) 3160.2 mg/kg 1129.7 mg/l Section 12. Ecological information Toxicity Product/ingredient name Result Species Exposure Acetone Acute EC50 20.
Section 12. Ecological information Product/ingredient name LogPow BCF Potential Toluene Lt. Aliphatic Hydrocarbon Solvent 1,2,4-Trimethylbenzene Cumene - 90 10 to 2500 low high - 243 94.69 low low Mobility in soil Soil/water partition coefficient (KOC) : Not available. Other adverse effects : No known significant effects or critical hazards. Section 13. Disposal considerations Disposal methods : The generation of waste should be avoided or minimized wherever possible.
Section 14. Transport information Special precautions for user : Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport.
Section 16. Other information It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given.