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Lithium Manganese Dioxide Coin Cell Batteries

August, 2009

As a courtesy to our customers, Energizer has prepared copyrighted Product Safety Datasheets to provide information on the different

Eveready/Energizer battery systems. As defined in OSHA Hazard Communication Standard, Section 1910.1200 (c), Eveready/Energizer batteries are

manufactured “articles”, which do not result in exposure to a hazardous chemical under normal conditions of use. For this reason, Material Safety

Datasheets are not required. The information and recommendations set forth herein are made in good faith, for information only, and are believed to be

accurate as of the date of preparation. However, ENERGIZER BATTERY MANUFACTURING, INC., MAKES NO WARRANTY, EITHER EXPRESS OR

IMPLIED, WITH RESPECT TO THIS INFORMATION AND DISCLAIMS ALL LIABILITY FROM REFERENCE ON IT.

PRODUCT SAFETY DATA SHEET

PRODUCT NAME: Energizer Battery Type No.: Volts: 3.0

TRADE NAMES: Energizer Lithium Manganese Dioxide Batteries Approximate Weight: 0.6 – 7.0 g

CHEMICAL SYSTEM: Lithium Manganese Dioxide Coin Cells

Designed for Recharge: No

SECTION 1- MANUFACTURER INFORMATION

Manufactured for

Energizer Battery Manufacturing, Inc. Telephone Number for Information:

25225 Detroit Rd.

Westlake, OH 44145

800-383-7323 (USA / CANADA)

Date Prepared: August, 2009

SECTION 2 – HAZARDS IDENTIFICATION

Under normal conditions of use, the battery is hermetically sealed.

Ingestion: Swallowing a battery can be harmful. 3 volt lithium coin batteries lodged in the esophagus should be removed immediately.

Leakage, chemical burns and potential perforation can occur within hours of ingestion. Seek medical attention immediately. Have physician

call the NATIONAL BATTERY INGESTION HOTLINE for advice and follow-up (202-625-3333) collect day or night.

Inhalation: Contents of an open battery can cause respiratory irritation.

Skin Contact: Contents of an open battery can cause skin irritation.

Eye Contact: Contents of an open battery can cause severe irritation.

SECTION 3 - INGREDIENTS

IMPORTANT NOTE: The battery should not be opened or burned. Exposure to the ingredients contained within or their combustion products could be

harmful.

MATERIAL OR INGREDIENT PEL (OSHA) TLV (ACGIH) %/wt.

Carbon Black

(CAS# 1333-86-4)

3.5 mg/m

TWA 3.5 mg/m

TWA 0-1

1,2-Dimethoxyethane

(CAS# 110-71-4)

None established None established 0-6

1,3-Dioxolane

(CAS# 646-06-0)

None established None established 0-8

Graphite

(CAS# 7782-42-5)

15 mg/m

TWA (total dust)

5 mg/m

TWA (respirable fraction)

2 mg/m

TWA (respirable fraction) 0-3

Lithium or Lithium Alloy

(CAS# 7439-93-2)

None established None established 1-6

Lithium Perchlorate

(CAS# 7791-03-9)

None established None established 0-3

Lithium Trifluoromethanesulfonate

(CAS# 33454-82-9)

None established None established 0-3

Summary of content (4 pages)

PAGE 1
Page 1 of 4 Lithium Manganese Dioxide Coin Cell Batteries August, 2009 As a courtesy to our customers, Energizer has prepared copyrighted Product Safety Datasheets to provide information on the different Eveready/Energizer battery systems. As defined in OSHA Hazard Communication Standard, Section 1910.1200 (c), Eveready/Energizer batteries are manufactured “articles”, which do not result in exposure to a hazardous chemical under normal conditions of use.
PAGE 2
Page 2 of 4 Lithium Manganese Dioxide Coin Cell Batteries August, 2009 Lithium Trifluoromethanesulfonimide (CAS# 90076-65-6) None established None established 0-3 Manganese Dioxide (CAS# 1313-13-9) 5 mg/m3 Ceiling (as Mn) 0.
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Page 3 of 4 Lithium Manganese Dioxide Coin Cell Batteries August, 2009 Handling: Accidental short circuit for a few seconds will not seriously affect the battery. Prolonged short circuit will cause the battery to lose energy, generate significant heat and can cause the safety release vent to open. Sources of short circuits include jumbled batteries in bulk containers, metal jewelry, metal covered tables or metal belts used for assembly of batteries into devices.
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Page 4 of 4 Lithium Manganese Dioxide Coin Cell Batteries August, 2009 SECTION 10 – STABILITY AND REACTIVITY Lithium manganese dioxide batteries do not meet any of the criteria established in 40 CFR 261.2 for reactivity. SECTION 11 – TOXICOLOGICAL INFORMATION Lithium manganese dioxide batteries are not hazardous waste. Under normal conditions of use, lithium manganese dioxide batteries are non-toxic.