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SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME:

LEAD ACID BATTERIES:

DEEP CYCLE & INDUSTRIAL

UN NUMBER:

2794

MANUFACTURER:

CROWN BATTERY

MANUFACTURING COMPANY

ADDRESS:

P.O. Box 990

1445 Majestic Drive

Fremont Ohio, 43420

CHEMTREC:

800.424.9300

(Domestic)

703.527.3887

(International)

CANUTEC:

613.996.6666 (Canada)

OTHER CALLS:

419.334.7181

FAX PHONE:

419.334.7416

COMPANY WEBSITE:

www.crownbattery.com

SECTION 2: GHS HAZARDS IDENTIFICATION

SAFETY DATA SHEET

EFFECTIVE DATE: 10/1/18

HEALTH ENVIRONMENTAL PHYSICAL

Acute Toxicity (Oral/Dermal/Inhalation)

Category 4

Aquatic Chronic 1 Explosive Chemical,

Division 1.3

Skin Corrosion/Irritation

Category 1A

Aquatic Acute 1

Eye Damage

Category 1

Reproductive

Category 1A

Carcinogenicity (lead compounds)

Category 1B

Carcinogenicity (arsenic)

Category 1A

Carcinogenicity (acid mist)

Category 1A

Speciﬁc Target Organ Toxicity (repeated exposure)

Category 2

Hazard Statements –

DANGER!

Harmful if swallowed, inhaled, or in contact with skin.

Acid causes severe skin burns and eye damage.

May damage fertility or the unborn child if ingested or inhaled.

May cause harm to breast-fed children.

May cause cancer if ingested or inhaled.

Causes skin irritation, serious eye damage.

Contact with internal components may cause irritation or severe

burns.

Causes damage to central nervous system, blood and kidneys

through prolonged or repeated exposure if ingested or inhaled.

Irritating to eyes, respiratory system, and skin.

May form explosive air/gas mixture during charging.

Extremely ﬂammable gas (hydrogen).

Explosive, ﬁre, blast or projection hazard

Precautionary Statements

Obtain special instructions before use.

Do not handle until all safety precautions have been read and understood.

Wash thoroughly after handling.

Do not eat drink or smoke when using this product.

Avoid contact during pregnancy/while nursing.

Wear protective gloves/protective clothing, eye protection/face protection.

Use only outdoors or in a well-ventilated area.

Avoid contact with internal acid.

Do not breathe dust/fume/gas/mist/vapors/spray.

Keep away from heat/sparks/open ﬂames/hot surfaces. No smoking

IF SWALLOWED OR CONSUMED: rinse mouth.

Do NOT induce vomiting. Call a poison center/doctor if you feel unwell.

IF ON CLOTHING OR SKIN (or hair): Remove/Take off immediately all contaminated

clothing and wash it before reuse. Rinse skin with water/shower.

IF INHALED: Remove person to fresh air and keep comfortable for breathing.

Immediately call a POISON CENTER or doctor/physician.

IF IN EYES: Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue rinsing.

If exposed/concerned, or if you feel unwell seek medical attention/advice.

Store locked up, in a well-ventilated area, in accordance with local and national regulation.

Dispose of contents/container in accordance with local and national regulation.

Keep out of reach of children.

SYNONYMS:

Industrial Battery, Traction Battery,

Stationary Battery, Deep Cycle Battery

CHEMICAL

FORMULA:

PbO2 + Pb +2H2SO4 = 2PbSO4 + 2H2O

PRODUCT USE:

Batteries, wet, ﬁlled with acid

PREPARED BY:

Jim Anderson

Summary of content (8 pages)

PAGE 1
EFFECTIVE DATE: 10/1/18 SAFETY DATA SHEET SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: LEAD ACID BATTERIES: DEEP CYCLE & INDUSTRIAL UN NUMBER: 2794 MANUFACTURER: CROWN BATTERY MANUFACTURING COMPANY ADDRESS: P.O. Box 990 1445 Majestic Drive Fremont Ohio, 43420 CHEMTREC: 800.424.9300 (Domestic) 703.527.3887 (International) CANUTEC: 613.996.6666 (Canada) OTHER CALLS: 419.334.7181 FAX PHONE: 419.334.7416 COMPANY WEBSITE: www.crownbattery.
PAGE 2
SAFETY DATA SHEET (continued) SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS INGREDIENTS (CHEMICAL/COMMON NAMES): CAS NO.: % BY WT: Lead and Lead Compounds 7439-92-1 50 to 75 Antimony 7440-36-0 < 0.1 Sulfuric Acid 7664-93-9 5 to 15 N.A 1 to 2 Water 7732-18-5 23 to 25 Arsenic 7440-38-2 < 0.1 Inert Components (Separator Material) SECTION 4: FIRST AID MEASURES INHALATION: Sulfuric Acid: Remove to fresh air immediately. If not breathing, give artificial respiration.
PAGE 3
SAFETY DATA SHEET (continued) SECTION 6: ACCIDENTAL RELEASE MEASURES Stop flow of material, contain/absorb small spills with dry sand, earth or vermiculite. Do not use combustible materials. If possible, carefully neutralize spilled electrolyte with soda ash, sodium bicarbonate, lime, etc. Wear acid-resistant clothing, boots, gloves, and face shield. Do not allow discharge of un-neutralized acid to sewer. Acid must be managed in accordance with approved local, state, and federal requirements.
PAGE 4
SAFETY DATA SHEET (continued) SKIN PROTECTION: If battery case is damaged, use rubber or plastic acid-resistant gloves with elbow-length gauntlet, acid-resistant apron, clothing and boots. EYE PROTECTION: If battery case is damaged, use chemical goggles or face shield. OTHER PROTECTION: In areas where water and sulfuric acid solutions are handled in concentrations greater than 1%, emergency eyewash stations and showers should be provided, with unlimited water supply.
PAGE 5
SAFETY DATA SHEET (continued) SECTION 11: TOXICOLOGICAL INFORMATION ROUTES OF ENTRY: Sulfuric Acid: Harmful by all routes of entry. Lead Compounds: Hazardous exposure can occur only when product is heated, oxidized or otherwise processed or damaged to create dust, vapor or fume. The presence of nascent hydrogen may generate highly toxic arsine gas. INHALATION: Sulfuric Acid: Breathing of sulfuric acid vapors or mists may cause severe respiratory irritation.
PAGE 6
SAFETY DATA SHEET ACUTE TOXICITY: Inhalation LD50: Electrolyte: Elemental Lead: Elemental arsenic: Oral LD50: Electrolyte: Elemental lead: Elemental arsenic: Elemental Antimony: (continued) LC50 rat: 375 mg/m3; LC50: guinea pig: 510 mg/m3 Acute Toxicity Point Estimate = 4500 ppmV (based on lead bullion) No data rat: 2140 mg/kg Acute Toxicity Estimate (ATE) = 500 mg/kg body weight (based on lead bullion) LD50 mouse: 145 mg/kg LD50 rat: 100 mg/kg ADDITIONAL HEALTH DATA: All heavy metals, including the haza
PAGE 7
SAFETY DATA SHEET (continued) SECTION 14: TRANSPORT INFORMATION UNITED STATES: The U.S. Department of Transportation (DOT) hazardous materials regulations (49 CFR) applicable to lead acid batteries are specified in 49 CFR 173.159. Proper Shipping Name: Hazard Class: ID Number: Packing Group: Labels: Batteries, wet, filled with acid 8 UN2794 N/A Corrosive 49 CFR 173.
PAGE 8
SAFETY DATA SHEET (continued) EPCRA Section 313 The reporting of lead and sulfuric acid (and their releases) in lead-acid batteries used in cars, trucks, most cranes, forklifts, locomotive engines, and aircraft for the purposes of EPCRA Section 313 is not required. Lead-acid batteries used for these purposes are exempt for Section 313 reporting per the “Motor Vehicle Exemption.” See page B-22 of the U.S.