Safety Data Sheet according to Regulation (EC) No 1907/2006 Page 1 of 14 SDS No. : 442955 V003.3 Revision: 27.07.2016 printing date: 15.05.2017 Replaces version from: 12.01.2016 LOCTITE 454 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier LOCTITE 454 Contains: Ethyl 2-cyanoacrylate 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Adhesive 1.3.
MSDS-No.: 442955 V003.3 LOCTITE 454 Page 2 of 14 Signal word: Warning Hazard statement: H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. Supplemental information EUH202 Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children. Precautionary statement: Prevention P261 Avoid breathing vapours. P280 Wear protective gloves/eye protection.
MSDS-No.: 442955 V003.3 LOCTITE 454 Page 3 of 14 SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Move to fresh air, consult doctor if complaint persists. Skin contact: Do not pull bonded skin apart. It may be gently peeled apart using a blunt object such as a spoon, preferably after soaking in warm soapy water. Cyanoacrylates give off heat on solidification. In rare cases a large drop will generate enough heat to cause a burn.
MSDS-No.: 442955 V003.3 LOCTITE 454 Page 4 of 14 6.2. Environmental precautions Do not empty into drains / surface water / ground water. 6.3. Methods and material for containment and cleaning up Do not use cloths for mopping up. Flood with water to complete polymerization and scrape off the floor. Cured material can be disposed of as non-hazardous waste. 6.4. Reference to other sections See advice in section 8 SECTION 7: Handling and storage 7.1.
MSDS-No.: 442955 V003.
MSDS-No.: 442955 V003.
MSDS-No.: 442955 V003.3 LOCTITE 454 Page 7 of 14 Biological Exposure Indices: None 8.2. Exposure controls: Engineering controls: Ensure good ventilation/extraction. Respiratory protection: Ensure adequate ventilation. An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly ventilated area Filter type: A Hand protection: Chemical-resistant protective gloves (EN 374).
MSDS-No.: 442955 V003.3 LOCTITE 454 () Bulk density Viscosity (; Instrument: RVT; speed of rotation: 20 min1; Spindle No: TC) Viscosity (kinematic) Explosive properties Solubility (qualitative) (Solvent: Water) Solidification temperature Melting point Flammability Auto-ignition temperature Explosive limits Partition coefficient: n-octanol/water Evaporation rate Vapor density Oxidising properties Page 8 of 14 No data available / Not applicable 18.000 - 40.000 mPa.
MSDS-No.: 442955 V003.3 LOCTITE 454 Page 9 of 14 Skin irritation: Causes skin irritation. Bonds skin in seconds. Considered to be of low toxicity: acute dermal LD50 (rabbit)>2000mg/kg Due to polymerisation at the skin surface allergic reaction is unlikely to occur Eye irritation: Causes serious eye irritation. Liquid product will bond eyelids. In a dry atmosphere (RH<50%) vapours may cause irritation and lachrymatory effect Acute oral toxicity: Hazardous components CAS-No.
MSDS-No.: 442955 V003.3 LOCTITE 454 Page 10 of 14 Germ cell mutagenicity: Hazardous components CAS-No. Ethyl 2-cyanoacrylate 7085-85-0 Result negative negative negative Bis(2-hydroxy-3-tertbutyl-5methylphenyl)methane 119-47-1 Hydroquinone 123-31-9 negative negative Type of study / Route of administration bacterial reverse mutation assay (e.
MSDS-No.: 442955 V003.3 LOCTITE 454 Page 11 of 14 Hazardous components CAS-No. Value type Value Exposure time > 10.
MSDS-No.: 442955 V003.3 LOCTITE 454 Bis(2-hydroxy-3-tert-butyl-5methylphenyl)methane 119-47-1 Hydroquinone 123-31-9 Page 12 of 14 Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vPvB) criteria. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vPvB) criteria. 12.6. Other adverse effects No data available. SECTION 13: Disposal considerations 13.1.
MSDS-No.: 442955 V003.3 LOCTITE 454 Page 13 of 14 SECTION 14: Transport information 14.1. UN number ADR RID ADN IMDG IATA 14.2. UN proper shipping name ADR RID ADN IMDG IATA 14.3. not applicable not applicable not applicable not applicable not applicable Special precautions for user ADR RID ADN IMDG IATA 14.7. Not dangerous goods Not dangerous goods Not dangerous goods Not dangerous goods III Environmental hazards ADR RID ADN IMDG IATA 14.6.
MSDS-No.: 442955 V003.3 LOCTITE 454 Page 14 of 14 SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: H302 Harmful if swallowed. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H341 Suspected of causing genetic defects.