Safety Data Sheet according to (EC) No 1907/2006 as amended Page 1 of 31 SDS No. : 450730 V011.0 Revision: 25.03.2022 printing date: 28.03.2022 Replaces version from: 11.10.2021 LOCTITE 648 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier LOCTITE 648 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Adhesive 1.3.
SDS No.: 450730 V011.0 LOCTITE 648 Page 2 of 31 Hazard pictogram: Contains 3,3,5 Trimethylcyclohexyl methacrylate 2-Hydroxyethyl methacrylate Acrylic acid Hydroxypropyl methacrylate maleic acid Acetic acid, 2-phenylhydrazide 2,2'-Ethylenedioxydiethyl dimethacrylate 2-Propenoic acid, 2-methyl-, 2-(2-hydroxyethoxy)ethyl ester S ignal word: Danger Hazard statement: H315 Causes skin irritation. H317 M ay cause an allergic skin reaction. H318 Causes serious eye damage.
SDS No.: 450730 V011.0 LOCTITE 648 Page 3 of 31 Declaration of the ingredients according to CLP (EC) No 1272/2008: Haz ardous components CAS-No. EC Number REACH-Reg No. Reaction mass of (1methylethylidene)bis(4,1phenyleneoxy-2,1-ethanediyl) bismethacrylate and 2-{4-[2-(4{2-[2-(methacryloyloxy)etho Concentration Classification 25- < 50 % Aquatic Chronic 4, H413 3,3,5 T rimethylcyclohexyl methacrylate 7779-31-9 231-927-0 01-2120748527-45 10- < 20 % Aquatic Chronic 2, H411 Skin Sens.
SDS No.: 450730 V011.0 LOCTITE 648 Page 4 of 31 2,2'-Ethylenedioxydiethyl dimethacrylate 109-16-0 203-652-6 01-2119969287-21 0,1- < 1 % Skin Sens. 1B, H317 2-Propenoic acid, 2-methyl-, 2(2-hydroxyethoxy)ethyl ester 2351-43-1 0,1- < 1 % Eye Irrit. 2, H319 Skin Sens. 1, H317 dermal:AT E = > 5.000 mg/kg inhalation:ATE = 28,17 mg/l;dust/mist For full text of the H - statements and other abbreviations see section 16 "Other information".
SDS No.: 450730 V011.0 LOCTITE 648 6.1. Personal precautions, protective equipment and emergency procedures Avoid contact with skin and eyes. Wear protective equipment. Ensure adequate ventilation. Keep away from sources of ignition. 6.2. Environmental precautions Do not empty into drains / surface water / ground water. 6.3. Methods and material for containment and cleaning up Dispose of contaminated material as waste according to Section 13.
SDS No.: 450730 V011.0 LOCTITE 648 Page 6 of 31 SECTION 8: Exposure controls/personal protection 8.1.
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SDS No.: 450730 V011.0 LOCTITE 648 27813-02-1 Methacrylic acid, monoester with propane1,2-diol 27813-02-1 Methacrylic acid, monoester with propane1,2-diol 27813-02-1 Methacrylic acid, monoester with propane1,2-diol 27813-02-1 Methacrylic acid, monoester with propane1,2-diol 27813-02-1 Methacrylic acid, monoester with propane1,2-diol 27813-02-1 Methacrylic acid, monoester with propane1,2-diol 27813-02-1 .alpha.,.alpha.-Dimethylbenzyl hydroperoxide 80-15-9 .alpha.,.alpha.
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SDS No.: 450730 V011.0 LOCTITE 648 Page 12 of 31 Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.
SDS No.: 450730 V011.0 LOCTITE 648 Page 13 of 31 10.2. Chemical stability Stable under recommended storage conditions. 10.3. Possibility of hazardous reactions See section reactivity 10.4. Conditions to avoid Stable under normal conditions of storage and use. 10.5. Incompatible materials See section reactivity. 10.6. Hazardous decomposition products carbon oxides. Hydrocarbons nitrogen oxides Rapid polymerisation may generate excessive heat and pressure.
SDS No.: 450730 V011.0 LOCTITE 648 Page 14 of 31 Acute dermal toxicity: The mixture is classified based on calculation method referring to the classified substances present in the mixture. Haz ardous substances CAS-No.
SDS No.: 450730 V011.0 LOCTITE 648 Page 15 of 31 Acute inhalative toxicity: The mixture is classified based on calculation method referring to the classified substances present in the mixture. Haz ardous substances CAS-No.
SDS No.: 450730 V011.0 LOCTITE 648 Page 16 of 31 S erious eye damage/irritation: The mixture is classified based on calculation method referring to the classified substances present in the mixture. Haz ardous substances CAS-No.
SDS No.: 450730 V011.0 LOCTITE 648 Page 17 of 31 Respiratory or skin sensitization: The mixture is classified based on threshold limits referring to the classified substances present in the mixture. Haz ardous substances CAS-No.
SDS No.: 450730 V011.0 LOCTITE 648 Page 18 of 31 Germ cell mutagenicity: The mixture is classified based on threshold limits referring to the classified substances present in the mixture. Haz ardous substances CAS-No.
SDS No.: 450730 V011.0 LOCTITE 648 maleic acid 110-16-7 negative maleic acid 110-16-7 negative methacrylic acid 79-41-4 negative 2,2'-Ethylenedioxydiethyl negative dimethacrylate 109-16-0 2,2'-Ethylenedioxydiethyl negative dimethacrylate 109-16-0 2,2'-Ethylenedioxydiethyl negative dimethacrylate 109-16-0 Page 19 of 31 Ames test) bacterial reverse no data mutation assay (e.
SDS No.: 450730 V011.0 LOCTITE 648 Page 20 of 31 Reproductive toxicity: The mixture is classified based on threshold limits referring to the classified substances present in the mixture. Haz ardous substances Result / Value CAS-No. Reaction mass of (1NOAEL P 1.000 mg/kg methylethylidene)bis(4,1phenyleneoxy-2,1ethanediyl) bismethacrylate and 2-{4[2-(4-{2-[2(methacryloyloxy)etho 2-Hydroxyethyl NOAEL P >= 1.000 mg/kg methacrylate 868-77-9 NOAEL F1 >= 1.
SDS No.: 450730 V011.0 LOCTITE 648 Page 21 of 31 S TOT-repeated exposure:: The mixture is classified based on threshold limits referring to the classified substances present in the mixture. Haz ardous substances CAS-No.
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SDS No.: 450730 V011.0 LOCTITE 648 Page 23 of 31 SECTION 12: Ecological information General ecological information: Do not empty into drains / surface water / ground water. 12.1. Toxicity Toxicity (Fish): The mixture is classified based on calculation method referring to the classified substances present in the mixture. Haz ardous substances CAS-No.
SDS No.: 450730 V011.0 LOCTITE 648 Page 24 of 31 Reaction products of 4,4'isopropylidenediphenol, ethoxylated and methacrylic acid Cumene hydroperoxide 80-15-9 EL50 T oxicity > Water solubility 48 h Daphnia magna EC50 18,84 mg/l 48 h Daphnia magna maleic acid 110-16-7 EC50 42,81 mg/l 48 h Daphnia magna methacrylic acid 79-41-4 EC50 > 130 mg/l 48 h Daphnia magna Immobilisation Test) OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) OECD Guideline 202 (Daphnia sp.
SDS No.: 450730 V011.0 LOCTITE 648 Page 25 of 31 The mixture is classified based on calculation method referring to the classified substances present in the mixture. Haz ardous substances CAS-No.
SDS No.: 450730 V011.0 LOCTITE 648 Page 26 of 31 Hydroxypropyl methacrylate EC10 27813-02-1 Cumene hydroperoxide EC10 80-15-9 maleic acid EC10 110-16-7 1.140 mg/l 16 h Consumption by Activated Sludge) not specified 70 mg/l 30 min not specified 44,6 mg/l 18 h methacrylic acid 79-41-4 100 mg/l 17 h EC10 Pseudomonas putida DIN 38412, part 8 (Pseudomonas ZellvermehrungshemmT est) not specified 12.2. Persistence and degradability Haz ardous substances CAS-No.
SDS No.: 450730 V011.0 Haz ardous substances CAS-No. Acrylic acid 79-10-7 Cumene hydroperoxide 80-15-9 12.4.
SDS No.: 450730 V011.0 LOCTITE 648 Haz ardous substances CAS-No.
SDS No.: 450730 V011.0 LOCTITE 648 Page 29 of 31 Product disposal: Do not empty into drains / surface water / ground water. Dispose of in accordance with local and national regulations. Disposal of uncleaned packages: After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in an authorised legal land fill site or incinerated.
SDS No.: 450730 V011.0 LOCTITE 648 RID ADN IM DG IATA 14.7. not applicable not applicable not applicable not applicable Maritime transport in bulk according to IMO instruments not applicable SECTION 15: Regulatory information 15.1.
SDS No.: 450730 V011.0 LOCTITE 648 Page 31 of 31 SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: H226 Flammable liquid and vapor. H242 Heating may cause a fire. H301 Toxic if swallowed. H302 Harmful if swallowed. H311 Toxic in contact with skin. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation.
