Safety Data Sheet according to Regulation (EC) No 1907/2006 Page 1 of 14 SDS No. : 298562 V008.0 Revision: 11.04.2017 printing date: 12.06.2017 Replaces version from: 23.06.2016 LOCTITE EA 3430 A BULK SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier LOCTITE EA 3430 A BULK Contains: Epoxy resin (number average molecular weight ≤ 700) Bisphenol-F epichlorhydrin resin; MW<700 Bisphenol A diglycidyl ether polymer 1.2.
MSDS-No.: 298562 V008.0 LOCTITE EA 3430 A BULK Page 2 of 14 Hazard pictogram: Signal word: Warning Hazard statement: H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H411 Toxic to aquatic life with long lasting effects. Precautionary statement: ***For consumer use only: P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children.
MSDS-No.: 298562 V008.0 LOCTITE EA 3430 A BULK SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Move to fresh air. If symptoms persist, seek medical advice. Skin contact: Rinse with running water and soap. Obtain medical attention if irritation persists. Eye contact: Rinse immediately with plenty of running water (for 10 minutes). Seek medical attention if necessary. Ingestion: Rinse out mouth, drink 1-2 glasses of water, do not induce vomiting. Seek medical advice. 4.2.
MSDS-No.: 298562 V008.0 LOCTITE EA 3430 A BULK 6.3. Methods and material for containment and cleaning up For small spills wipe up with paper towel and place in container for disposal. For large spills absorb onto inert absorbent material and place in sealed container for disposal. Wash spillage site thoroughly with soap and water or detergent solution. Dispose of contaminated material as waste according to Section 13. 6.4.
MSDS-No.: 298562 V008.
MSDS-No.: 298562 V008.
MSDS-No.: 298562 V008.0 LOCTITE EA 3430 A BULK Page 7 of 14 Biological Exposure Indices: None 8.2. Exposure controls: Engineering controls: Ensure good ventilation/extraction. Respiratory protection: Ensure adequate ventilation. An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly ventilated area Filter type: A (EN 14387) Hand protection: Chemical-resistant protective gloves (EN 374).
MSDS-No.: 298562 V008.
MSDS-No.: 298562 V008.0 LOCTITE EA 3430 A BULK Page 9 of 14 Acute oral toxicity: Hazardous components CAS-No. Epoxy resin (number average molecular weight ≤ 700) 25068-38-6 Bisphenol-F epichlorhydrin resin; MW<700 9003-36-5 Bisphenol A diglycidyl ether polymer 25085-99-8 Value type LD50 Value > 2.000 mg/kg Route of application oral LD50 > 5.000 mg/kg LD50 > 2.
MSDS-No.: 298562 V008.0 LOCTITE EA 3430 A BULK Page 10 of 14 Respiratory or skin sensitization: Hazardous components CAS-No.
MSDS-No.: 298562 V008.0 LOCTITE EA 3430 A BULK Page 11 of 14 Reproductive toxicity: Hazardous substances CAS-No. Epoxy resin (number average molecular weight ≤ 700) 25068-38-6 Result / Classification NOAEL P = >= 50 mg/kg NOAEL F1 = >= 750 mg/kg NOAEL F2 = >= 750 mg/kg Species Two generation study oral: gavage Exposure time 238 d Species Method rat OECD Guideline 416 (TwoGeneration Reproduction Toxicity Study) Repeated dose toxicity Hazardous components CAS-No.
MSDS-No.: 298562 V008.0 LOCTITE EA 3430 A BULK Page 12 of 14 12.2. Persistence and degradability Persistence and Biodegradability: No data available for the product. Hazardous components CAS-No.
MSDS-No.: 298562 V008.0 LOCTITE EA 3430 A BULK Page 13 of 14 SECTION 14: Transport information 14.1. UN number ADR RID ADN IMDG IATA 14.2. UN proper shipping name ADR RID ADN IMDG IATA 14.3. III III III III III Environmental hazards ADR RID ADN IMDG IATA 14.6. 9 9 9 9 9 Packing group ADR RID ADN IMDG IATA 14.5. ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Bisphenol-F Epichlorhydrin resin,Bisphenol-A Epichlorhydrin resin) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
MSDS-No.: 298562 V008.0 LOCTITE EA 3430 A BULK Page 14 of 14 SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture VOC content < 3,00 % (2004/42/EC) 15.2. Chemical safety assessment A chemical safety assessment has not been carried out. SECTION 16: Other information The labelling of the product is indicated in Section 2.
Safety Data Sheet according to Regulation (EC) No 1907/2006 Page 1 of 16 SDS No. : 205861 V010.0 Revision: 24.08.2016 printing date: 12.06.2017 Replaces version from: 26.07.2016 LOCTITE EA 3430 B BULK SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1.
MSDS-No.: 205861 V010.0 LOCTITE EA 3430 B BULK Page 2 of 16 2.2. Label elements Label elements (CLP): Hazard pictogram: Signal word: Danger Hazard statement: H302 Harmful if swallowed. H332 Harmful if inhaled. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects. Precautionary statement: ***For consumer use only: P101 If medical advice is needed, have product container or label at hand.
MSDS-No.: 205861 V010.0 LOCTITE EA 3430 B BULK Page 3 of 16 Declaration of the ingredients according to CLP (EC) No 1272/2008: Hazardous components CAS-No. Epoxy resin (number average molecular weight ≤ 700) 25068-38-6 EC Number REACH-Reg No. 500-033-5 500-033-5 01-2119456619-26 content Classification 40- 60 % Skin Irrit. 2 H315 Skin Sens. 1 H317 Eye Irrit. 2 H319 Aquatic Chronic 2 H411 2,2'-[1,2ethanediylbis(oxy)]bis(ethanethiol) 14970-87-7 239-044-2 40- 60 % Aquatic Chronic 2 H411 Acute Tox.
MSDS-No.: 205861 V010.0 LOCTITE EA 3430 B BULK 4.2. Most important symptoms and effects, both acute and delayed Causes burns. SKIN: Rash, Urticaria. RESPIRATORY: Irritation, coughing, shortness of breath, chest tightness. INGESTION: Nausea, vomiting, diarrhea, abdominal pain. 4.3. Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures SECTION 5: Firefighting measures 5.1.
MSDS-No.: 205861 V010.0 LOCTITE EA 3430 B BULK Hygiene measures: Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working. Good industrial hygiene practices should be observed. 7.2. Conditions for safe storage, including any incompatibilities Store in sealed original container. Store in a cool, well-ventilated place. 7.3. Specific end use(s) Epoxy Hardener SECTION 8: Exposure controls/personal protection 8.1.
MSDS-No.: 205861 V010.
MSDS-No.: 205861 V010.
MSDS-No.: 205861 V010.
MSDS-No.: 205861 V010.0 LOCTITE EA 3430 B BULK Page 9 of 16 Biological Exposure Indices: None 8.2. Exposure controls: Engineering controls: Ensure good ventilation/extraction. Respiratory protection: Ensure adequate ventilation. An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly ventilated area Filter type: A (EN 14387) Hand protection: Chemical-resistant protective gloves (EN 374).
MSDS-No.: 205861 V010.
MSDS-No.: 205861 V010.0 LOCTITE EA 3430 B BULK Page 11 of 16 Acute oral toxicity: Hazardous components CAS-No. Epoxy resin (number average molecular weight ≤ 700) 25068-38-6 2,2'-[1,2ethanediylbis(oxy)]bis(eth anethiol) 14970-87-7 3,3'Oxybis(ethyleneoxy)bis(p ropylamine) 4246-51-9 N'-(3-Aminopropyl)-N,Ndimethylpropane-1,3diamine 10563-29-8 Benzyldimethylamine 103-83-3 Value type LD50 Value > 2.
MSDS-No.: 205861 V010.0 LOCTITE EA 3430 B BULK Page 12 of 16 Respiratory or skin sensitization: Hazardous components CAS-No. Epoxy resin (number average molecular weight ≤ 700) 25068-38-6 Result sensitising Test type Species Method Mouse local lymphnod e assay (LLNA) mouse OECD Guideline 429 (Skin Sensitisation: Local Lymph Node Assay) Germ cell mutagenicity: Hazardous components CAS-No.
MSDS-No.: 205861 V010.0 LOCTITE EA 3430 B BULK Hazardous components CAS-No.
MSDS-No.: 205861 V010.0 LOCTITE EA 3430 B BULK Epoxy resin (number average aerobic molecular weight ≤ 700) 25068-38-6 2,2'-[1,2ethanediylbis(oxy)]bis(ethanet hiol) 14970-87-7 3,3'aerobic Oxybis(ethyleneoxy)bis(propy lamine) 4246-51-9 N'-(3-Aminopropyl)-N,Nreadily biodegradable dimethylpropane-1,3-diamine 10563-29-8 Benzyldimethylamine Not readily aerobic 103-83-3 biodegradable.
MSDS-No.: 205861 V010.0 LOCTITE EA 3430 B BULK Page 15 of 16 Product disposal: Collection and delivery to recycling enterprise or other registered elimination institution. Dispose of in accordance with local and national regulations. Disposal of uncleaned packages: After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in an authorised legal land fill site or incinerated.
MSDS-No.: 205861 V010.0 LOCTITE EA 3430 B BULK RID ADN IMDG IATA 14.7. Page 16 of 16 Tunnelcode: (E) not applicable not applicable not applicable not applicable Transport in bulk according to Annex II of Marpol and the IBC Code not applicable SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture VOC content <3% (2010/75/EC) 15.2. Chemical safety assessment A chemical safety assessment has not been carried out.
