Safety Data Sheet according to (EC) No 1907/2006 Page 1 of 17 SDS No. : 153501 V006.2 Revision: 14.07.2015 printing date: 27.10.2015 Replaces version from: 14.07.2015 Loctite 319 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Loctite 319 Contains: Hydroxypropyl methacrylate Acrylic acid 2-Hydroxyethyl methacrylate 2,2'-Ethylenedioxydiethyl dimethacrylate Acetic acid, 2-phenylhydrazide 1.2.
MSDS-No.: 153501 V006.2 Loctite 319 Page 2 of 17 2.2. Label elements Label elements (CLP): Hazard pictogram: Signal word: Danger Hazard statement: H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H335 May cause respiratory irritation. H412 Harmful to aquatic life with long lasting effects. Precautionary statement: ***For consumer use only: P101 If medical advice is needed, have product container or label at hand.
MSDS-No.: 153501 V006.2 Loctite 319 Page 3 of 17 Declaration of the ingredients according to CLP (EC) No 1272/2008: Hazardous components CAS-No. Hydroxypropyl methacrylate 27813-02-1 EC Number REACH-Reg No. 248-666-3 01-2119490226-37 content Classification 20- 40 % Skin Sens. 1 H317 Eye Irrit. 2 H319 Acrylic acid 79-10-7 201-177-9 01-2119452449-31 1- < 5 % Flam. Liq. 3 H226 Acute Tox. 4; Oral H302 Acute Tox. 4; Dermal H312 Skin Corr. 1A H314 Acute Tox.
MSDS-No.: 153501 V006.2 Loctite 319 Page 4 of 17 H301 Eye Irrit. 2 H319 STOT SE 3 H335 Skin Irrit. 2 H315 Aquatic Acute 1 H400 M factor: 10 M factor (Chron Aquat Tox): 10 For full text of the H - statements and other abbreviations see section 16 "Other information". Substances without classification may have community workplace exposure limits available. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Move to fresh air. If symptoms persist, seek medical advice.
MSDS-No.: 153501 V006.2 Loctite 319 Page 5 of 17 6.1. Personal precautions, protective equipment and emergency procedures Avoid skin and eye contact. 6.2. Environmental precautions Do not let product enter drains. 6.3. Methods and material for containment and cleaning up For small spills wipe up with paper towel and place in container for disposal. For large spills absorb onto inert absorbent material and place in sealed container for disposal.
MSDS-No.: 153501 V006.
MSDS-No.: 153501 V006.
MSDS-No.: 153501 V006.
MSDS-No.: 153501 V006.2 Loctite 319 Page 9 of 17 2-Hydroxyethyl methacrylate 868-77-9 general population Dermal 2-Hydroxyethyl methacrylate 868-77-9 general population Inhalation 2-Hydroxyethyl methacrylate 868-77-9 general population oral systemic effects Long term exposure systemic effects Long term exposure systemic effects Long term exposure systemic effects 0,83 mg/kg bw/day 2,9 mg/m3 0,83 mg/kg bw/day Biological Exposure Indices: None 8.2.
MSDS-No.: 153501 V006.
MSDS-No.: 153501 V006.2 Loctite 319 Page 11 of 17 Acute oral toxicity: Hazardous components CAS-No. Hydroxypropyl methacrylate 27813-02-1 Acrylic acid 79-10-7 2,2'-Ethylenedioxydiethyl dimethacrylate 109-16-0 Methacrylic acid 79-41-4 Cumene hydroperoxide 80-15-9 Value type LD50 Value > 2.000 mg/kg Route of application oral LD50 1.500 mg/kg LD50 Exposure time Species Method rat OECD Guideline 401 (Acute Oral Toxicity) oral rat BASF Test 10.837 mg/kg oral rat LD50 1.
MSDS-No.: 153501 V006.2 Loctite 319 Page 12 of 17 Respiratory or skin sensitization: Hazardous components CAS-No. Acrylic acid 79-10-7 Methacrylic acid 79-41-4 Result not sensitising not sensitising Test type Species Skin painting test Buehler test guinea pig guinea pig Method Buehler test Germ cell mutagenicity: Hazardous components CAS-No.
MSDS-No.: 153501 V006.2 Loctite 319 Page 13 of 17 Hazardous components CAS-No.
MSDS-No.: 153501 V006.2 Loctite 319 Benzoquinone p106-51-4 EC50 Page 14 of 17 6 mg/l Algae Scenedesmus sp. Test) OECD Guideline 201 (Alga, Growth Inhibition Test) 12.2. Persistence and degradability Persistence and Biodegradability: The product is not biodegradable. Hazardous components CAS-No.
MSDS-No.: 153501 V006.2 Loctite 319 Hazardous components CAS-No. Hydroxypropyl methacrylate 27813-02-1 Acrylic acid 79-10-7 2,2'-Ethylenedioxydiethyl dimethacrylate 109-16-0 Methacrylic acid 79-41-4 2-Hydroxyethyl methacrylate 868-77-9 Page 15 of 17 PBT/vPvB Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vPvB) criteria. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vPvB) criteria.
MSDS-No.: 153501 V006.2 VOC content (2010/75/EC) Loctite 319 Page 16 of 17 <3% 15.2. Chemical safety assessment A chemical safety assessment has not been carried out. SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: H226 Flammable liquid and vapor. H242 Heating may cause a fire. H301 Toxic if swallowed. H302 Harmful if swallowed. H311 Toxic in contact with skin.
MSDS-No.: 153501 V006.2 Loctite 319 Page 17 of 17 Contains: Hydroxypropyl methacrylate, Acrylic acid, 2,2'-Ethylenedioxydiethyl dimethacrylate, Methacrylic acid Relevant changes in this safety data sheet are indicated by vertical lines at the left margin in the body of this document. Corresponding text is displayed in a different color on shadowed fields.
Safety Data Sheet according to (EC) No 1907/2006 Page 1 of 11 SDS No. : 153557 V003.1 Revision: 03.06.2015 printing date: 22.10.2015 Replaces version from: 27.06.2014 Loctite 7649 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Loctite 7649 Contains: Acetone 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: activator 1.3.
MSDS-No.: 153557 V003.1 Loctite 7649 Page 2 of 11 Signal word: Danger Hazard statement: H225 Highly flammable liquid and vapor. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. Supplemental information EUH066 Repeated exposure may cause skin dryness or cracking. Precautionary statement: Prevention P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 Avoid breathing vapours.
MSDS-No.: 153557 V003.1 Loctite 7649 4.2. Most important symptoms and effects, both acute and delayed EYE: Irritation, conjunctivitis. Prolonged or repeated contact may cause skin irritation. Vapors may cause drowsiness and dizziness. 4.3. Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures SECTION 5: Firefighting measures 5.1.
MSDS-No.: 153557 V003.1 Loctite 7649 Page 4 of 11 7.2. Conditions for safe storage, including any incompatibilities Store in a cool, well-ventilated place. Keep away from heat and direct sunlight. 7.3. Specific end use(s) activator SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational Exposure Limits Valid for Great Britain Ingredient [Regulated substance] ppm mg/m3 Value type Acetone 67-64-1 [ACETONE] Acetone 67-64-1 [ACETONE] Acetone 67-64-1 [ACETONE] 500 1.
MSDS-No.: 153557 V003.
MSDS-No.: 153557 V003.1 Loctite 7649 Page 6 of 11 SECTION 9: Physical and chemical properties 9.1.
MSDS-No.: 153557 V003.1 Loctite 7649 Page 7 of 11 SECTION 11: Toxicological information 11.1. Information on toxicological effects General toxicological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following.
MSDS-No.: 153557 V003.1 Loctite 7649 Page 8 of 11 Germ cell mutagenicity: Hazardous components CAS-No. Result Acetone 67-64-1 negative 2-Ethylhexanoic acid 149-57-5 negative Type of study / Route of administration bacterial reverse mutation assay (e.g Ames test) bacterial reverse mutation assay (e.
MSDS-No.: 153557 V003.1 Loctite 7649 Page 9 of 11 Acetone 67-64-1 readily biodegradable aerobic 81 - 92 % 2-Ethylhexanoic acid 149-57-5 readily biodegradable aerobic 99 % EU Method C.4-E (Determination of the "Ready" BiodegradabilityClosed Bottle Test) OECD Guideline 301 E (Ready biodegradability: Modified OECD Screening Test) 12.3. Bioaccumulative potential / 12.4. Mobility in soil Mobility: The product evaporates readily. Bioaccumulative potential: No data available.
MSDS-No.: 153557 V003.1 Loctite 7649 SECTION 14: Transport information 14.1. UN number ADR RID ADN IMDG IATA 14.2. UN proper shipping name ADR RID ADN IMDG IATA 14.3. not applicable not applicable not applicable not applicable not applicable Special precautions for user ADR RID ADN IMDG IATA 14.7. II II II II II Environmental hazards ADR RID ADN IMDG IATA 14.6. 3 3 3 3 3 Packaging group ADR RID ADN IMDG IATA 14.5.
MSDS-No.: 153557 V003.1 Loctite 7649 Page 11 of 11 SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: H225 Highly flammable liquid and vapor. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. H361d Suspected of damaging the unborn child. H361f Suspected of damaging fertility.
