Safety Data Sheet according to Regulation (EC) No 1907/2006 Page 1 of 14 SDS No. : 313072 V006.4 Revision: 15.05.2019 printing date: 22.07.2019 Replaces version from: 30.05.2017 LOCTITE 4850 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier LOCTITE 4850 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Adhesive 1.3.
SDS No.: 313072 V006.4 LOCTITE 4850 Page 2 of 14 Hazard pictogram: Ethyl 2-cyanoacrylate Contains Triethyl O-acetylcitrate Signal word: Warning Hazard statement: H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H335 May cause respiratory irritation. Supplemental information EUH202 Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children. Precautionary statement: Prevention P261 Avoid breathing vapors.
SDS No.: 313072 V006.4 LOCTITE 4850 Page 3 of 14 Declaration of the ingredients according to CLP (EC) No 1272/2008: Hazardous components CAS-No. Ethyl 2-cyanoacrylate 7085-85-0 EC Number REACH-Reg No. 230-391-5 01-2119527766-29 content Classification 25- 50 % Eye Irrit. 2 H319 STOT SE 3 H335 Skin Irrit. 2 H315 Skin Sens. 1 H317 Aquatic Acute 1 H400 Aquatic Chronic 1 H410 Carc. 2 H351 Muta. 2 H341 Acute Tox. 4; Oral H302 Eye Dam. 1 H318 Skin Sens.
SDS No.: 313072 V006.4 LOCTITE 4850 Page 4 of 14 4.3. Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media: Foam, extinguishing powder, carbon dioxide. Fine water spray Extinguishing media which must not be used for safety reasons: None known 5.2.
SDS No.: 313072 V006.4 LOCTITE 4850 Page 5 of 14 SECTION 8: Exposure controls/personal protection 8.1.
SDS No.: 313072 V006.
SDS No.: 313072 V006.4 LOCTITE 4850 Page 7 of 14 Eye protection: Safety glasses with sideshields or chemical safety goggles should be worn if there is a risk of splashing. Protective eye equipment should conform to EN166. Skin protection: Wear suitable protective clothing. Protective clothing should conform to EN 14605 for liquid splashes or to EN 13982 for dusts. Advices to personal protection equipment: The information provided on personal protective equipment is for guidance purposes only.
SDS No.: 313072 V006.4 LOCTITE 4850 Page 8 of 14 10.4. Conditions to avoid Stable under normal conditions of storage and use. 10.5. Incompatible materials See section reactivity. 10.6. Hazardous decomposition products None if used for intended purpose. SECTION 11: Toxicological information General toxicological information: Cyanoacrylates are considered to have relatively low toxicity. Acute oral LD50 is >5000mg/kg (rat). It is almost impossible to swallow as it rapidly polymerises in the mouth.
SDS No.: 313072 V006.4 LOCTITE 4850 Page 9 of 14 Respiratory or skin sensitization: May cause an allergic skin reaction. Hazardous substances CAS-No.
SDS No.: 313072 V006.4 LOCTITE 4850 Page 10 of 14 Reproductive toxicity: The mixture is classified based on threshold limits referring to the classified substances present in the mixture. Hazardous substances CAS-No. Hydroquinone 123-31-9 Result / Value Test type NOAEL P 15 mg/kg Two generation study NOAEL F1 150 mg/kg Route of application oral: gavage Species Method rat EPA OTS 798.4700 (Reproduction and Fertility Effects) NOAEL F2 150 mg/kg STOT-single exposure: No data available.
SDS No.: 313072 V006.4 LOCTITE 4850 Page 11 of 14 SECTION 12: Ecological information General ecological information: Biological and Chemical Oxygen Demands (BOD and COD) are insignificant. Do not empty into drains / surface water / ground water. 12.1. Toxicity Toxicity (Fish): The mixture is classified based on calculation method referring to the classified substances present in the mixture. Hazardous substances CAS-No.
SDS No.: 313072 V006.4 LOCTITE 4850 Page 12 of 14 Hazardous substances CAS-No. Ethyl 2-cyanoacrylate 7085-85-0 Result Test type Degradability not readily biodegradable. aerobic 57 % Exposure time 28 d Hydroquinone 123-31-9 readily biodegradable aerobic 75 - 81 % 30 d Method OECD Guideline 301 D (Ready Biodegradability: Closed Bottle Test) EU Method C.4-E (Determination of the "Ready" BiodegradabilityClosed Bottle Test) 12.3. Bioaccumulative potential No data available for the product.
SDS No.: 313072 V006.4 LOCTITE 4850 Page 13 of 14 SECTION 14: Transport information 14.1. UN number ADR RID ADN IMDG IATA 14.2. UN proper shipping name ADR RID ADN IMDG IATA 14.3. not applicable not applicable not applicable not applicable not applicable Special precautions for user ADR RID ADN IMDG IATA 14.7. Not dangerous goods Not dangerous goods Not dangerous goods Not dangerous goods III Environmental hazards ADR RID ADN IMDG IATA 14.6.
SDS No.: 313072 V006.4 LOCTITE 4850 Page 14 of 14 SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: H302 Harmful if swallowed. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H341 Suspected of causing genetic defects.
