Certifications 2

ManualsBrandsLOCTITE® ManualsAdhesivesLOCTITE® 9466 A&B Two-component adhesive 451199 50 ml

Safety Data Sheet according to Regulation (EC) No 1907/2006

Page 1 of 16

LOCTITE EA 9466 DC50ML DE

SDS No. : 178390

V001.0

Revision: 21.10.2019

printing date: 23.07.2021

Replaces version from: -

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

LOCTITE EA 9466 DC50ML DE

1.2. Relevant identified uses of the substance or mixture and uses advised against

Intended use:

Epoxy adhesive

1.3. Details of the supplier of the safety data sheet

Henkel AG & Co. KGaA

Henkelstr. 67

40589

Düsseldorf

Germany

Phone:

+49 211 797 0

Fax-no.:

+49 211 798 2009

ua-productsafety.de@henkel.com

1.4. Emergency telephone number

The Henkel information service also provides an around-the-clock telephone service on phone no.+49-(0)211-797-3350 for

exceptional cases.

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (CLP):

Skin irritation

Category 2

H315 Causes skin irritation.

Serious eye irritation

Category 2

H319 Causes serious eye irritation.

Skin sensitizer

Category 1

H317 May cause an allergic skin reaction.

Chronic hazards to the aquatic environment

Category 2

H411 Toxic to aquatic life with long lasting effects.

2.2. Label elements

Label elements (CLP):

Hazard pictogram:

Contains

reaction product: bisphenol-A-(epichlorhydrin); epoxy resin (number average molecular

weight≤700)

Summary of content (32 pages)

PAGE 1
Safety Data Sheet according to Regulation (EC) No 1907/2006 Page 1 of 16 SDS No. : 178390 V001.0 LOCTITE EA 9466 DC50ML DE Revision: 21.10.2019 printing date: 23.07.2021 Replaces version from: - SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier LOCTITE EA 9466 DC50M L DE 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Epoxy adhesive 1.3. Details of the supplier of the safety data sheet Henkel AG & Co.
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SDS No.: 178390 V001.0 LOCTITE EA 9466 DC50ML DE Page 2 of 16 Bisphenol-F epichlorhydrin resin; M W<700 S ignal word: Warning Hazard statement: H315 Causes skin irritation. H317 M ay cause an allergic skin reaction. H319 Causes serious eye irritation. H411 Toxic to aquatic life with long lasting effects. Precautionary statement: "***" ***For consumer use only: P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children.
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SDS No.: 178390 V001.0 LOCTITE EA 9466 DC50ML DE Eye contact: Rinse immediately with plenty of running water (for 10 minutes), seek medical attention from a specialist. Ingestion: Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor. 4.2. Most important symptoms and effects, both acute and delayed SKIN: Redness, inflammation. SKIN: Rash, Urticaria. EYE: Irritation, conjunctivitis. 4.3.
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SDS No.: 178390 V001.0 LOCTITE EA 9466 DC50ML DE Hygiene measures: Do not eat, drink or smoke while working. Good industrial hygiene practices should be observed. Wash hands before work breaks and after finishing work. 7.2. Conditions for safe storage, including any incompatibilities Store in sealed original container. Store in a cool, well-ventilated place. Refer to Technical Data Sheet 7.3. S pecific end use(s) Epoxy adhesive SECTION 8: Exposure controls/personal protection 8.1.
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SDS No.: 178390 V001.
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SDS No.: 178390 V001.
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SDS No.: 178390 V001.0 LOCTITE EA 9466 DC50ML DE Page 7 of 16 Respiratory protection: Ensure adequate ventilation. An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly ventilated area Filter type: A (EN 14387) Hand protection: Chemical-resistant protective gloves (EN 374).
PAGE 8
SDS No.: 178390 V001.0 LOCTITE EA 9466 DC50ML DE speed of rotation: 20 min-1; Spindle No: 7) Viscosity (kinematic) Explosive properties Oxidising properties Page 8 of 16 No data available / Not applicable No data available / Not applicable No data available / Not applicable 9.2. Other information No data available / Not applicable SECTION 10: Stability and reactivity 10.1. Reactivity Reaction with strong bases 10.2. Chemical stability Stable under recommended storage conditions. 10.3.
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SDS No.: 178390 V001.0 LOCTITE EA 9466 DC50ML DE Page 9 of 16 Acute inhalative toxicity: No data available. S kin corrosion/irritation: The mixture is classified based on calculation method referring to the classified substances present in the mixture. Haz ardous substances CAS-No.
PAGE 10
SDS No.: 178390 V001.0 LOCTITE EA 9466 DC50ML DE Page 10 of 16 Germ cell mutagenicity: The mixture is classified based on threshold limits referring to the classified substances present in the mixture. Haz ardous substances CAS-No.
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SDS No.: 178390 V001.0 LOCTITE EA 9466 DC50ML DE Page 11 of 16 S TOT-single exposure: No data available. S TOT-repeated exposure:: The mixture is classified based on threshold limits referring to the classified substances present in the mixture. Haz ardous substances CAS-No. reaction product: bisphenol-A(epichlorhydrin); epoxy resin (number average molecular weight ≤700) 25068-38-6 Bisphenol-F epichlorhydrin resin; MW<700 9003-36-5 Aspiration hazard: No data available.
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SDS No.: 178390 V001.0 LOCTITE EA 9466 DC50ML DE Page 12 of 16 SECTION 12: Ecological information General ecological information: Do not empty into drains / surface water / ground water. 12.1. Toxicity Toxicity (Fish): The mixture is classified based on calculation method referring to the classified substances present in the mixture. Haz ardous substances CAS-No.
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SDS No.: 178390 V001.0 LOCTITE EA 9466 DC50ML DE Page 13 of 16 The mixture is classified based on calculation method referring to the classified substances present in the mixture. Haz ardous substances CAS-No.
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SDS No.: 178390 V001.0 LOCTITE EA 9466 DC50ML DE Haz ardous substances LogPow CAS-No. reaction product: bisphenol-A- 3,242 (epichlorhydrin); epoxy resin (number average molecular weight≤700) 25068-38-6 Bisphenol-F epichlorhydrin 2,7 - 3,6 resin; MW<700 9003-36-5 Temperature Method 25 °C EU Method A.8 (Partition Coefficient) Page 14 of 16 OECD Guideline 117 (Partition Coefficient (n-octanol / water), HPLC Method) 12.5. Results of PBT and vPvB assessment Haz ardous substances CAS-No.
PAGE 15
SDS No.: 178390 V001.0 LOCTITE EA 9466 DC50ML DE Page 15 of 16 SECTION 14: Transport information 14.1. UN number ADR RID ADN IM DG IATA 14.2. UN proper shipping name ADR RID ADN IM DG IATA 14.3. (Epoxy (Epoxy (Epoxy 9 9 9 9 9 III III III III III Environmental hazards ADR RID ADN IM DG IATA 14.6. (Epoxy Packing group ADR RID ADN IM DG IATA 14.5. ENVIRONM ENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. resin) ENVIRONM ENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
PAGE 16
SDS No.: 178390 V001.0 LOCTITE EA 9466 DC50ML DE Page 16 of 16 SECTION 15: Regulatory information 15.1. S afety, health and environmental regulations/legislation specific for the substance or mixture VOC content <3% (2010/75/EC) 15.2. Chemical safety assessment A chemical safety assessment has not been carried out. National regulations/information (Germany): WGK: WGK = 3, highly water endangering mixture. Classification according to the mixture rules in German AwSV regulation annex 1, number 5.
PAGE 17
Safety Data Sheet according to Regulation (EC) No 1907/2006 Page 1 of 16 SDS No. : 152810 V001.0 LOCTITE EA 9466 DC50ML DE Revision: 21.10.2019 printing date: 23.07.2021 Replaces version from: 11.04.2017 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier LOCTITE EA 9466 DC50M L DE 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Epoxy Hardener 1.3.
PAGE 18
SDS No.: 152810 V001.0 LOCTITE EA 9466 DC50ML DE Page 2 of 16 reaction product: bisphenol-A-(epichlorhydrin); epoxy resin (number average molecular weight≤700) S ignal word: Danger Hazard statement: H314 Causes severe skin burns and eye damage. H317 M ay cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects. Precautionary statement: "***" ***For consumer use only: P101 If medical advice is needed, have product container or label at hand.
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SDS No.: 152810 V001.0 LOCTITE EA 9466 DC50ML DE Skin contact: Rinse with running water and soap. Obtain medical attention if irritation persists. Eye contact: Rinse immediately with plenty of running water (for 10 minutes), seek medical attention from a specialist. Ingestion: Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor. 4.2. Most important symptoms and effects, both acute and delayed Causes burns. SKIN: Rash, Urticaria. 4.3.
PAGE 20
SDS No.: 152810 V001.0 LOCTITE EA 9466 DC50ML DE 7.1. Precautions for safe handling Avoid skin and eye contact. Use only in well-ventilated areas. Gloves and safety glasses should be worn Do not inhale vapors and fumes. See advice in section 8 Hygiene measures: Good industrial hygiene practices should be observed. Do not eat, drink or smoke while working. Wash hands before work breaks and after finishing work. 7.2.
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SDS No.: 152810 V001.
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SDS No.: 152810 V001.
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SDS No.: 152810 V001.0 LOCTITE EA 9466 DC50ML DE Page 7 of 16 Biological Exposure Indices: None 8.2. Exposure controls: Engineering controls: Ensure good ventilation/extraction. Respiratory protection: Ensure adequate ventilation. An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly ventilated area Filter type: A (EN 14387) Hand protection: Chemical-resistant protective gloves (EN 374).
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SDS No.: 152810 V001.
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SDS No.: 152810 V001.0 LOCTITE EA 9466 DC50ML DE Page 9 of 16 Acute dermal toxicity: The mixture is classified based on calculation method referring to the classified substances present in the mixture. Haz ardous substances CAS-No.
PAGE 26
SDS No.: 152810 V001.0 LOCTITE EA 9466 DC50ML DE Page 10 of 16 Germ cell mutagenicity: The mixture is classified based on threshold limits referring to the classified substances present in the mixture. Haz ardous substances CAS-No.
PAGE 27
SDS No.: 152810 V001.0 LOCTITE EA 9466 DC50ML DE Page 11 of 16 S TOT-single exposure: No data available. S TOT-repeated exposure:: The mixture is classified based on threshold limits referring to the classified substances present in the mixture. Haz ardous substances CAS-No.
PAGE 28
SDS No.: 152810 V001.0 LOCTITE EA 9466 DC50ML DE Page 12 of 16 SECTION 12: Ecological information General ecological information: Do not empty into drains / surface water / ground water. 12.1. Toxicity Toxicity (Fish): The mixture is classified based on calculation method referring to the classified substances present in the mixture. Haz ardous substances CAS-No.
PAGE 29
SDS No.: 152810 V001.0 LOCTITE EA 9466 DC50ML DE Page 13 of 16 The mixture is classified based on calculation method referring to the classified substances present in the mixture. Haz ardous substances CAS-No.
PAGE 30
SDS No.: 152810 V001.0 LOCTITE EA 9466 DC50ML DE Haz ardous substances LogPow CAS-No. 3,3'-1,25 Oxybis(ethyleneoxy)bis(propy lamine) 4246-51-9 reaction product: bisphenol-A- 3,242 (epichlorhydrin); epoxy resin (number average molecular weight≤700) 25068-38-6 Page 14 of 16 Te mperature Method 25 °C OECD Guideline 107 (Partition Coefficient (n-octanol / water), Shake Flask Method) 25 °C EU Method A.8 (Partition Coefficient) 12.5. Results of PBT and vPvB assessment Haz ardous substances CAS-No.
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SDS No.: 152810 V001.0 LOCTITE EA 9466 DC50ML DE Page 15 of 16 SECTION 14: Transport information 14.1. UN number ADR RID ADN IM DG IATA 14.2. UN proper shipping name ADR RID ADN IM DG IATA 14.3. Environmentally Hazardous Environmentally Hazardous Environmentally Hazardous M arine pollutant not applicable S pecial precautions for user ADR RID ADN IM DG IATA 14.7. II II II II II Environmental hazards ADR RID ADN IM DG IATA 14.6. 8 8 8 8 8 Packing group ADR RID ADN IM DG IATA 14.5.
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SDS No.: 152810 V001.0 LOCTITE EA 9466 DC50ML DE VOC content (2010/75/EC) Page 16 of 16 < 3,00 % Combined A/B 15.2. Chemical safety assessment A chemical safety assessment has not been carried out. National regulations/information (Germany): WGK: WGK = 2, significantly water endangering mixture. Classification according to the mixture rules in German AwSV regulation annex 1, number 5.2 from 18. April 2017.