SECTION 1. CHEMICIAL PRODUCT AND COMPANY NAME Safety Data Sheet Lithium-Ion Rechargeable Battery Pack BL1850B Complies with the OSHA Hazard Communication Standard : 29 CFR 1910 1200 Makita U.S.A., Inc.
CONTINUED: SECTION 3. COMPOSITION, INFORMATION OR INGREDIENTS CAS No. EC No. REACH Registration No. %[weight] Name Common Name (Synonyms) 12190-79-3 235-362-0 - 1~5 Cobalt Lithium Dioxide Not available 554-12-1 209-060-4 - 1~5 Methyl Propanoate Not available Flam. Liq. 2, H225 Acute Tox.
CONTINUED: SECTION 4. FIRST AID MEASURE Following inhalation : - In case of inhalation of organic electrolyte mist, remove from exposure to fresh air. - If necessary give oxygen. Get medical attention. Following ingestion : - In case of ingestion of electrolyte don’t induce vomiting. - If patient is conscious and alert give 2~4 cupful’s of milk or water. -Never give anything by mouth to an unconscious person. -Get medical attention immediately.
CONTINUED: SECTION 6. ACCIDENTAL RELEASE MEASURES For emergency responders - Eliminate all ignition sources. - Please note that materials and conditions to avoid. - Move battery to well ventilated area to prevent gas accumulation. 6.2 Environmental precautions : - Avoid release to the environment. - Prevent entry into waterways, sewers, basements or confined areas. 6.
CONTINUED: SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION Lithium Nickel Oxide Graphite Iron Copper Cobalt Lithium Dioxide Cobalt, Co Methyl Propanoate TWA = 1.5 mg/m³ (inhalable particulate matter) (Nickel CAS. No7440-02-0) Not available TWA = 1 mg/m³ (metal and insoluble compounds (as Ni)) TWA = 1 mg/m³ (soluble compounds (as Ni)) (Nickel CAS.no 7440-02-0) TWA = 2mg/m3 Not available Not applicable Not applicable TWA = 0.2 mg/m³ (fume) Not available Not applicable TWA = 0.
CONTINUED: SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION 1-Methyl-2pyrrolidinone Aluminum Lithium Oxide (LiAlO) Not applicable Not applicable TWA = 1 mg/m³ (respirable particulate matter)(Aluminum CAS.no 7429-90-5) Not available Not applicable Not applicable TWA = 15 mg/m³ (Aluminum Metal (as Al) Total dust) TWA = 5 mg/m³ (Aluminum Metal (as Al) Respirable fraction) (Aluminum CAS. No 7429-90-5) TWA = 1 mg/m³ (Aluminum Metal (as Al), Respirable fraction) (Aluminum CAS.
CONTINUED: SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION -Wear NIOSH or European Standard EN 149 approved full or half face piece (with goggles) respiratory protective equipment when necessary.
CONTINUED: SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Oxidizing properties : Molecular weight : 9.2 Other information Not available Not available Not available SECTION 10. STABILITY AND REACTIVITY 10.1 Reactivity - Stable at ambient temperature. 10.2 Chemical stability - There is no hazard when the measures for handling and storage are followed. - Stable under normal temperatures and pressures. 10.3 Possibility of hazardous reactions - Will not occur under normal conditions.
CONTINUED: SECTION 11.
CONTINUED: SECTION 11. TOXICOLOGICAL INFORMATION - 1-Methyl-2-pyrrolidinone : In the skin irritation test using rabbits, the test material was slightly irritating. (OECD Guideline 404, GLP) - Chromium : In test on skin irritation with rabbits, skin irritations were not observed.(Read across; chromium(III) oxide)(OECD TG 404, GLP) - Lithium carbonate;Lithane : In the skin irritation test using rabbits, the test material was not irritating.
CONTINUED: SECTION 11.
CONTINUED: SECTION 11. TOXICOLOGICAL INFORMATION Reproductive toxicity : - Graphite : - Copper : In reproductive toxicity with rats, there were no effects considered (up to 1500 ppm). (OECD TG 416, GLP) - Aluminum : No reproduction, breeding and early post-natal developmental toxicity was observed in rats at 1000 mg/kg bw for males and females.
CONTINUED: SECTION 11. TOXICOLOGICAL INFORMATION - Chromium : In the repeated Dose 90-Day Oral toxicity test using rat, there were no effects on clinical signs, mortality. - Ethylbenzene : In repeated oral toxicity study with rats for 28 days, increased liver weight and hepatocellular hypertrophy at higher dose levels were observed.
CONTINUED: SECTION 12. ECOLOGICAL INFORMATION - 1-Methyl-2-pyrrolidinone : 72hr-EC50 = 600.5 mg/L - Lithium carbonate;Lithane : 72hr-EC50 ＞ 400 mg/L - Ethylbenzene : 96hr-EC50 = 3.6 mg/L (U.S. EPA. 1985. Toxic substance Control Act Test guidelines) 12.2 Persistence and degradability Persistence - Graphite : Low persistency (log Kow is less than 4 estimated.) (Log Kow = 0.78) - : Low persistency (log Kow is less than 4 estimated.) (Log Kow = 0.
CONTINUED: SECTION 13. DISPOSAL CONSIDERATIONS Sewage disposal-relevant information: Not available Other disposal recommendations: Not available SECTION 14. TRANSPORT INFORMATION • When a number of batteries are transported by ship, vehicle and railroad avoid high temperature and dew condensation. • Avoid transportation which may cause damage of package.
CONTINUED: SECTION 14. TRANSPORT INFORMATION Where classified as lithium batteries packed with equipment (UN3481), IATA Dangerous Goods Regulations packing instruction 966 is applied. Where classified as lithium batteries installed in equipment (UN3481), IATA Dangerous Goods Regulations packing instruction 967 is applied. SECTION 15. REGULATORY INFORMATION 15.
CONTINUED: SECTION 16. OTHER INFORMATION 16.2 Abbreviations and acronyms ACGIH = American Conference of Government Industrial Hygienists CLP = Classification Labelling Packaging Regulation ; Regulation (EC) No 1272/2008 CAS No.
