Manual

M39, Heavy Duty Vinyl Cleaner (24-161B): M3916
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Hydrocarbons. Not specified.
Carbon monoxide. Not specified.
Carbon dioxide. Not specified.
Irritant vapours or gases. Not specified.
SECTION 11: Toxicological information
The information below may not agree with the EU material classification in Section 2 and/or the ingredient
classifications in Section 3 if specific ingredient classifications are mandated by a competent authority. In addition,
statements and data presented in Section 11 are based on UN GHS calculation rules and classifications derived from
3M assessments.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation
Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
Skin contact
Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain.
Eye contact
Severe eye irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
Overall product Ingestion No data available; calculated ATE >5,000 mg/kg
Trisodium Phosphate Dermal Rat LD50 > 2,000 mg/kg
Trisodium Phosphate Inhalation-
Dust/Mist
(4 hours)
Rat LC50 > 0.83 mg/l
Trisodium Phosphate Ingestion Rat LD50 > 2,000 mg/kg
Glycerin Dermal Rabbit LD50 estimated to be > 5,000 mg/kg
Glycerin Ingestion Rat LD50 > 5,000 mg/kg
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-
2H-isothiazol-3-one
Dermal Rabbit LD50 87 mg/kg
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-
2H-isothiazol-3-one
Inhalation-
Dust/Mist
(4 hours)
Rat LC50 0.33 mg/l
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-
2H-isothiazol-3-one
Ingestion Rat LD50 40 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Trisodium Phosphate Rabbit Irritant