SDS

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SAFETY DATA SHEET

Issuing Date No data available

Revision Date 20-Jan-2015

Revision Number 1

____________________________________________________________________________________________

The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS,

and all information in this SDS was provided by the supplier or was reproduced from publically available regulatory data sources. UL makes no

representations or warranties regarding the completeness or accuracy of the information in this SDS and disclaims all liability in connection with the use of

____________________________________________________________________________________________

Page 1 / 15

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE

COMPANY/UNDERTAKING

Product identifier

Product Name TIANQIU Carbon Zinc battery R03/AAA (No lead added)

Other means of identification

Synonyms

None

Recommended use of the chemical and restrictions on use

Recommended Use

Carbon Zinc Battery

Uses advised against

No information available

Details of the supplier of the safety data sheet

Supplier Name

GUANGZHOU TIANQIU ENTERPRISE CO., LTD.

Supplier Address

9/F TianQiu Business Building No.16-30, He Yi Rd., San Yuan Li Ave., GuangZhou China

GUANGZHOU

GUANDONG

510410

Supplier Phone Number

Phone:8620-36322277

Fax:8620-3623339

Contact Phone13825131170

Supplier Email

qd@gztianqiu.com

Emergency telephone number

2. HAZARDS IDENTIFICATION

Classification

This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) This product

is an article which is a sealed battery and as such does not require an MSDS per the OSHA hazard communication standard

unless ruptured. The hazards indicated are for a ruptured battery.

cute toxicity - Oral Category 4

cute toxicity - Inhalation (Gases) Category 4

cute toxicity - Inhalation (Dusts/Mists) Category 4

Summary of content (44 pages)

PAGE 1
SAFETY DATA SHEET Issuing Date No data available Revision Date 20-Jan-2015 Revision Number 1 _____________________________________________________________________________________________ The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS, and all information in this SDS was provided by the supplier or was reproduced from publically available regulatory data sources.
PAGE 2
1199792 added) TIANQIU Carbon Zinc battery R03/AAA Revision Date (No lead 20-Jan-2015 _____________________________________________________________________________________________ Skin corrosion/irritation Serious eye damage/eye irritation Carcinogenicity Specific target organ toxicity (repeated exposure) Category 1 Sub-category B Category 1 Category 2 Category 2 GHS Label elements, including precautionary statements Emergency Overview Signal word Danger Hazard Statements Harmful if swallowed Har
PAGE 3
1199792 added) TIANQIU Carbon Zinc battery R03/AAA (No lead Revision Date 20-Jan-2015 _____________________________________________________________________________________________ Ingestion IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth Do NOT induce vomiting Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicabl
PAGE 4
1199792 added) TIANQIU Carbon Zinc battery R03/AAA (No lead Revision Date 20-Jan-2015 _____________________________________________________________________________________________ Inhalation Remove to fresh air. If breathing has stopped, give artificial respiration. Get medical attention immediately.
PAGE 5
1199792 added) TIANQIU Carbon Zinc battery R03/AAA (No lead Revision Date 20-Jan-2015 _____________________________________________________________________________________________ 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media CAUTION: Use of water spray when fighting fire may be inefficient.
PAGE 6
1199792 added) TIANQIU Carbon Zinc battery R03/AAA Revision Date (No lead 20-Jan-2015 _____________________________________________________________________________________________ 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Attention! Corrosive material. Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Use personal protective equipment as required. Evacuate personnel to safe areas.
PAGE 7
1199792 added) TIANQIU Carbon Zinc battery R03/AAA Revision Date (No lead 20-Jan-2015 _____________________________________________________________________________________________ 3 Zinc 7440-66-6 STEL: 10 mg/m respirable fraction 3 TWA: 2 mg/m respirable fraction 3 TWA: 0.02 mg/m Mn 3 TWA: 0.
PAGE 8
1199792 added) TIANQIU Carbon Zinc battery R03/AAA Revision Date (No lead 20-Jan-2015 _____________________________________________________________________________________________ Physical and Chemical Properties Physical State Appearance Color Solid No data available No information available Property Values pH No data available Melting / freezing point No data available Boiling point / boiling range No data available Flash Point No data available Evaporation Rate No data available Flammability (sol
PAGE 9
1199792 added) TIANQIU Carbon Zinc battery R03/AAA (No lead Revision Date 20-Jan-2015 _____________________________________________________________________________________________ 10. STABILITY AND REACTIVITY Reactivity No data available. Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization Hazardous polymerization does not occur. Conditions to avoid Exposure to air or moisture over prolonged periods.
PAGE 10
1199792 added) TIANQIU Carbon Zinc battery R03/AAA Revision Date (No lead 20-Jan-2015 _____________________________________________________________________________________________ Component Information Chemical Name Manganese dioxide 1313-13-9 Graphite 7782-42-5 Zinc chloride 7646-85-7 Iron 7439-89-6 Carbon black 1333-86-4 Oral LD50 = 9000 mg/kg ( Rat ) > 10000 mg/kg Dermal LD50 - Inhalation LC50 - - - ( Rat ) = 350 mg/kg ( Rat ) - - = 984 mg/kg ( Rat ) - - > 15400 mg/kg ( Rat ) > 3
PAGE 11
99792 added) TIANQIU Carbon Zinc battery R03/AAA (No lead Revision Date 20-Jan-2015 _____________________________________________________________________________________________ Target Organ Effects Aspiration Hazard Respiratory system. Eyes. Skin. Gastrointestinal tract (GI). Blood. Central Nervous System (CNS). Central Vascular System (CVS). Kidney. Lymphatic System. Cardiovascular system. Liver. Lungs. Pancreas. No information available.
PAGE 12
1199792 added) TIANQIU Carbon Zinc battery R03/AAA Revision Date (No lead 20-Jan-2015 _____________________________________________________________________________________________ 12. ECOLOGICAL INFORMATION This product contains a chemical which, although not listed, meets the IMDG criteria for being a severe marine pollutant Ecotoxicity Very toxic to aquatic life with long lasting effects. Chemical Name Toxicity to Algae Zinc 7440-66-6 Toxicity to Fish Toxicity to Microorganisms 96h EC50: 0.
PAGE 13
1199792 added) TIANQIU Carbon Zinc battery R03/AAA Revision Date (No lead 20-Jan-2015 _____________________________________________________________________________________________ 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal methods This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261).
PAGE 14
1199792 added) TIANQIU Carbon Zinc battery R03/AAA Revision Date (No lead 20-Jan-2015 _____________________________________________________________________________________________ 15. REGULATORY INFORMATION International Inventories TSCA DSL Complies All components are listed either on the DSL or NDSL.
PAGE 15
1199792 added) TIANQIU Carbon Zinc battery R03/AAA Revision Date (No lead 20-Jan-2015 _____________________________________________________________________________________________ Chemical Name Zinc 7440-66-6 Manganese dioxide 1313-13-9 Graphite 7782-42-5 Zinc chloride 7646-85-7 Carbon black 1333-86-4 PVC (Chloroethylene, polymer) 9002-86-2 New Jersey X Massachusetts X Pennsylvania X Rhode Island X Illinois X X X X X X X X X X X X X X X International Regulations Mexico National oc
PAGE 16
SAFETY DATA SHEET Issuing Date 05-Sep-2017 Revision Date 04-Sep-2017 Revision Number 1 NGHS / English _____________________________________________________________________________________________ The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS, and all information in this SDS was provided by the supplier or was reproduced from publically available regulatory data sources.
PAGE 17
1416207 - R02P,R6P,R14P,R20P,6F22 Revision Date 04-Sep-2017 _____________________________________________________________________________________________ This is a battery. In case of rupture: the above hazards exist.
PAGE 18
1416207 - R02P,R6P,R14P,R20P,6F22 Revision Date 04-Sep-2017 _____________________________________________________________________________________________ 91.53 % of the mixture consists of ingredient(s) of unknown acute dermal toxicity 68.38 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (gas) 68.38 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (vapor) 68.
PAGE 19
1416207 - R02P,R6P,R14P,R20P,6F22 Revision Date 04-Sep-2017 _____________________________________________________________________________________________ Most important symptoms and effects, both acute and delayed Symptoms Burning sensation. Coughing and/ or wheezing. Difficulty in breathing. Indication of any immediate medical attention and special treatment needed Note to physicians Product is a corrosive material. Use of gastric lavage or emesis is contraindicated.
PAGE 20
1416207 - R02P,R6P,R14P,R20P,6F22 Revision Date 04-Sep-2017 _____________________________________________________________________________________________ respiratory equipment. Handle product only in closed system or provide appropriate exhaust ventilation. Do not eat, drink or smoke when using this product. Take off contaminated clothing and wash before reuse. Avoid breathing dust/fume/gas/mist/vapors/spray. Avoid generation of dust.
PAGE 21
1416207 - R02P,R6P,R14P,R20P,6F22 Revision Date 04-Sep-2017 _____________________________________________________________________________________________ 12125-02-9 PVC (Chloroethylene, polymer) 9002-86-2 Copper 7440-50-8 Zinc oxide 1314-13-2 STEL: 20 mg/m3 STEL: 20 mg/m3 TWA: 1 mg/m3 STEL: 20 mg/m3 TWA: 1 mg/m3 STEL: 20 mg/m3 TWA: 0.2 mg/m3 TWA: 1 mg/m3 TWA: 2 mg/m3 STEL: 10 mg/m3 TWA: 1 mg/m3 TWA: 0.2 mg/m3 TWA: 2 mg/m3 STEL: 10 mg/m3 TWA: 0.2 mg/m3 TWA: 1 mg/m3 TWA: 2 mg/m3 STEL: 10 mg/m3 TWA: 0.
PAGE 22
1416207 - R02P,R6P,R14P,R20P,6F22 Revision Date 04-Sep-2017 _____________________________________________________________________________________________ No data available Vapor density No data available Relative density Insoluble in water Water Solubility No data available Solubility(ies) Partition coefficient: n-octanol/waterNo data available No data available Autoignition temperature No data available Decomposition temperature No data available Kinematic viscosity No data available Dynamic viscosity Othe
PAGE 23
1416207 - R02P,R6P,R14P,R20P,6F22 Revision Date 04-Sep-2017 _____________________________________________________________________________________________ Ingestion Specific test data for the substance or mixture is not available. Causes burns. (based on components). Ingestion causes burns of the upper digestive and respiratory tracts. May cause severe burning pain in the mouth and stomach with vomiting and diarrhea of dark blood. Blood pressure may decrease.
PAGE 24
1416207 - R02P,R6P,R14P,R20P,6F22 Revision Date 04-Sep-2017 _____________________________________________________________________________________________ Reproductive toxicity No information available. STOT - single exposure No information available. STOT - repeated exposure No information available. Aspiration hazard No information available. 12.
PAGE 25
1416207 - R02P,R6P,R14P,R20P,6F22 Revision Date 04-Sep-2017 _____________________________________________________________________________________________ (Cyprinus carpio) 96h LC50: = 0.8 mg/L (Cyprinus carpio) Persistence and Degradability No information available. Bioaccumulation Chemical name Manganese dioxide Log Pow <0 Mobility No information available. Other adverse effects No information available. 13.
PAGE 26
1416207 - R02P,R6P,R14P,R20P,6F22 Revision Date 04-Sep-2017 _____________________________________________________________________________________________ IATA Proper Shipping Name Hazard Class Not regulated NON REGULATED N/A IMDG/IMO Hazard Class Marine Pollutant Not regulated N/A This product contains a chemical which is listed as a marine pollutant according to IMDG/IMO RID Not regulated ADR Not regulated ADN Not regulated 15.
PAGE 27
1416207 - R02P,R6P,R14P,R20P,6F22 Revision Date 04-Sep-2017 _____________________________________________________________________________________________ No No No No No Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden release of pressure hazard Reactive Hazard CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.
PAGE 28
1416207 - R02P,R6P,R14P,R20P,6F22 Revision Date 04-Sep-2017 _____________________________________________________________________________________________ 9002-86-2 Copper 7440-50-8 Zinc oxide 1314-13-2 X X X X X X X X X 16. OTHER INFORMATION NFPA Health hazards 1 Flammability 0 Instability 0 HMIS Health hazards 0 Flammability 0 Physical hazards 0 Prepared By Product Stewardship 23 British American Blvd.
PAGE 29
Article Information Sheet Product name: Carbon Zinc Battery Printing date: 2021.12.30 Fiche d'information Article Nom du produit: pile au carbone-zinc Date d'impression: 2021.12.30 Article Information Sheet (AIS) Article Feuillet d'information (AIS) This Article Information Sheet (AIS) provides relevant battery information to retailers, consumers, OEMs and other users requesting a GHS‐compliant SDS. Articles, such as batteries, are exempt from GHS SDS classification criteria.
PAGE 30
Article Information Sheet Product name: Carbon Zinc Battery Printing date: 2021.12.30 Fiche d'information Article Date d'impression: 2021.12.30 Nom du produit: pile au carbone-zinc 4. ARTICLE CONSTRUCTION 4. ARTICLE CONSTRUCTION IMPORTANT NOTE: The battery should not be opened or burned. Exposure to the ingredients contained within or their combustion products could be harmful. REMARQUE IMPORTANTE: La batterie ne doit pas être ouvert ou brûlé.
PAGE 31
Article Information Sheet Product name: Carbon Zinc Battery Eye contact: Self-protection of the first aider: Printing date: 2021.12.30 Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. Do not rub affected area. Remove contact lenses, if present and easy to do. Continue rinsing. Seek immediate medical attention/advice.
PAGE 32
Article Information Sheet Product name: Carbon Zinc Battery fire-fighters Printing date: 2021.12.30 batteries produce toxic and corrosive lithium hydroxide fumes. 7. HANDLING AND STORAGE Storage Handling Spills of Large Quantities Batteries (unpackaged) Store in a cool, well ventilated area. Elevated temperatures can result in shortened battery life. In locations that handle large quantities of lithium batteries, such as warehouses, lithium batteries should be isolated from unnecessary combustibles.
PAGE 33
Article Information Sheet Fiche d'information Article Printing date: 2021.12.30 Product name: Carbon Zinc Battery short-circuit. Do not incinerate. In countries, such as Canada and the EU, where there are regulations for the collection and recycling of batteries, consumers should dispose of their used batteries into the collection network at municipal depots and retailers. They should not dispose of batteries with household trash. 9.
PAGE 34
Article Information Sheet Printing date: 2021.12.30 Product name: Carbon Zinc Battery 7439-89-6 Not listed 9003-07-0 7646-85-7 68188-15-8 Listed Listed Listed Listed Not listed Listed Listed Fiche d'information Article Listed Listed Listed Not listed Listed Listed Listed Listed Listed Listed Listed Listed Listed Listed Listed Listed 11. OTHER INFORMATION TSCA: Toxic Substances Control Act, The American chemical inventory.
PAGE 35
Article Information Sheet Product name: Carbon Zinc Battery Printing date: 2021.12.30 Fiche d'information Article Nom du produit: pile au carbone-zinc Date d'impression: 2021.12.30 IECSC: Inventaire des substances chimiques existantes en Chine. Parce que toutes nos batteries sont définis comme des « articles », ils sont exemptés des exigences de la norme de communication des risques. Les informations contenues dans ce AIS est fourni tous les pleinement et véritablement les données pertinentes.
PAGE 36
SAFETY DATA SHEET Issuing Date 31-Jan-2019 Revision Date 31-Jan-2019 Revision Number NGHS 2 / English _____________________________________________________________________________________________ The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS, and all information in this SDS was provided by the supplier or was reproduced from publically available regulatory data sources.
PAGE 37
1500576 - R32 air conditioner Revision Date 31-Jan-2019 _____________________________________________________________________________________________ Appearance No information available Physical state Gas Odor No information available GHS Label elements, including precautionary statements Danger Hazard statements Extremely flammable gas Contains gas under pressure; may explode if heated Precautionary Statements - Prevention Keep away from heat, hot surfaces, sparks, open flames and other ignition so
PAGE 38
1500576 - R32 air conditioner Revision Date 31-Jan-2019 _____________________________________________________________________________________________ 4. FIRST AID MEASURES First aid measures General advice Inhalation In case of rupture. Do not get in eyes, on skin, or on clothing. Do not breathe dust/fume/gas/mist/vapors/spray. Remove to fresh air. If breathing is difficult, (trained personnel should) give oxygen. If not breathing, give artificial respiration.
PAGE 39
1500576 - R32 air conditioner Revision Date 31-Jan-2019 _____________________________________________________________________________________________ Personal precautions Stop leak if you can do it without risk. Other Information Ventilate the area. Methods and material for containment and cleaning up Methods for containment If possible, turn leaking containers so that gas escapes rather than liquid. Methods for cleaning up Do not direct water at spill or source of leak. 7.
PAGE 40
1500576 - R32 air conditioner Revision Date 31-Jan-2019 _____________________________________________________________________________________________ Physical and Chemical Properties Physical state Appearance Odor Color Odor Threshold Gas No information available No information available No information available No information available Property Values pH No data available Melting / freezing point No data available Boiling point / boiling range No data available Flash Point No data available Evaporation R
PAGE 41
1500576 - R32 air conditioner Revision Date 31-Jan-2019 _____________________________________________________________________________________________ 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Product does not present an acute toxicity hazard based on known or supplied information In case of rupture: Inhalation In high concentration the gas may cause a suffocation. Victim may not be aware of asphyxiation.
PAGE 42
1500576 - R32 air conditioner Revision Date 31-Jan-2019 _____________________________________________________________________________________________ STOT - repeated exposure No information available. Aspiration hazard No information available. 12. ECOLOGICAL INFORMATION Ecotoxicity The environmental impact of this product has not been fully investigated. Persistence and Degradability No information available. Bioaccumulation There is no data for this product. Mobility No information available.
PAGE 43
1500576 - R32 air conditioner Revision Date 31-Jan-2019 _____________________________________________________________________________________________ ADR Not regulated ADN Not regulated 15.
PAGE 44
1500576 - R32 air conditioner Revision Date 31-Jan-2019 _____________________________________________________________________________________________ This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355).