SDS

DATE: 08/29/2012 COMPANY NAME: GIANI, Inc. PRODUCT CODE: NUVO TITANIUM INFUSION Page 1
Date: 08/29/2012
MATERIAL SAFETY DATA SHEET
PREPARED BY: Environmental, Health and Safety Department
MSDS PREPARATION DATE: 08/29/2012, Version 1
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Section 1 - Chemical Product and Company Identification
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MANUFACTURER Giani,Inc.
ADDRESS 2216 North Broadway
St. Louis, MO 63102
INFORMATION 314-241-3500
EMERGENCY CHEMTREC 800-424-9300 or 703-527-3887
TRADE NAME Nuvo Titanium Infusion
PRODUCT CODE TKA 1169-21
HMIS Classification: Health 1, Flammability 0, Reactivity 0, Personal Protection Code
NFPA 0, 1, 0
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Section 2 - Composition, Information on Ingredients
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1 Non hazardous Acrylic CAS# trade secret, EINECS# , Non hazardous Acrylic
Pct By Wt: <20.0% Vapor Pressure: 17.500
ACGIH TLV-TWA NE ACGIH TLV-STEL/C NE
OSHA PEL-TWA NE OSHA PEL-STEL NE
OSHA PEL-CEILING NE LD50 (INGESTION) NE
LC50 (INHALATION) NE AUTOIGNITION TEMP. NA
SARA: NO/NO
Other Limits: IARC-NO, NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
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2 Non hazardous Urethane CAS# trade secret, EINECS# , Non hazardous Acrylic
Pct By Wt: <20.0% Vapor Pressure: 17.500
ACGIH TLV-TWA NE ACGIH TLV-STEL/C NE
OSHA PEL-TWA NE OSHA PEL-STEL NE
OSHA PEL-CEILING NE LD50 (INGESTION) NE
LC50 (INHALATION) NE AUTOIGNITION TEMP. NA
SARA: NO/NO
Other Limits: IARC-NO, NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
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3 WATER CAS# 7732-18-5, EINECS# 231-791-2, Water
Pct By Wt: 53.09 Vapor Pressure: 17.500
ACGIH TLV-TWA NE ACGIH TLV-STEL/C NE
OSHA PEL-TWA NE OSHA PEL-STEL NE
OSHA PEL-CEILING NE LD50 (INGESTION) NE
LC50 (INHALATION) NE AUTOIGNITION TEMP. NA
SARA: NO/NO
Other Limits: IARC-NO, NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
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4 GLYCOL CAS# 57-55-6 PROPYLENE GLYCOL
Pct By Wt: 1.0% LEL: 2.6
ACGIH TLV-TWA NE ACGIH TLV-STEL/C NE
OSHA PEL-TWA NE OSHA PEL-STEL NE
OSHA PEL-CEILING NE LD50 (INGESTION) >2000 mg/kg
LC50 (INHALATION) NE AUTOIGNITION TEMP. 790 F
FLASH POINT 99 °C / 210 °F SARA: NO/NO
Other Limits: IARC-NO. NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
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5 TPM GLYCOL ETHER CAS# 25498-49-1 TRIPROPYLENE GLYCOL MONOMETHYL ETHER
Pct By Wt: < 2.0%
ACGIH TLV-TWA NE ACGIH TLV-STEL/C NE
OSHA PEL-TWA NE OSHA PEL-STEL NE
OSHA PEL-CEILING NE LD50 (INGESTION) 3200 mg/kg (rat)
LC50 (INHALATION) NE AUTOIGNITION TEMP. NA
FLASH POINT 93 °C / 199.4 °F SARA: NO/NO
Other Limits: IARC-NO. NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
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6 Calcium Carbonate CAS# 13463-67-7 EINECS# Calcium Carbonate
Pct By Wt: 4.0%
ACGIH TLV-TWA 10 mg/m3 OSHA PEL-TWA 10 mg/m3
LD50 (INGESTION) NE LC50 (INHALATION) NE
Other Limits: IARC-NO, NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
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7 TITANIUM DIOXIDE CAS# 13463-67-7 Titanium Dioxide
Pct By Wt: < 23.0%
ACGIH TLV-TWA 10 mg/m3 OSHA PEL-TWA 15 mg/m3
LD50 (INGESTION) NE LC50 (INHALATION) NE
Other Limits: IARC-NO, NTP-NO, OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
Titanium Dioxide contains, Aluminum Hydroxide CAS# 21645-51-2, EINECS# 244-492-7 (0-9% of
Ti02), Amorphous Silica CAS# 7631-86-9, EINECS# 231-545-4 (0-11% of Ti02).
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8 CARBON BLACK CAS# 1333-86-4 CARBON BLACK
Pct By Wt: < 0.1%
ACGIH TLV-TWA 3.5 MG/M3 ACGIH TLV-STEL/C 3.5MG/M3
OSHA PEL-TWA 3.5 MG/M3 OSHA PEL-STEL NE
OSHA PEL-CEILING NE LD50 (INGESTION) NE
LC50 (INHALATION) NE AUTOIGNITION TEMP. NA
SARA: NO/NO/
Other Limits: IARC-YES (GROUP 2B), NTP-NO OSHA-NO, ACGIH-NO, NIOSH-NO HAPS-NO
Other Limits: IARC-YES WARNING: The Carbon Black pigment in this product contains less than 0.1% polynuclear aromatic
hydrocarbons (PAH), some of which, in non-adsorbed form, have been found to be carcinogens in animal studies. Carbon
Black has not been listed by the NTP or OSHA. NIOSH criteria recommends that only carbon blacks with PAH levels greater
than 0.1% be considered suspect carcinogens. In April 1996, the International Agency for Research on Cancer
(IARC) published Monograph 65 wherein IARC’s overall evaluation is that Carbon Black is possibly carcinogenic to humans
(Group 2B).
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Section 3 - Hazards Identification
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Routes of Entry: Inhalation, Skin Contact, Eye Contact
Effects of Overexposure: (No hazardous solvent present)
Inhalation – ACUTE (Pigments): Irritation of the nose, throat and eyes: Asthma-like breathing
may be a delayed reaction. Other possible symptoms of overexposure may include headache,
nausea, narcosis, fatigue and loss of appetite.
Eye Contact: Liquid is irritating to the eyes and can cause pain, tearing, reddening and
swelling.
Skin Contact: Repeated or prolonged skin contact can result in dry, defatted and cracked skin
causing increased susceptibility to infection.
Ingestion: Ingestion can result in irritation in the mouth, stomach tissue and digestive
tract. Symptoms can include sore throat, abdominal pain, nausea, vomiting and diarrhea.
Vomiting may cause aspiration resulting in chemical pneumonitis.
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Section 4 - First Aid Measures
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PRIMARY ROUTE(S) OF ENTRY: Inhalation, Dermal, Ingestion.
EMERGENCY FIRST AID PROCEDURES: When exposed always get medical attention.
EYE CONTACT: Flush with water for 15 minutes.
SKIN CONTACT: Wash with soap and water. Remove contaminated clothing and clean before reuse.
INHALATION: Remove to fresh air. Provide oxygen if breathing is difficult. Use artificial
respiration if not breathing. Get medical attention.
IF SWALLOWED: DO NOT INDUCE VOMITING!! Always get medical attention.
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Section 5 - Fire Fighting Measures
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FIRE AND EXPLOSIVE PROPERTIES OF THE CHEMICAL: (Unless otherwise noted, data are derived from
ingredients existing in this formula at concentrations of 1% by weight or greater, i.e., the
flashpoint given is the lowest flashpoint of the ingredients listed in section 2.)
Flashpoint - - - - - - - - - - - - - - -: >93 °C / > 199 °F PENSKY MARTENS (CLOSED CUP)
Explosion Level - - - - - - - - - - - - : Low 2.6 High 15.3
Flammability Limits - - - - - - - - - - : Low N/A High N/A
Auto-ignition Temperature - - - - - - - : N/A
Extinguishing Media: Not required
Hazard Class: DOT: Not regulated
OSHA: Not regulated
Water may be used to cool fire-exposed structures and vessels.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep away from heat, sparks, and flame. Do not smoke.
Extinguish all pilot lights and turn off all sources of ignition, including heaters, fans and
other non-explosion proof electrical equipment, during use and until all vapors are gone.
Vapors may ignite explosively. Vapors may spread long distances and beyond closed doors.
Prevent build up of vapors by maintaining a continuous flow of fresh air.
FIRE-FIGHTING PROCEDURES AND EQUIPMENT: Self-contained breathing apparatus with full
facepiece operated in pressure-demand or other positive pressure mode. In case of fire, use
Dry chemical, Foam, CO2 or other approved method for treating a Class B fire. Summon
professional firefighters. Extreme dust conditions due to sanding or abrading may be a source
of autoignition in the presence of a flame. Closed container may explode when exposed to
extreme heat.
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Section 6 - Accidental Release Measures
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Steps to take in case of spills:
· Remove all sources of ignition. Ventilate area (refer to extinguishing media in section 4)
· Remove with inert absorbent material
Waste Disposal Method: If discarded this material and containers should be treated as a
hazardous waste, based on the Ignitability characteristics as defined under Federal RCRA
Regulations (40 CFR 261). Dispose of in accordance with local, state, and federal regulations.
DO NOT INCINERATE IN CLOSED CONTAINERS. For further information, contact the United States
Environmental Protection Agency RCRA hotline [phone].
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Section 7 - Handling and Storage
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Handling and Storage: Keep away from heat. When storing, tightly
close containers to prevent evaporation. Do not reseal if contamination
is suspected. Do not take internally.
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Section 8 - Exposure Controls, Personal Protection
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Respiratory Protection: If personal exposure cannot be controlled below applicable limits by
ventilation, use an air-purifying respirator demonstrated to be effective for organic
vapor/particulate and approved by NIOSH for protection against materials in section 2.
Ventilation: Local exhaust is preferable. General exhaust is acceptable if the exposure to
materials in section 2 is maintained below acceptable
exposure limits. Protective Gloves: Wear gloves which are recommended by glove
supplier for protection against Materials in Section 2.