Safety data sheet

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Safety Data Sheet according to Regulation (EC) No 1907/2006

Page 1 of 24

Pattex Spray Permanent

SDS No. : 43180

V007.0

Revision: 13.07.2017

printing date: 01.08.2017

Replaces version from: 08.07.2016

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Pattex Spray Permanent

Contains:

Methyl acetate

1.2. Relevant identified uses of the substance or mixture and uses advised against

Intended use:

Spray adhesive

1.3. Details of the supplier of the safety data sheet

Henkel Ltd

Wood Lane End

HP2 4RQ

Hemel Hempstead

Great Britain

Phone:

+44 1442 278000

Fax-no.:

+44 1442 278071

ua-productsafety.uk@henkel.com

1.4. Emergency telephone number

24 Hours Emergency Tel: +44 0 8701 906777 - For further general health & safety, technical and practical advice on this

product, please call +44 (0) 1606 593933 or write to: Technical Services; Henkel Limited; Road 5; Winsford Industrial Estate;

Winsford; Cheshire; CW7 3QY- Email: technical.services@henkel.co.uk

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (CLP):

Aerosols

Category 1

H222 Extremely flammable aerosol.

Aerosols

Category 3

H229 Pressurised container: May burst if heated.

Skin irritation

Category 2

H315 Causes skin irritation.

Serious eye irritation

Category 2

H319 Causes serious eye irritation.

Specific target organ toxicity - single exposure

Category 3

H336 May cause drowsiness or dizziness.

Target organ: Central Nervous System

Chronic hazards to the aquatic environment

Category 3

H412 Harmful to aquatic life with long lasting effects.

Summary of content (24 pages)

PAGE 1
Safety Data Sheet according to Regulation (EC) No 1907/2006 Page 1 of 24 SDS No. : 43180 V007.0 Revision: 13.07.2017 printing date: 01.08.2017 Replaces version from: 08.07.2016 Pattex Spray Permanent SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Pattex Spray Permanent Contains: Methyl acetate 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Spray adhesive 1.3.
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MSDS-No.: 43180 V007.0 Pattex Spray Permanent Page 2 of 24 2.2. Label elements Label elements (CLP): Hazard pictogram: Signal word: Danger Hazard statement: H222 Extremely flammable aerosol. H229 Pressurised container: May burst if heated. H315 Causes skin irritation. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. H412 Harmful to aquatic life with long lasting effects. Precautionary statement: P101 If medical advice is needed, have product container or label at hand.
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MSDS-No.: 43180 V007.0 Pattex Spray Permanent Page 3 of 24 Declaration of the ingredients according to CLP (EC) No 1272/2008: Hazardous components CAS-No. Methyl acetate 79-20-9 EC Number REACH-Reg No. 201-185-2 01-2119459211-47 content Classification 20- 40 % Flam. Liq. 2 H225 Eye Irrit. 2 H319 STOT SE 3 H336 Flam. Gas 1 H220 Press. Gas Isobutane 75-28-5 200-857-2 01-2119485395-27 20- 40 % Propane 74-98-6 200-827-9 01-2119486944-21 10- 20 % Flam. Gas 1 H220 Press.
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MSDS-No.: 43180 V007.0 Pattex Spray Permanent Page 4 of 24 Butyl hydroxytoluene 128-37-0 204-881-4 01-2119480433-40 01-2119555270-46 01-2119565113-46 0,1- < 1 % Aquatic Acute 1 H400 Aquatic Chronic 1 H410 n-Hexane 110-54-3 203-777-6 01-2119480412-44 0,1- < 1 % Flam. Liq. 2 H225 Repr. 2 H361f Asp. Tox. 1 H304 STOT RE 2 H373 Skin Irrit. 2 H315 STOT SE 3 H336 Aquatic Chronic 2 H411 For full text of the H - statements and other abbreviations see section 16 "Other information".
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MSDS-No.: 43180 V007.0 Pattex Spray Permanent Page 5 of 24 5.2. Special hazards arising from the substance or mixture In the event of a fire, carbon monoxide (CO) and carbon dioxide (CO2) can be released. 5.3. Advice for firefighters Wear protective equipment. Wear self-contained breathing apparatus. Additional information: Cool endangered containers with water spray jet. SECTION 6: Accidental release measures 6.1.
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MSDS-No.: 43180 V007.0 Pattex Spray Permanent Page 6 of 24 SECTION 8: Exposure controls/personal protection 8.1.
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MSDS-No.: 43180 V007.0 Pattex Spray Permanent [ETHYL ACETATE] Ethyl acetate 141-78-6 [ETHYL ACETATE] n-Hexane 110-54-3 [N-HEXANE] n-Hexane 110-54-3 [N-HEXANE] n-Hexane 110-54-3 [N-HEXANE] Cyclohexane 110-82-7 [CYCLOHEXANE] Cyclohexane 110-82-7 [CYCLOHEXANE] 2,6-di-tert-Butyl-p-cresol 128-37-0 [2,6-DITERTIARY-BUTYL-PARACRESOL] Page 7 of 24 400 1.
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MSDS-No.: 43180 V007.0 Pattex Spray Permanent Page 13 of 24 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance pressurized can liquid colourless Odor of solvent Odour threshold No data available / Not applicable pH Melting point Solidification temperature Initial boiling point (1.
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MSDS-No.: 43180 V007.0 Pattex Spray Permanent Page 14 of 24 10.5. Incompatible materials None if used properly. 10.6. Hazardous decomposition products None known. SECTION 11: Toxicological information 11.1. Information on toxicological effects General toxicological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation (EC) No 1272/2008.
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MSDS-No.: 43180 V007.0 Pattex Spray Permanent Page 15 of 24 Acute inhalative toxicity: Hazardous components CAS-No.
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MSDS-No.: 43180 V007.0 Pattex Spray Permanent Page 16 of 24 Serious eye damage/irritation: Hazardous components CAS-No.
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MSDS-No.: 43180 V007.0 Pattex Spray Permanent Page 17 of 24 Germ cell mutagenicity: Hazardous components CAS-No.
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MSDS-No.: 43180 V007.0 Pattex Spray Permanent Page 18 of 24 Reproductive toxicity: Hazardous substances CAS-No. Ethyl acetate 141-78-6 Result / Classification NOAEL P = 1.
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MSDS-No.: 43180 V007.0 Pattex Spray Permanent Hazardous components CAS-No. Value type Value Methyl acetate 79-20-9 LC50 Methyl acetate 79-20-9 Methyl acetate 79-20-9 Page 19 of 24 Exposure time Species 250 - 350 mg/l Acute Toxicity Study Fish 96 h Brachydanio rerio (new name: Danio rerio) EC50 1.026,7 mg/l Daphnia 48 h EC50 > 120 mg/l Algae 72 h NOEC 120 mg/l Algae 72 h Methyl acetate 79-20-9 EC10 1.
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MSDS-No.: 43180 V007.0 Pattex Spray Permanent Page 20 of 24 <0,1% benzene 64742-49-0 Naphtha, hydrotreated light, <0,1% benzene 64742-49-0 Cyclohexane 110-82-7 202 (Daphnia sp. Acute Immobilisation Test) OECD Guideline 201 (Alga, Growth Inhibition Test) Pimephales promelas OECD Guideline 203 (Fish, Acute Toxicity Test) Daphnia magna OECD Guideline 202 (Daphnia sp.
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MSDS-No.: 43180 V007.0 Pattex Spray Permanent Hazardous components CAS-No.
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MSDS-No.: 43180 V007.0 Pattex Spray Permanent SECTION 14: Transport information 14.1. UN number ADR RID ADN IMDG IATA 14.2. UN proper shipping name ADR RID ADN IMDG IATA 14.3. AEROSOLS AEROSOLS AEROSOLS AEROSOLS Aerosols, flammable Transport hazard class(es) ADR RID ADN IMDG IATA 14.4. 1950 1950 1950 1950 1950 2.1 2.1 2.1 2.1 2.1 Packing group ADR RID ADN IMDG IATA 14.5. Environmental hazards ADR RID ADN IMDG IATA 14.6. Special precautions for user ADR RID ADN IMDG IATA 14.7.
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MSDS-No.: 43180 V007.0 Pattex Spray Permanent Page 24 of 24 15.2. Chemical safety assessment A chemical safety assessment has not been carried out. SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: H220 Extremely flammable gas. H225 Highly flammable liquid and vapor. H280 Contains gas under pressure; may explode if heated. H304 May be fatal if swallowed and enters airways.