Safety data sheet

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Safety Data Sheet according to Regulation (EC) No1907/2006

Page 1 of 16

Pattex Power Spray permanent

SDS No. : 43180

V005.1

Revision: 18.07.2014

printing date: 29.05.2015

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Pattex Power Spray permanent

Contains:

Methyl acetate

1.2. Relevant identified uses of the substance or mixture and uses advised against

Intended use:

Spray adhesive

1.3. Details of the supplier of the safety data sheet

Henkel France SAS

Rue de Silly 161

92100

Boulogne Billancourt

France

Phone:

+33 (1) 4684 9000

Fax-no.:

+33 (1) 4684 9090

ua-productsafety.fr@fr.henkel.com

1.4. Emergency telephone number

N° d' appel d' urgence I.N.R.S.: 01 45 42 59 59 (24h)

Anti poison center Paris, France: Tel (emergency) : +33.1.40.05.48.48

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (CLP):

Flammable aerosols

Category 1

H222 Extremely flammable aerosol.

aerosols

Category 3

H229 Pressurised container: May burst if heated.

Serious eye irritation

Category 2

H319 Causes serious eye irritation.

Specific target organ toxicity - single exposure

Category 3

H336 May cause drowsiness or dizziness.

Target organ: Central Nervous System

Chronic hazards to the aquatic environment

Category 3

H412 Harmful to aquatic life with long lasting effects.

Summary of content (16 pages)

PAGE 1
Safety Data Sheet according to Regulation (EC) No1907/2006 Page 1 of 16 SDS No. : 43180 V005.1 Pattex Power Spray permanent Revision: 18.07.2014 printing date: 29.05.2015 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Pattex Power Spray permanent Contains: Methyl acetate 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Spray adhesive 1.3.
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MSDS-No.: 43180 V005.1 Pattex Power Spray permanent Page 2 of 16 Classification (DPD): F+ - Extremely flammable R12 Extremely flammable. Xi - Irritant R36 Irritating to eyes. Dangerous for the environment R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. 2.2.
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MSDS-No.: 43180 V005.1 Pattex Power Spray permanent Page 3 of 16 Label elements (DPD): F+ - Extremely flammable Xi - Irritant Risk phrases: R12 Extremely flammable. R36 Irritating to eyes. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. Safety phrases: S2 Keep out of the reach of children. S9 Keep container in a well-ventilated place.
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MSDS-No.: 43180 V005.1 Pattex Power Spray permanent Page 4 of 16 Declaration of the ingredients according to CLP (EC) No 1272/2008: Hazardous components CAS-No. Methyl acetate 79-20-9 EC Number REACH-Reg No. 201-185-2 content Classification > 20- < 30 % Flammable liquids 2 H225 Serious eye irritation 2 H319 Specific target organ toxicity - single exposure 3 H336 Butane, n- (< 0.1 % butadiene) 106-97-8 203-448-7 01-2119474691-32 > 20- < 30 % Gases under pressure Liquef.
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MSDS-No.: 43180 V005.1 Pattex Power Spray permanent Page 5 of 16 Declaration of ingredients according to DPD (EC) No 1999/45: Hazardous components CAS-No. Methyl acetate 79-20-9 EC Number REACH-Reg No. 201-185-2 content Classification > 20 - < 30 % > 20 - < 30 % F - Highly flammable; R11 Xi - Irritant; R36 R66 R67 F+ - Extremely flammable; R12 Butane, n- (< 0.
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MSDS-No.: 43180 V005.1 Pattex Power Spray permanent Page 6 of 16 4.3. Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media: carbon dioxide, foam, powder, water spray jet, fine water spray Extinguishing media which must not be used for safety reasons: High pressure waterjet 5.2.
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MSDS-No.: 43180 V005.1 Pattex Power Spray permanent Page 7 of 16 SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational Exposure Limits Valid for France Ingredient Methyl acetate 79-20-9 Methyl acetate 79-20-9 Methyl acetate 79-20-9 Butane 106-97-8 Butane 106-97-8 Ethyl acetate 141-78-6 N-HEXANE 110-54-3 n-Hexane 110-54-3 2,6-di-tert-Butyl-p-cresol 128-37-0 ppm 250 mg/m3 760 200 610 800 1.900 800 1.900 400 1.
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MSDS-No.: 43180 V005.
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MSDS-No.: 43180 V005.1 Pattex Power Spray permanent Page 9 of 16 Biological Exposure Indices: Ingredient Parameters n-Hexane 110-54-3 2,5Hexanedion Biological specimen Creatinine in urine Sampling time Conc. Sampling time: End of shift. 5 mg/g Basis of biol. Remark Additional exposure index Information FR IBE Nonspecific 8.2. Exposure controls: Respiratory protection: The product should only be used at workplaces with intensive ventilation/extraction.
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MSDS-No.: 43180 V005.1 Pattex Power Spray permanent upper Page 10 of 16 10,8 %(V) Values referring to propellant The product is not explosive. The formation of explosive vapor/air mixtures is possible. No data available / Not applicable No data available / Not applicable No data available / Not applicable No data available / Not applicable Explosive limits Partition coefficient: n-octanol/water Evaporation rate Vapor density Oxidising properties 9.2.
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MSDS-No.: 43180 V005.1 Pattex Power Spray permanent Page 11 of 16 Acute dermal toxicity: Hazardous components CAS-No. Methyl acetate 79-20-9 Ethyl acetate 141-78-6 Value type LD50 Value > 2.000 mg/kg Route of application dermal LD50 > 18.
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MSDS-No.: 43180 V005.1 Pattex Power Spray permanent Page 12 of 16 SECTION 12: Ecological information General ecological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following.
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MSDS-No.: 43180 V005.1 Pattex Power Spray permanent Hazardous components CAS-No. Value type Value Methyl acetate 79-20-9 LC50 Methyl acetate 79-20-9 Methyl acetate 79-20-9 Page 13 of 16 Exposure time Species 250 - 350 mg/l Acute Toxicity Study Fish 96 h Brachydanio rerio (new name: Danio rerio) EC50 1.
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MSDS-No.: 43180 V005.
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MSDS-No.: 43180 V005.1 Pattex Power Spray permanent SECTION 14: Transport information 14.1. UN number ADR RID ADNR IMDG IATA 14.2. UN proper shipping name ADR RID ADNR IMDG IATA 14.3. AEROSOLS AEROSOLS AEROSOLS AEROSOLS Aerosols, flammable Transport hazard class(es) ADR RID ADNR IMDG IATA 14.4. 1950 1950 1950 1950 1950 2.1 2.1 2.1 2.1 2.1 Packaging group ADR RID ADNR IMDG IATA 14.5. Environmental hazards ADR RID ADNR IMDG IATA 14.6. Special precautions for user ADR RID ADNR IMDG IATA 14.7.
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MSDS-No.: 43180 V005.1 Pattex Power Spray permanent Page 16 of 16 15.2. Chemical safety assessment A chemical safety assessment has not been carried out. National regulations/information (France): General information: Dangerous preparations: Occupational Health: Table No.